Evaluation of heat treated wood swelling by differential scanning calorimetry in relation with chemical composition

24 pagesInternational audienceRetification® is a heat treatment which decreases the swelling of wood and increases its resistance to fungal attack. In this study, differential scanning calorimetry (DSC) was applied in order to determine the fiber saturation point (FSP) of natural and retified® wood. FSP values were used to determine the total swelling of natural and heat-treated wood. The DSC method was compared to the volumetric shrinkage approach. The influence of the heat treatment temperature and duration on the swelling of wood was investigated. Relationships between chemical changes and the reduction of swelling were analysed thoroughly. The equivalence of the DSC method and the volumetric shrinkage method is shown. FSP in association with anhydrous density is a good indicator for the evaluation of the overall swelling of heat-treated wood. Reduction of wood swelling with increasing temperature and duration of thermal treatment is often attributed to hemicelluloses destruction. This study shows that the reduction of beech wood swelling can not only be attributed to the disappearing of adsorption sites that goes with the hemicelluloses destruction. It is suggested that other phenomena such as structural modifications and chemical changes of lignin also play an important part

Evaluation of heat treated beech by non destructive testing

10 pagesImprovement of dimensional stability and durability is wished for the use of wood as a building material. For the last decade, retification® has been industrially developed. It consists in a stabilization and preservation of wood by heat treatment. The aim of this study is to find simple and fast methods to characterize heat treated beech. Non destructive testing is expected to be relevant to evaluate the level of treatment and the properties for the use of heat treated wood. Six treatments were carried out in a pilot reactor. The parameters of the retification® stage (temperature and time) were studied. For each treatment, the non destructive tests (free oscillations in the fundamental mode, colour and dry weight loss)were performed, and the properties for use (mechanical resistance and volumetric shrinkage) measured. Lightness and dry weight loss seem to be suitable properties to characterize beech retification® when the time parameter is fixed. However, they are not suitable for other wood species, and for retification stages with a variable duration. Moreover, the correlation with the properties for use were plotted, but presented too large dispersion to be relevant. After correction of moisture content, the longitudinal Young's modulus of the material is slightly increased by each of the six treatments, but do not present any variation with changing parameters values. On the contrary, the mechanical resistance decreased with increasing temperature and time. Thus the dynamic Young's modulus is not reliable to evaluate the treatment and to predict the loss of mechanical resistance. The logarithmic decrement was not increased by any of the treatments, which is in opposition with the hypothesis that retification® generates cracks and microcracks in the material. Effects of long time at low temperature have been investigated. From these experiments, properties of treated wood may be improved significantly by choosing appropriate values of the parameters

Modification of cement hydration at early ages by natural and heated wood

International audienceHeat treatments of wood are widely used for the reduction of wood swelling and dimensional instability of wood-cement composites. The effect of natural and heated wood on the hydration of cement at early ages was investigated by isothermal calorimetry, thermogravimetry (TGA) and Fourier transform infrared (FTIR) spectroscopy. The addition of wood strongly delays and inhibits the hydration of the silicate phases. Consequently, the amount of portlandite is lower in composites than in neat cement. Approximately 30% of the inhibition of portlandite precipitation is due to an increase of calcium carbonate content in cement paste. The absorption of a part of water by wood produces a decrease in gypsum consumption. Nevertheless, the ettringite formation is not significantly affected since a diffusion of sulfate ions from wood occurs

Thermo-gravimetric analysis as a tool for the optimisation of wood heat treatment parameters

9 pagesRetification is a heat treatment that decreases the swelling of wood and increases its resistance to fungal attack. It consists in a mild pyrolysis of wood (180°C-260°C) that takes place in a non oxidative atmosphere (nitrogen). The industrial development of retification requires optimisation of the treatment temperature and duration. In order to enhance the homogeneity of temperature in the furnace, and to avoid exothermic reaction, low temperatures seem to be preferable to high temperature. On the contrary, duration and temperature of treatment have to be high enough to provide good biological resistance and stabilization to the wood. However, high temperatures lead to a loss of mechanical strength. A question arises from these previous observations: is there any equivalence between a treatment of short time carried out at high temperature and a treatment of longer time at lower temperature? Answering this question can help to optimise rétification temperature and duration. The purpose of this study is to evaluate the relevance of a “time temperature equivalence” (TTE) for wood pyrolysis in the temperature range of retification. The principle of TTE is adapted from the study of wood viscoelastic properties. In this study, it is applied to the rate of anhydrous weight loss during wood pyrolysis. Thermo-gravimetric analysis (TGA) were performed on maritime pine (Pinus pinaster Ait.-) and beech (Fagus sylvatica) wood powder. Isothermal degradations were carried out at different temperatures ranging from 160°C to 260°C. A specific data analyse was carried out on the TGA derivative (DTG) in order to assess the relevance of the TTE in the temperature range of retification. It gave interpretable results for maritime pine, but not for beech. It showed that for maritime pine wood the TTE is confirmed from 200°C to 220°C, and not confirmed for temperatures superior to 230°C. An optimization of the temperature and time of treatment is thus possible

Etude physico-chimique d'un composite ciment-bois durant les premières heures d'hydratation.

3 pagesDans le domaine des nouveaux matériaux de construction, l'utilisation de composites à base ciment et de matériaux organiques devient essentiel. Elle permet d'améliorer ou de modifier les propriétés d'un ciment. Dans ce contexte, le matériau composite ciment-fibre de bois est extrêmement intéressant de par ses propriétés d'isolation phonique et acoustique ainsi que par sa faible masse spécifique. Le but de ce travail est de mieux comprendre les interactions chimiques entre le bois et le ciment ainsi que ces conséquences sur l'hydratation du ciment

Study of efflorescence forming process on cementitious materials // Etude du processus de formation des efflorescences sur des matériaux cimentaires

International audienceEfflorescence is a white deposit of calcium carbonate on the surface of cementitious materials. It appears under specific climatic conditions. Besides the aesthetic problems, an important economical problem also exists, especially for colored materials. Indeed, this phenomenon is a cause for rejection of products by customers. The aims of the study presented herein are to understand the mechanisms involved and identify the main parameters which control efflorescence formation. A procedure was previously performed to produce primary efflorescence in a climatic chamber. As pozzolans are frequently used in order to decrease the intensity of efflorescence, substitution of cement by different pozzolans was studied. This latest research allowed the Authors to underline which parameters were modified by the substitutions and to link decreases in the intensity of efflorescence with those modifications. // Les efflorescences forment un dépôt blanc de carbonate de calcium à la surface de matériaux cimentaires. Elles apparaissent pour des conditions climatiques spécifiques. Au delà du problème esthétique, un important problème économique intervient car ce phénomène peut être la cause du rejet d'un produit par les clients. Les objectifs de l'étude sont la compréhension des mécanismes et l'identification des paramètres principaux qui contrôlent la formation d'efflorescences. Au préalable, un test a été mis au point dans une chambre climatique pour reproduire des efflorescences. Comme les pouzzolanes sont souvent utilisées pour atténuer les efflorescences, la substitution du ciment par différentes pouzzolanes a été étudiée. Cette étude a permis d'identifier les paramètres affectés par ces substitutions et de relier ces modifications à l'atténuation des efflorescences

Energy requirement for fine grinding of torrefied wood

International audienceThe purpose of this study is to investigate the influence of torrefaction on wood grinding energy. Wood chips were torrefied at different temperatures and durations. The energy required to obtain fine powder was measured. Particle size analyses were carried out on each powder sample. It is showed that torrefaction decreases both grinding energy and particle size distribution. A criterion to compare grindability of natural and torrefied wood is proposed. It takes into account both grinding energy and particle size distribution. It accounts the energy required for grinding particles to sizes inferior to 200 μm, for given grinding conditions. Torrefaction is characterised by the anhydrous weight loss (AWL) of wood. For AWL inferior to around 8%, grinding energy decreases fast. Over 8%, grinding energy decreases at a slow rate. Particle size distribution decreases linearly as the AWL increases. Both for spruce and beech, the grinding criterion is decreased of 93% when the AWL is around 28%

Impact des éthers de cellulose sur l'hydratation du silicate tricalcique

National audienceLes mécanismes d'hydratation du ciment en présence de molécules organiques restent assez mal élucidés. Les éthers de cellulose sont systématiquement introduits dans les formulations des mortiers industriels. Leurs conséquences macroscopiques sur la réaction d'hydratation du ciment sont parfaitement connues, notamment en terme de ralentissement de la cinétique d'hydratation, mais elles n'en restent pas moins inexpliquées. Par conséquent, l'interaction des éthers de cellulose avec la matrice cimentaire a été examinée. Les résultats tendent à montrer que les éthers de cellulose ont un impact mineur sur la dissolution des différentes phases anhydres. Au contraire, ces adjuvants présentent un effet important sur la germination-croissance de certains hydrates comme l'hydrosilicate de calcium et la portlandite

Modelling anhydrous weight loss of wood chips during torrefaction in a pilot kiln

International audienceBeech and spruce chips were torrefied in a batch rotating pilot kiln. For each torrefaction the temperature curve of the moving chips bed was recorded. The anhydrous weight loss (AWL) of each torrefaction was measured. Effect of torrefaction temperature and duration on the AWL was studied. In order to optimise short time torrefaction, models that can estimate the AWL from the chips temperature curve are required. Three phenomenological models were successfully applied. They all gave good correlations between experimental and calculated AWL. These three models can be employed to optimise industrial torrefaction. However, the more complex they are, the more difficult it is to understand their physical meaning. It is thus preferable to use simple model for the industrial control of torrefaction

The influence of wood aqueous extractives on the hydration kinetics of plaster

International audienceThe influence of wood aqueous extractives on the hydration of plaster is discussed in this paper. Two species were chosen: poplar and forest pine, and the effect of a thermal treatment, which acts as a dimensional stabiliser for wood, was considered. Calorimetric measurements prove that delays of the setting must be expected, especially for the retified poplar. Conductimetric experiments show that wood extractives seem to act as a retardant of the nucleation phase of the hydration reaction. The chemical analysis of the extracts reveals the presence of acetic acid and phenolic molecules, but other experiments prove that their action is not sufficient to explain the retarding effect. Special attention should be given to the influence of polyphenolic substances known as tannins