4 research outputs found
Overlapping Resonances Interference-induced Transparency: The Photoexcitation Spectrum of Pyrazine
The phenomenon of "overlapping resonances interference-induced transparency"
(ORIT) is introduced and studied in detail for the
photoexcitation of cold pyrazine (CHN). In ORIT a molecule becomes
transparent at specific wavelengths due to interferences between envelopes of
spectral lines displaying overlapping resonances. An example is the
internal conversion in pyrazine where destructive
interference between overlapping resonances causes the light
absorption to disappear at certain wavelengths. ORIT may be of practical
importance in multi-component mixtures where it would allow for the selective
excitation of some molecules in preference to others. Interference induced
cross section enhancement is also shown.Comment: 13 pages, 7 figure
The Al+-H2 cation complex: Rotationally resolved infrared spectrum, potential energy surface, and rovibrational calculations
The infrared spectrum of the Al+-H-2 complex is recorded in the H-H stretch region (4075-4110 cm(-1)) by monitoring Al+ photofragments. The H-H stretch band is centered at 4095.2 cm(-1), a shift of -66.0 cm(-1) from the Q(1)(0) transition of the free H-2 molecule. Altogether, 47 rovibrational transitions belonging to the parallel K-a=0-0 and 1-1 subbands were identified and fitted using a Watson A-reduced Hamiltonian, yielding effective spectroscopic constants. The results suggest that Al+-H-2 has a T-shaped equilibrium configuration with the Al+ ion attached to a slightly perturbed H-2 molecule, but that large-amplitude intermolecular vibrational motions significantly influence the rotational constants derived from an asymmetric rotor analysis. The vibrationally averaged intermolecular separation in the ground vibrational state is estimated as 3.03 A, decreasing by 0.03 A when the H-2 subunit is vibrationally excited. A three-dimensional potential energy surface for Al+-H-2 is calculated ab initio using the coupled cluster CCSD(T) method and employed for variational calculations of the rovibrational energy levels and wave functions. Effective dissociation energies for Al+-H-2(para) and Al+-H-2(ortho) are predicted, respectively, to be 469.4 and 506.4 cm(-1), in good agreement with previous measurements. The calculations reproduce the experimental H-H stretch frequency to within 3.75 cm(-1), and the calculated B and C rotational constants to within similar to 2%. Agreement between experiment and theory supports both the accuracy of the ab initio potential energy surface and the interpretation of the measured spectrum