Some aspects of steroidal epoxide rearrangements

The reactions of 5,6α-epoxy-3β-hydroxy-5α-cholestane, 5,6β-epoxy-3β-hydroxy-5β-cholestane, and 5,6α-epoxy-3β-methoxy-5α-cholestane with boron trifluoride etherate in benzene give largely products of rearrangement via C(5)-O cleavage. These results contrast with the known reactions of the corresponding 3β-acetoxy-epoxides which give high yields of fluorohydrins. [Continues.

Investigating the Digital Literacy Needs of Healthcare Students: Using Mobile Tablet Devices for the Assessment of Student-Nurse Competency in Clinical Practice.

This case study investigates the digital attitudes, skills and development needs of nursing students when using mobile tablet devices to assess studentnurse competencies in clinical practice. Participants have been asked to complete a bespoke skills-based digital competence self-assessment questionnaire based on the EU DIGCOMP framework; this enabled a baseline for both individual and group. The individual characteristics of students were further explored through comments and their reflective diaries results show a complex, highly-individual profile for each student while the group exhibits common characteristics. Further work is proposed to investigate intricacies on how students perceive and use technologies in education and daily lives

Invariant metrics and Hamiltonian Systems

Via a non degenerate symmetric bilinear form we identify the coadjoint representation with a new representation and so we induce on the orbits a simplectic form. By considering Hamiltonian systems on the orbits we study some features of them and finally find commuting functions under the corresponding Lie-Poisson bracketComment: 16 pages corrected typos, changed contents (Prop. 3.4 and Theorem in Section 3

Geometric structures on loop and path spaces

Is is known that the loop space associated to a Riemannian manifold admits a quasi-symplectic structure. This article shows that this structure is not likely to recover the underlying Riemannian metric by proving a result that is a strong indication of the "almost" independence of the quasi-symplectic structure with respect to the metric. Finally conditions to have contact structures on these spaces are studied.Comment: Final version. To appear in Proceedings of Math. Sci. Indian Academy of Science

Large-volume lava flow fields on Venus: Dimensions and morphology

Of all the volcanic features identified in Magellan images, by far the most extensive and really important are lava flow fields. Neglecting the widespread lava plains themselves, practically every C1-MIDR produced so far contains several or many discrete lava flow fields. These range in size from a few hundred square kilometers in area (like those fields associated with small volcanic edifices for example), through all sizes up to several hundred thousand square kilometers in extent (such as many rift related fields). Most of these are related to small, intermediate, or large-scale volcanic edifices, coronae, arachnoids, calderas, fields of small shields, and rift zones. An initial survey of 40 well-defined flow fields with areas greater than 50,000 sq km (an arbitrary bound) has been undertaken. Following Columbia River Basalt terminology, these have been termed great flow fields. This represents a working set of flow fields, chosen to cover a variety of morphologies, sources, locations, and characteristics. The initial survey is intended to highlight representative flow fields, and does not represent a statistical set. For each flow field, the location, total area, flow length, flow widths, estimated flow thicknesses, estimated volumes, topographic slope, altitude, backscatter, emissivity, morphology, and source has been noted. The flow fields range from about 50,000 sq km to over 2,500,000 sq km in area, with most being several hundred square kilometers in extent. Flow lengths measure between 140 and 2840 km, with the majority of flows being several hundred kilometers long. A few basic morphological types have been identified

Noncommutative geometry, topology and the standard model vacuum

As a ramification of a motivational discussion for previous joint work, in which equations of motion for the finite spectral action of the Standard Model were derived, we provide a new analysis of the results of the calculations herein, switching from the perspective of Spectral triple to that of Fredholm module and thus from the analogy with Riemannian geometry to the pre-metrical structure of the Noncommutative geometry. Using a suggested Noncommutative version of Morse theory together with algebraic $K$-theory to analyse the vacuum solutions, the first two summands of the algebra for the finite triple of the Standard Model arise up to Morita equivalence. We also demonstrate a new vacuum solution whose features are compatible with the physical mass matrix.Comment: 24 page

Propulsion system ignition overpressure for the Space Shuttle

Liquid and solid rocket motor propulsion systems create an overpressure wave during ignition, caused by the accelerating gas particles pushing against or displacing the air contained in the launch pad or launch facility and by the afterburning of the fuel-rich gases. This wave behaves as a blast or shock wave characterized by a positive triangular-shaped first pulse and a negative half-sine wave second pulse. The pulse travels up the space vehicle and has the potential of either overloading individual elements or exciting overall vehicle dynamics. The latter effect results from the phasing difference of the wave from one side of the vehicle to the other. This overpressure phasing, or delta P environment, because of its frequency content as well as amplitude, becomes a design driver for certain panels (e.g., thermal shields) and payloads for the Space Shuttle. The history of overpressure effects on the Space Shuttle, the basic overpressure phenomenon, Space Shuttle overpressure environment, scale model overpressure testing, and techniques for suppressing the overpressure environments are considered