Double-shell CeO2:Yb, Er@SiO2@Ag upconversion composite nanofibers as an assistant layer enhanced near-infrared harvesting for dye-sensitized solar cells

Double-shell CeO2:Yb,Er@SiO2@ Ag upconversion composite nanofibers are synthesized by electro- spinning and subsequent process. CeO2:Yb,Er@SiO2@ Ag nanofibers show high upconversion luminescence property due to the coating of amorphous SiO2 and the surface plasmon resonance effect of Ag nanoparticles. CeO2:Yb,Er@SiO2@ Ag nanofibers act as an assistant layer in dye-sensitized solar cells (DSSCs) and enhance the photoelectric conversion efficiency (PCE) to 8.17%. The photocurrent-voltage characteristic is obtained under 980 nm laser as illumination light source. In addition, the absorption of the incident photon-to-current conversion efficiency curve in 900-1000 nm near-infrared light confirms that the introduction of the upconversion nanomaterial broadens the absorption range, improves the utilization rate of the sunlight and increases the PCE of DSSCs. (C) 2018 Elsevier B.V. All rights reserved

Electrochemistry/Photoelectrochemistry-Based Immunosensing and Aptasensing of Carcinoembryonic Antigen

Recently, electrochemistry- and photoelectrochemistry-based biosensors have been regarded as powerful tools for trace monitoring of carcinoembryonic antigen (CEA) due to the fact of their intrinsic advantages (e.g., high sensitivity, excellent selectivity, small background, and low cost), which play an important role in early cancer screening and diagnosis and benefit people’s increasing demands for medical and health services. Thus, this mini-review will introduce the current trends in electrochemical and photoelectrochemical biosensors for CEA assay and classify them into two main categories according to the interactions between target and biorecognition elements: immunosensors and aptasensors. Some recent illustrative examples are summarized for interested readers, accompanied by simple descriptions of the related signaling strategies, advanced materials, and detection modes. Finally, the development prospects and challenges of future electrochemical and photoelectrochemical biosensors are considered

Calix[4,6,8]arenesulfonates Functionalized Reduced Graphene Oxide with High Supramolecular Recognition Capability: Fabrication and Application for Enhanced Host–Guest Electrochemical Recognition

Reduced graphene oxide (rGO) modified with three kinds of water-soluble p-sulfonated calix­[4,6,8]­arene sodium (SCn: SC4, SC6, SC8) were successfully prepared by using a simple wet chemical strategy. Three obtained SCn-rGO nanocomposites were characterized by Fourier transform infrared spectroscopy, Ultraviolet–visible spectroscopy, static contact angle measurement, thermogravimetric analysis, scanning electron microscope and electrochemical impedance spectroscopy, which confirmed that different amount of SCn molecules had been effectively loaded onto the surface of rGO, and the water-dispersity and stability of SCn-rGO increased with the increase of the value of n in SCn (<i>n</i> = 4, 6, 8). More significantly, cyclic voltammetry measurement showed that the SCn-rGO could exhibit high supramolecular recognition and enrichment capability and consequently displayed excellent electrochemical response toward four probe molecules (biological and organic dye molecules). Especially, SC8-rGO exhibited an excellent electrochemical performance for dopamine with high current densities of 73.04 mA mM^–1 L cm^–2, broad linear range (1 × 10^–8 to 2.1 × 10^–5 M) and very low detection limit (8 × 10^–9 M) at a signal-to-noise ratio of 3

Smart Combination of Cyclodextrin Polymer Host–Guest Recognition and Mg²⁺-Assistant Cyclic Cleavage Reaction for Sensitive Electrochemical Assay of Nucleic Acids

A novel enzyme-free electrochemical sensing strategy was proposed for sensitive monitoring of DNA and miRNA by smart combination of the cyclic cleavage reaction of Mg²⁺-dependent DNAzyme and the host–guest inclusion between ferrocene-labeled hairpin probe (H-1) and nitrogen-doped reduced graphene oxide/β-cyclodextrin polymer (NRGO/β-CDP) nanocomposites. The synthesized NRGO/β-CDP nanocomposites with high electrocatalytic activity and recognition capability were modified on the glassy carbon electrode to construct the sensing platform. Upon the hybridization reaction of subunit DNA in the loop region with target sequence, the active DNAzyme was liberated from the caged structure, which bound with H-1 to catalyze its cleavage in the presence of Mg²⁺ and triggered the target recycling amplification for the cleavage of a large number of H-1. Each cleaved H-1 was divided into two single-stranded oligonucleotides, leading to an obvious enhancement of peak current by the molecular recognition of β-CDP on the electrode. Thus, the constructed biosensor showed high sensitivity and selectivity for DNA and miRNA assays, with wide concentration ranges of 0.01–1000 and 0.05–500 pM and low detection limits of 3.2 and 18 fM, respectively. This developed sensing strategy may become a promising nucleic acid detection method in bioassays and clinical diagnosis

Crystal Structures and Optical Properties of Two Novel 1,3,5-Trisubstituted Pyrazoline Derivatives

Two novel 1,3,5-trisubstituted pyrazoline derivatives&#8212;1-acetyl-3-(4-methoxyphenyl)-5-(6-methoxy-2-naphthyl)-pyrazoline (2a) and 1-(4-nitrophenyl)-3-(4-methoxyphenyl)-5-(6-methoxy-2-naphtyl)-pyrazoline (2b)&#8212;were synthesized and their structures were determined by single crystal X-ray crystallography. Both of the two crystals exhibit twisted structures due to the large dihedral angles between the pyrazolinyl ring and the aromatic ring at the 5-position (88.09&#176; for 2a and 71.26&#176; for 2b). The optical&#8315;physical properties of the two compounds were investigated. The fluorescent emission of 2b arises from the 1,3-disubstituted pyrazoline chromophores and exhibits a red shift in polar solvents and solid-state, which could be attributed to photo-induced intramolecular charge transfer (ICT) from N1 to C3 in the pyrazoline moiety and the intermolecular interactions within the crystal. The fluorescent emissions of 2a (&#955;max 358&#8315;364 nm) in solvents and solid-state both come from 6-methoxy-2-naphthyl chromophores, which are fairly insensitive to the solvent polarity