202 research outputs found

    On spin-rotation contribution to nuclear spin conversion in C_{3v}-symmetry molecules. Application to CH_3F

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    The symmetrized contribution of E-type spin-rotation interaction to conversion between spin modifications of E- and A_1-types in molecules with C_{3v}-symmetry is considered. Using the high-J descending of collisional broadening for accidental rotational resonances between these spin modifications, it was possible to co-ordinate the theoretical description of the conversion with (updated) experimental data for two carbon-substituted isotopes of fluoromethane. As a result, both E-type spin-rotation constants are obtained. They are roughly one and a half times more than the corresponding constants for (deutero)methane.Comment: 13 pages with single-spacing, REVTeX, no figures, accepted for publication in <J. Phys. B

    Nuclear spin conversion in formaldehyde

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    Theoretical model of the nuclear spin conversion in formaldehyde (H2CO) has been developed. The conversion is governed by the intramolecular spin-rotation mixing of molecular ortho and para states. The rate of conversion has been found equal 1.4*10^{-4}~1/s*Torr. Temperature dependence of the spin conversion has been predicted to be weak in the wide temperature range T=200-900 K.Comment: REVTEX, 16 pages + 5 eps figure

    Coherent control of nuclear spin isomers of molecules: The role of molecular motion

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    Molecular center-of-mass motion is taken into account in the theory of coherent control of nuclear spin isomers of molecules. It is shown that infrared radiation resonant to the molecular rovibrational transition can substantially enrich nuclear spin isomers and speed up their conversion rate.Comment: REVTEX, 13 pages + 3 eps figure

    Extreme matter compression caused by radiation cooling effect in gigabar shock wave driven by laser-accelerated fast electrons

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    Heating a solid with laser-accelerated fast electrons is unique way for a laboratory experiment to generate a plane powerful shock wave with a pressure of several hundred or even thousands of Mbar. Behind the front of such a powerful shock wave, dense plasma is heated to a temperature of several keV. Then, a high rate of radiation energy loss occurs even in low-ZZ plasmas. The effect of strong compression of matter due to radiation cooling in a gigabar shock wave driven by fast electrons is found in computational and theoretical researches. It is shown that the effect of radiation cooling leads to the compression of matter in the peripheral region of shock wave to a density several times larger than the density at its front. Heating a solid by a petawatt flux of laser-accelerated fast electrons allows one to surpass the gigabar pressure level of a plane shock wave, which is the maximum level for the impact of laser-accelerated pellets. Higher pressure about 100 Gbar can be achieved under laboratory conditions only when a spherical target is imploded under the action of a terawatt laser pulse

    The Impact of Supply Chain Management for The Innovation Activity Development in Russia: Relevant Issues

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    Abstract- Innovation activity plays a crucial role in the supply chain and socio-economic development of society, both globally and at the level of individual economic entities. Competent and, as a result, effective management of innovation activities contributes to the satisfaction of the material and intellectual needs of society, provides vital functions of society with fundamentally new benefits and leads to a positive economic effect for the economic entities at the micro, meso, and macro levels. An exploratory case study approach to answer the research questions has been conducted in order to develop a model for innovation management within a supply chain of large manufacturing firm. To study the features of the formation of the innovation activity practice and the current state of innovation activity in the Russia; to identify the causes of technological backwardness of Russia and assess the potential for the development of innovation activity to strengthen the position of the state at the global level

    Kinetic magnetization by fast electrons in laser-produced plasmas at sub-relativistic intensities

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    The problem of spontaneous magnetic field generation with nanosecond laser pulses raises a series of fundamental questions, including the intrinsic magnetization mechanisms in laser-driven plasmas and the understanding of charge-discharge processes in the irradiated target. These two issues are tightly bound as the charge-discharge processes are defined by the currents, which have in turn a feedback by magnetic fields in the plasma. Using direct polaro-interferometric measurements and theoretical analysis, we show that at parameters related to the PALS laser system (1.315 μ1.315 μm, 350 350 ps, and 1016 1016 W/cm2), fast electrons play a decisive role in the generation of magnetic fields in the laser-driven plasma. Spatial distributions of electric currents were calculated from the measured magnetic field and plasma density distributions. The obtained results revealed the characteristics of strong currents observed in capacitor-coil magnetic generation schemes and open a new approach to fundamental studies related to magnetized plasmas.<br/
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