Adsorption of hexavalent and trivalent chromium to a clayey silt soil : batch kinetic and equilibrium studies

Chromium, an element of widespread use, is toxic in some forms. Improper disposal of waste chromium products has resulted in contamination of many sites throughout the United States, including the United Chrome Products Superfund site in Corvallis, Oregon. A better understanding of chromium chemistry is needed to facilitate the remediation of these contaminated sites. The purpose of this study was to investigate the characteristics of adsorption of hexavalent and trivalent chromium (Cr(VI) and Cr(III), respectively) to a clayey silt soil similar to that found at the United Chrome Products site. The effects of pH on adsorption rates and magnitudes, and the effectiveness of selected extractant solutions in removing adsorbed chromium from soil, were evaluated. Simple mathematical models were used to describe adsorption kinetics and equilibrium, and the chemical nature of the adsorption reactions were postulated. Cr(VI) adsorption magnitudes and rates increased as pH decreased. Neither distilled water or groundwater were effective extractants of adsorbed Cr(VI); an 0.02 molar orthophosphate solution was a moderately successfull extractant. Cr(VI) adsorption kinetics were diphasic in nature, and could be described with an irreversible two-site adsorption reaction model. Cr(VI) uptake by the soil was thought to be adsorbed to metallic oxide surfaces rather than reduced to insoluble Cr(III). Trivalent chromium (Cr(III)) was most effectively adsorbed between pH values of four and five. At lower pH values, Cr(III) adsorption magnitudes decreased proportionally with hydrogen ion concentration; at higher pH values, the decrease in Cr(III) adsorption was probably due to complexation with soluble and colloidal organic matter released from the soil. EDTA was only moderately effective in extracting adsorbed Cr(III) from soil

A Search for Water in the Atmosphere of HAT-P-26b Using LDSS-3C

The characterization of a physically-diverse set of transiting exoplanets is an important and necessary step towards establishing the physical properties linked to the production of obscuring clouds or hazes. It is those planets with identifiable spectroscopic features that can most effectively enhance our understanding of atmospheric chemistry and metallicity. The newly-commissioned LDSS-3C instrument on Magellan provides enhanced sensitivity and suppressed fringing in the red optical, thus advancing the search for the spectroscopic signature of water in exoplanetary atmospheres from the ground. Using data acquired by LDSS-3C and the Spitzer Space Telescope, we search for evidence of water vapor in the transmission spectrum of the Neptune-mass planet HAT-P-26b. Our measured spectrum is best explained by the presence of water vapor, a lack of potassium, and either a high-metallicity, cloud-free atmosphere or a solar-metallicity atmosphere with a cloud deck at ~10 mbar. The emergence of multi-scale-height spectral features in our data suggests that future observations at higher precision could break this degeneracy and reveal the planet's atmospheric chemical abundances. We also update HAT-P-26b's transit ephemeris, t_0 = 2455304.65218(25) BJD_TDB, and orbital period, p = 4.2345023(7) days.Comment: 9 pages, 8 figures, Accepted for publication in Ap

Listening to Students: Voices From the Inner City

What do students in Catholic schools view as important aspects of their unique form of education? They want a safe environment for learning, caring and concerned teachers, high expectations for learning, responsibility and respect in the school community, and a clear sense of how school relates to success in life. This article describes a study which clearly documents student perceptions and values

Detection of Helium in the Atmosphere of the Exo-Neptune HAT-P-11b

The helium absorption triplet at a wavelength of 10,833 \AA\ has been proposed as a way to probe the escaping atmospheres of exoplanets. Recently this feature was detected for the first time using Hubble Space Telescope (HST) WFC3 observations of the hot Jupiter WASP-107b. We use similar HST/WFC3 observations to detect helium in the atmosphere of the hot Neptune HAT-P-11b at the $4\sigma$ confidence level. We compare our observations to a grid of 1D models of hydrodynamic escape to constrain the thermospheric temperatures and mass loss rate. We find that our data are best fit by models with high mass loss rates of $\dot{M} \approx 10^{9}$ - $10^{11}$ g s$^{-1}$. Although we do not detect the planetary wind directly, our data are consistent with the prediction that HAT-P-11b is experiencing hydrodynamic atmospheric escape. Nevertheless, the mass loss rate is low enough that the planet has only lost up to a few percent of its mass over its history, leaving its bulk composition largely unaffected. This matches the expectation from population statistics, which indicate that close-in planets with radii greater than 2 R$_{\oplus}$ form and retain H/He-dominated atmospheres. We also confirm the independent detection of helium in HAT-P-11b obtained with the CARMENES instrument, making this the first exoplanet with the detection of the same signature of photoevaporation from both ground- and space-based facilities.Comment: 12 pages, 9 figures, accepted for publication in ApJ

Data from a Public–industry Partnership for Enhancing corn Nitrogen Research

Improving corn (Zeamays L.) N managementis pertinent to economic andenvironmental objectives. However, there are limited comprehensive data sources to develop and test N fertilizer decision aid tools across a wide geographic range of soil and weather scenarios. Therefore, a public-industry partnership was formed to conduct standardized corn N rate response field studies throughout the U.S. Midwest. This research was conducted using a standardized protocol at 49 site-years across eight states over the 2014–2016 growing seasons with many soil, plant, and weather related measurements. This note provides the data (found in supplemental files), outlines the data, summarizes key findings, and highlights the strengths and weakness for those who wish to use this dataset

A Precise Water Abundance Measurement for the Hot Jupiter WASP-43b

The water abundance in a planetary atmosphere provides a key constraint on the planet's primordial origins because water ice is expected to play an important role in the core accretion model of planet formation. However, the water content of the Solar System giant planets is not well known because water is sequestered in clouds deep in their atmospheres. By contrast, short-period exoplanets have such high temperatures that their atmospheres have water in the gas phase, making it possible to measure the water abundance for these objects. We present a precise determination of the water abundance in the atmosphere of the 2 $M_\mathrm{Jup}$ short-period exoplanet WASP-43b based on thermal emission and transmission spectroscopy measurements obtained with the Hubble Space Telescope. We find the water content is consistent with the value expected in a solar composition gas at planetary temperatures (0.4-3.5x solar at 1 $\sigma$ confidence). The metallicity of WASP-43b's atmosphere suggested by this result extends the trend observed in the Solar System of lower metal enrichment for higher planet masses.Comment: Accepted to ApJL; this version contains three supplemental figures that are not included in the published paper. See also our companion paper "Thermal structure of an exoplanet atmosphere from phase-resolved emission spectroscopy" by Stevenson et a

Duality Cascade in Brane Inflation

We show that brane inflation is very sensitive to tiny sharp features in extra dimensions, including those in the potential and in the warp factor. This can show up as observational signatures in the power spectrum and/or non-Gaussianities of the cosmic microwave background radiation (CMBR). One general example of such sharp features is a succession of small steps in a warped throat, caused by Seiberg duality cascade using gauge/gravity duality. We study the cosmological observational consequences of these steps in brane inflation. Since the steps come in a series, the prediction of other steps and their properties can be tested by future data and analysis. It is also possible that the steps are too close to be resolved in the power spectrum, in which case they may show up only in the non-Gaussianity of the CMB temperature fluctuations and/or EE polarization. We study two cases. In the slow-roll scenario where steps appear in the inflaton potential, the sensitivity of brane inflation to the height and width of the steps is increased by several orders of magnitude comparing to that in previously studied large field models. In the IR DBI scenario where steps appear in the warp factor, we find that the glitches in the power spectrum caused by these sharp features are generally small or even unobservable, but associated distinctive non-Gaussianity can be large. Together with its large negative running of the power spectrum index, this scenario clearly illustrates how rich and different a brane inflationary scenario can be when compared to generic slow-roll inflation. Such distinctive stringy features may provide a powerful probe of superstring theory.Comment: Corrections in Eq.(5.47), Eq (5.48), Eq(5.49) and Fig

DBI Inflation using a One-Parameter Family of Throat Geometries

We demonstrate the possibility of examining cosmological signatures in the DBI inflation setup using the BGMPZ solution, a one-parameter family of geometries for the warped throat which interpolate between the Maldacena-Nunez and Klebanov-Strassler solutions. The warp factor is determined numerically and subsequently used to calculate cosmological observables including the scalar and tensor spectral indices, for a sample point in the parameter space. As one moves away from the KS solution for the throat the warp factor is qualitatively different, which leads to a significant change for the observables, but also generically increases the non-Gaussianity of the models. We argue that the different models can potentially be differentiated by current and future experiments.Comment: 17 pages, 10 figures; v2: section 4 expanded, references added; v3: typos fixe

The Antarctic Submillimeter Telescope and Remote Observatory (AST/RO)

AST/RO, a 1.7 m diameter telescope for astronomy and aeronomy studies at wavelengths between 200 and 2000 microns, was installed at the South Pole during the 1994-1995 Austral summer. The telescope operates continuously through the Austral winter, and is being used primarily for spectroscopic studies of neutral atomic carbon and carbon monoxide in the interstellar medium of the Milky Way and the Magellanic Clouds. The South Pole environment is unique among observatory sites for unusually low wind speeds, low absolute humidity, and the consistent clarity of the submillimeter sky. Four heterodyne receivers, an array receiver, three acousto-optical spectrometers, and an array spectrometer are installed. A Fabry-Perot spectrometer using a bolometric array and a Terahertz receiver are in development. Telescope pointing, focus, and calibration methods as well as the unique working environment and logistical requirements of the South Pole are described.Comment: 57 pages, 15 figures. Submitted to PAS

Reconstructing Single Field Inflationary Actions From CMBR Data

This paper describes a general program for deriving the action of single field inflation models with nonstandard kinetic energy terms using CMBR power spectrum data. This method assumes that an action depends on a set of undetermined functions, each of which is a function of either the inflaton wave function or its time derivative. The scalar, tensor and non-gaussianity of the curvature perturbation spectrum are used to derive a set of reconstruction equations whose solution set can specify up to three of the undetermined functions. The method is then used to find the undetermined functions in various types of actions assuming power law type scalar and tensor spectra. In actions that contain only two unknown functions, the third reconstruction equation implies a consistency relation between the non-gaussianty, sound speed and slow roll parameters. In particular we focus on reconstructing a generalized DBI action with an unknown potential and warp factor. We find that for realistic scalar and tensor spectra, the reconstructed warp factor and potential are very similar to the theoretically derived result. Furthermore, physical consistency of the reconstructed warp factor and potential imposes strict constraints on the scalar and tensor spectral indices.Comment: 33 pages, 3 figures: v3 - References adde