Microwave drying kinetics and quality characteristics of corn

In recent years, microwave (MW) drying has gained popularity as an alternative drying method for a wide variety of food and agricultural products because of increasing concerns over product quality and production costs. However, the determination of drying kinetics that accurately describes microwave drying characteristics is crucial for the optimization of operating parameters, performance improvement of the drying system and product quality. The objective of this study was to investigate the drying kinetics and the quality characteristics of corn kernels, especially the effects of different initial moisture contents (18.3%, 26.3%, 34.3% and 42.3% db), MW power levels (70, 175 and 245 W) and exposure time (80 s and 120 s) on the drying kinetics, drying rate and various key quality parameters. The results indicated that the increased drying rate at higher power levels (P3, 245 W) reduced the drying time considerably but increased stress crack index and reduced germination. In addition, it reduced bulk density, true density and thousand grain weight (TGW). The germination rate of corn was the highest at MW power level P1 (70 W), with the lowest drying rate and observed to decrease with increase in initial moisture content. The reduction in exposure time decreased stress crack index and increased germination rate, bulk density and true density. The correlation analysis among drying rate, germination, stress-crack index (SCI), bulk density, true density and TGW showed that increasing drying rate could lead to an increase in SCI and decrease in germination, bulk density and true densit

Growth of N-substituted polypyrrole layers in ionic liquids: Synthesis and its electrochromic properties

A new series of pyrrole family, N-substituted phenyl attached alkyl at the ortho, meta and para position were synthesized by a straight forward method and were exploited as an innovative monomer for electroactive polymers. Ionic liquids were employed as a medium for electro-polymerization of these monomers to obtain N-(methyl)phenyl polypyrroles. N-substituted polypyrroles show different morphologies and conductivity according to position of methyl group on the benzene ring and synthesis medium. The electrical conductivity value varies with the position of methyl group and was > 10(-5) S/cm, higher than the sample obtained from conventional media. The resulting polymer films were characterized by Fr-IR and UV-Vis spectroscopy, contact angle measurements, cyclic voltammetry and scanning probe microscopic technique along with their electrochromic behavior

A novel lactose biosensor based on electrochemically synthesized 3,4-ethylenedioxythiophene/thiophene (EDOT/Th) copolymer

In this study, a new lactose biosensor has been developed in which the 3,4-ethylenedioxythiophene/thiophene (EDOT/Th) copolymer is used as a transducer. The EDOT/Th copolymer was deposited on the glassy carbon electrode to be used as the working electrode. In addition to the working electrode, the three-electrode system was used in both the electrochemical synthesis and in the biosensor measurements. Lactase (β-galactosidase) that catalyzes the breakdown of lactose into monosaccharides (glucose and galactose) and galactose oxidase that catalyzes the oxidation of the resulting galactose were attached to the copolymer by a cross-linker on the modified working electrode. The response of the enzyme electrode to lactose was determined by cyclic voltammetry (CV) at +0.12 V. Enzyme electrode optimization parameters (pH, temperature, enzyme concentration, etc.) were performed. Fourier transform infrared spectroscopy, scanning electron microscopy and CV methods were used to support copolymer formation. In addition, the characteristics of the enzyme electrode prepared in this study (Km, 0.02 mM; activation energy Ea, 38 kJ/mol; linear working range, up to 1.72 mM; limit of detection, 1.9 × 10−5 M and effects of interferents [uric acid and ascorbic acid]) were determined