A new perspective on staurolite crystal chemistry: use of stoichiometric and chemical end-members for a mole fraction model

Recent contributions to the crystal chemistry of staurolite have been aided by Mossbauer studies on 35 natural and synthetic samples and structure determinations on 42 single crystals. The combination of these data with chemical studies enables us to understand better the crystal chemistry of this mineral relative to its use as a petrogenetic indicator. The preferred thermodynamic mole fraction (activity) model for phase equilibrium calculations takes into account dilution on all cation sites except H. Applied to staurolite-chloritoid pairs, this mole fraction model does not provide an explanation for the variable Kd values between these two minerals. Knowledge of the ferric content, formula, and mole fraction model of staurolite enables meaningful retrieval and use of thermochemical quantities from experimental studies. -from Author

Decompression through clockwise P-T path: implications for early N-S shortening orogenesis in the Mesoproterozoic Mt Isa Inlier (NE Australia)

Mesoproterozoic terranes of the Australian craton exhibit complex tectonometamorphic histories that are generally considered to result from low-pressure/high-temperature (LPHT) metamorphism with an anticlockwise pressure (P)–temperature (T) path. Yet studies regarding the nature of the P–T history and tectonic regime that led to such a LPHT signature have been quite limited. A foliation intersection/inflection axes preserved in the porphyroblast (FIA) analysis combined with textural relationships and P–T pseudosections, using a key locality of the Eastern Fold Belt of the Mt Isa Inlier, has resolved the cause of the LPHT signature in this region. Two periods of porphyroblast growth have been distinguished using a change in FIA trends with time; the first formed during N–S shortening and the second during W–E shortening orogenesis (D1 & D2, respectively). Significantly, D1 porphyroblasts preserving W–E FIAs are minerals of the Barrovian style, whereas D2 formed porphyroblasts preserving N–S FIAs are Buchan in style. This is consistent with the emplacement of the Williams/Naraku Batholiths after D1 around the onset of D2. Higher-pressure garnet cores, that can be modelled in MnNCKFMASH P–T pseudosections, preserve early W–E FIA and formed during D1. This was followed by decompression and then LPHT metamorphism and deformation during which N–S FIAs were preserved within porphyroblasts. This is supported by the presence of at least two generations of staurolite that crystallized before and after andalusite/cordierite. Middle to upper amphibolite facies metamorphic conditions occurred during D1 with crustal thickening followed by near-isothermal decompression leading to LPHT conditions. This was followed by D2 and a second period of middle to upper amphibolite facies metamorphism that obliterated and/or obscured the tectonometamorphic signature of D1 in the matrix of most rocks

Andalusite and Na- and Li-rich cordierite in the La Costa pluton, Sierras Pampeanas, Argentina: textural and chemical evidence for a magmatic origin

The La Costa pluton in the Sierra de Velasco (NW Argentina) consists of S-type granitoids that can be grouped into three igneous facies: the alkali-rich Santa Cruz facies (SCF, SiO2 *67 wt%) distinguished by the presence of andalusite and Na- and Li-rich cordierite (Na2O = 1.55–1.77 wt% and Li2O = 0.14–0.66 wt%), the Anillaco facies (SiO2 *74 wt%) with a significant proportion of Mn-rich garnet, and the Anjullo´n facies (SiO2 *75 wt%) with abundant albitic plagioclase. The petrography, mineral chemistry and whole-rock geochemistry of the SCF are compatible with magmatic crystallization of Na- and Li-rich cordierite, andalusite and muscovite from the peraluminous magma under moderate P–T conditions (*1.9 kbar and ca. 735C). The high Li content of cordierite in the SCF is unusual for granitic rocks of intermediate composition