Effect of surface hydrogen on the anomalous surface segregation behavior of Cr in Fe-rich Fe-Cr alloys

The segregation behavior of Cr in dilute Fe-Cr alloys is known to be anomalous since the main barrier for surface segregation of Cr in these alloys arises not from the topmost surface layer but from the subsurface layer where the solution energy of Cr is much more endothermic as compared to the topmost surface layer. The Fe-Cr alloys are candidate structural materials for the new generation of nuclear reactors. The surfaces of these alloys will be exposed to hydrogen or its isotopes in these reactors, and although hydrogen is soluble neither in Fe nor in Fe-Cr alloys, it is known that the adsorption energy of hydrogen on the surface of iron is not only exothermic but relatively large. This clearly raises the question of the effect of the hydrogen adsorbed on the surface of iron on the segregation behavior of chromium towards the surface of iron. In this paper we show, on the basis of our ab initio density functional theory calculations, that the presence of hydrogen on the surface of iron leads to a considerably reduced barrier for Cr segregation to both the topmost surface layer and the subsurface layer, but the subsurface layer still controls the barrier for surface segregation. This reduction in the barrier for surface segregation is due to the nature of the Cr-H couple that acts in a complex and synergistic manner. The presence of Cr enhances the exothermic nature of hydrogen adsorption that in turn leads to a reduced barrier for surface segregation. These results should be included in the multiscale modeling of Fe-Cr alloys

A transport coefficient: the electrical conductivity

I describe the lattice determination of the electrical conductivity of the quark gluon plasma. Since this is the first extraction of a transport coefficient with a degree of control over errors, I next use this to make estimates of other transport related quantities using simple kinetic theory formulae. The resulting estimates are applied to fluctuations, ultra-soft photon spectra and the viscosity. Dimming of ultra-soft photons is exponential in the mean free path, and hence is a very sensitive probe of transport.Comment: Talk given in ICPAQGP 2005, SINP, Kolkat

Solar thermal plant impact analysis and requirements definition

Progress on a continuing study comprising of ten tasks directed at defining impact and requirements for solar thermal power systems (SPS), 1 to 10 MWe each in capacity, installed during 1985 through year 2000 in a utility or a nonutility load in the United States is summarized. The point focus distributed receiver (PFDR) solar power systems are emphasized. Tasks 1 through 4, completed to date, include the development of a comprehensive data base on SPS configurations, their performance, cost, availability, and potential applications; user loads, regional characteristics, and an analytic methodology that incorporates the generally accepted utility financial planning methods and several unique modifications to treat the significant and specific characteristics of solar power systems deployed in either central or distributed power generation modes, are discussed

Helicopter external noise prediction and correlation with flight test

Mathematical analysis procedures for predicting the main and tail rotor rotational and broadband noise are presented. The aerodynamic and acoustical data from Operational Loads Survey (OLS) flight program are used for validating the analysis and noise prediction methodology. For the long method of rotational noise prediction, the spanwise, chordwise, and azimuthwise airloading is used. In the short method, the airloads are assumed to be concentrated at a single spanwise station and for higher harmonics an airloading harmonic exponent of 2.0 is assumed. For the same flight condition, the predictions from long and short methods of rotational noise prediction are compared with the flight test results. The short method correlates as well or better than the long method

Vibrations and stresses in layered anisotropic cylinders

An equation describing the radial displacement in a k layered anisotropic cylinder was obtained. The cylinders are initially unstressed but are subjected to either a time dependent normal stress or a displacement at the external boundaries of the laminate. The solution is obtained by utilizing the Vodicka orthogonalization technique. Numerical examples are given to illustrate the procedure