Effectiveness of incentives offered by mobile phone app to encourage cycling: A long‐term study

Reduction of car use is one of the most effective ways to tackle congestion-related problems. Using positive incentives to stimulate bicycle use is one possibility to reduce car use. Cycling is a sustainable transport mode that uses little space and is healthy. There is evidence that positive incentives may be more effective than punishing travellers for undesirable behaviour, and the emergence of mobile applications for delivering interventions has opened up new opportunities for influencing travellers. So far, few studies have focused on exploring the effectiveness of positive incentives on long-term behavioural change. We used the SMART app to deliver positive incentives to more than 6000 travellers in the Dutch region of Twente. The app automatically tracks users and provides incentives such as challenges with rewards, feedback, and messages. This study covers the period from March 2017 to June 2018, in which more than 1000 SMART users participated in monthly challenges. We evaluated the effects of the challenges and rewards and found that the challenges did encourage cycling and reduced car use in the short term. There is also some evidence for behavioural change over a longer time period

Adsorption hysteresis of nitrogen and argon in pore networks and characterization of novel microand mesoporous silicas

We report results of nitrogen and argon adsorption experiments performed at 77.4 and 87.3 K on novel micro/ mesoporous silica materials with morphologically different networks of mesopores embedded into microporous matrixes: SE3030 silica with wormlike cylindrical channels of mode diameter of ∼95 Å, KLE silica with cagelike spheroidal pores of ca. 140 Å, KLE/IL silica with spheroidal pores of ∼140 Å connected by cylindrical channels of ∼26 Å, and, also for a comparison, on Vycor glass with a disordered network of pores of mode diameter of ∼70 Å. We show that the type of hysteresis loop formed by adsorption/desorption isotherms is determined by different mechanisms of condensation and evaporation and depends upon the shape and size of pores. We demonstrate that adsorption experiments performed with different adsorptives allow for detecting and separating the effects of pore blocking/percolation and cavitation in the course of evaporation. The results confirm that cavitation-controlled evaporation occurs in ink-bottle pores with the neck size smaller than a certain critical value. In this case, the pressure of evaporation does not depend upon the neck size. In pores with larger necks, percolation-controlled evaporation occurs, as observed for nitrogen (at 77.4 K) and argon (at 87.3 K) on porous Vycor glass. We elaborate a novel hybrid nonlocal density functional theory (NLDFT) method for calculations of pore size distributions from adsorption isotherms in the entire range of micro-and mesopores. The NLDFT method, applied to the adsorption branch of the isotherm, takes into account the effect of delayed capillary condensation in pores of different geometries. The pore size data obtained by the NLDFT method for SE3030, KLE, and KLE/IL silicas agree with the data of SANS/SAXS techniques

Metal-free graphene-carbon nitride hybrids for photodegradation of organic pollutants in water

Hybrid photocatalysts of graphitic carbon nitride (g-C3N4) and reduced graphene oxide (rGO) composites were prepared in one-pot via a thermal condensation of melamine with different amounts of graphene oxide (GO). As metal-free hybrids, the prepared photocatalysts presented enhanced performances in photooxidation of both methylene blue and phenol in water solutions under various light irradiations. The level of rGO significantly affected MB photodegradation efficiencies. The introduced graphene can improve the MB adsorption and optical absorption in visible light region, therefore enables the hybrids to efficiently degrade MB under visible light with wavelengths longer than 430 nm. The metal-free photocatalysts were also able to degrade phenol effectively and the effects of catalyst loading and initial phenol concentration were investigated. This study provided an efficient and environmentally benign photocatalyst for degradation of organic pollutants in water, with complete prevention of secondary contamination from metal-leaching