260 research outputs found
A benzopyrylium dye as a novel effective cationic uncoupler of oxidative phosphorylation
AbstractBenzopyrylium dye BDBP was found to be an effective uncoupler of oxidative phosphorylation. It stimulates state 4 respiration of mitochondria 2-fold at about 2 μM, reveals a maximum stimulation (8-fold) at 30 μM and inhibits the respiration at higher concentrations. BDBP is also an effective proton (hydroxyl) carrier through bilayer lipid membranes (BLM) as is seen from the electrical properties of BLM with BDBP. Picrate enhances the effects of BDBP on the mitochondrial respiration and BLM conductance. The BDBP activities are accounted for by formation of dimers and complexes with picrate
Mean-field theory of temperature cycling experiments in spin-glasses
We study analytically the effect of temperature cyclings in mean-field
spin-glasses. In accordance with real experiments, we obtain a strong
reinitialization of the dynamics on decreasing the temperature combined with
memory effects when the original high temperature is restored. The same
calculation applied to mean-field models of structural glasses shows no such
reinitialization, again in accordance with experiments. In this context, we
derive some relations between experimentally accessible quantities and propose
new experimental protocols. Finally, we briefly discuss the effect of field
cyclings during isothermal aging.Comment: Some misprints corrected, references updated, final version to apper
in PR
Slow dynamics and aging in spin-glasses
Contribution presented by Eric Vincent in the Conference `Complex Behaviour
of Glassy Systems', Sitges, Barcelona, Spain, June, 1996. It contains a review
of the experimental results on Slow dynamics and aging in spin-glasses. It also
presents their comparison with recent theoretical developments in the
description of the out of equilibrium dynamics of disordered systems; namely,
the trap model and the mean-field theory.Comment: 35 pages, 12 figures, macro lmamult.sty (included
Strong Electronic and Counterion Effects on Geminal Digold Formation and Reactivity as Revealed by Gold(I)-Aryl Model Complexes
Die geminale Diaurierung von [Ph3PAu(Aryl)]‐Komplexen wurde als Modell untersucht, um Einblick in die intermediäre Bildung von geminalen diaurierten Gold(I)‐Vinylkomplexen in der Katalyse zu gewinnen (siehe Schema). Die Ergebnisse tragen zum Verständnis der Faktoren bei, die die Stabilität, Reaktivität und Dynamik dieser metallorganischen Zwischenstufen bestimmen
Recent advances in the chemistry of gold(I) complexes with C-, N- and S-donor ligands part I: alkynyl, amino, imino and nitrido derivatives
ChemInform Abstract: INDOLE 36. MITT. METHODE ZUR SYNTH. VON 2-UNSUBSTITUIERTEN TRYPTAMINEN
ChemInform Abstract: INDOLE 29. MITT. DIE STRUKTUR DER ZWISCHENSTUFE BEI DER SYNTH. VON 2-METHYL-7-AZATRYPTAMIN
ChemInform Abstract: INDOLE 31. MITT. ASYMM. CYCLISCHE ENAMINE BEI DER SYNTH. VON INDOLYLALKYLAMINEN
ChemInform Abstract: (P-TOLYL-(TRIPHENYLPHOSPHIN)-GOLD)-TRIPHENYLPHOSPHIN-GOLD-BORFLUORID
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