164 research outputs found
Glasslike Arrest in Spinodal Decomposition as a Route to Colloidal Gelation
Colloid-polymer mixtures can undergo spinodal decomposition into colloid-rich
and colloid-poor regions. Gelation results when interconnected colloid-rich
regions solidify. We show that this occurs when these regions undergo a glass
transition, leading to dynamic arrest of the spinodal decomposition. The
characteristic length scale of the gel decreases with increasing quench depth,
and the nonergodicity parameter exhibits a pronounced dependence on scattering
vector. Mode coupling theory gives a good description of the dynamics, provided
we use the full static structure as input.Comment: 14 pages, 4 figures; replaced with published versio
Particle dynamics in sheared granular matter
The particle dynamics and shear forces of granular matter in a Couette
geometry are determined experimentally. The normalized tangential velocity
declines strongly with distance from the moving wall, independent of
the shear rate and of the shear dynamics. Local RMS velocity fluctuations
scale with the local velocity gradient to the power . These results agree with a locally Newtonian, continuum model, where the
granular medium is assumed to behave as a liquid with a local temperature
and density dependent viscosity
Configurational Entropy and its Crisis in Metastable States: Ideal Glass Transition in a Dimer Model as a Paragidm of a Molecular Glass
We discuss the need for discretization to evaluate the configurational
entropy in a general model. We also discuss the prescription using restricted
partition function formalism to study the stationary limit of metastable
states. We introduce a lattice model of dimers as a paradigm of molecular fluid
and study metastability in it to investigate the root cause of glassy behavior.
We demonstrate the existence of the entropy crisis in metastable states, from
which it follows that the entropy crisis is the root cause underlying the ideal
glass transition in systems with particles of all sizes. The orientational
interactions in the model control the nature of the liquid-liquid transition
observed in recent years in molecular glasses.Comment: 36 pages, 9 figure
Collective dynamics of liquid aluminum probed by Inelastic X-ray Scattering
An inelastic X-ray scattering experiment has been performed in liquid
aluminum with the purpose of studying the collective excitations at wavevectors
below the first sharp diffraction peak. The high instrumental resolution (up to
1.5 meV) allows an accurate investigation of the dynamical processes in this
liquid metal on the basis of a generalized hydrodynamics framework. The
outcoming results confirm the presence of a viscosity relaxation scenario ruled
by a two timescale mechanism, as recently found in liquid lithium.Comment: 8 pages, 7 figure
Closure of the Monte Carlo dynamical equations in the spherical Sherrington-Kirkpatrick model
We study the analytical solution of the Monte Carlo dynamics in the spherical
Sherrington-Kirkpatrick model using the technique of the generating function.
Explicit solutions for one-time observables (like the energy) and two-time
observables (like the correlation and response function) are obtained. We show
that the crucial quantity which governs the dynamics is the acceptance rate. At
zero temperature, an adiabatic approximation reveals that the relaxational
behavior of the model corresponds to that of a single harmonic oscillator with
an effective renormalized mass.Comment: Uuencoded file including: REVTEX (33 pages) and 7 figures
(PostScript)
Fragile-glass behavior of a short range -spin model
In this paper we propose a short range generalization of the -spin
interaction spin-glass model. The model is well suited to test the idea that an
entropy collapse is at the bottom-line of the dynamical singularity encountered
in structural glasses. The model is studied in three dimensions through Monte
Carlo simulations, which put in evidence fragile glass behavior with stretched
exponential relaxation and super-Arrhenius behavior of the relaxation time. Our
data are in favor of a Vogel-Fulcher behavior of the relaxation time, related
to an entropy collapse at the Kauzmann temperature. We however encounter
difficulties analogous to those found in experimental systems when
extrapolating thermodynamical data at low temperatures. We study the spin glass
susceptibility investigating the behavior of the correlation length in the
system. We find that the the increase of the relaxation time is not accompanied
by any growth of the correlation length. We discuss the scaling properties of
off-equilibrium dynamics in the glassy regime, finding qualitative agreement
with the mean-field theory.Comment: 8 pages, LaTeX, 8 postscript figure
Violation of the fluctuation-dissipation theorem in glassy systems: basic notions and the numerical evidence
This review reports on the research done during the past years on violations
of the fluctuation-dissipation theorem (FDT) in glassy systems. It is focused
on the existence of a quasi-fluctuation-dissipation theorem (QFDT) in glassy
systems and the currently supporting knowledge gained from numerical simulation
studies. It covers a broad range of non-stationary aging and stationary driven
systems such as structural-glasses, spin-glasses, coarsening systems,
ferromagnetic models at criticality, trap models, models with entropy barriers,
kinetically constrained models, sheared systems and granular media. The review
is divided into four main parts: 1) An introductory section explaining basic
notions related to the existence of the FDT in equilibrium and its possible
extension to the glassy regime (QFDT), 2) A description of the basic analytical
tools and results derived in the framework of some exactly solvable models, 3)
A detailed report of the current evidence in favour of the QFDT and 4) A brief
digression on the experimental evidence in its favour. This review is intended
for inexpert readers who want to learn about the basic notions and concepts
related to the existence of the QFDT as well as for the more expert readers who
may be interested in more specific results.Comment: 120 pages, 37 figures. Topical review paper . Several typos and
misprints corrected, new references included and others updated. to be
published in J. Phys. A (Math. Gen.
Detection of Crosslinks within and between Proteins by LC-MALDI-TOFTOF and the Software FINDX to Reduce the MSMS-Data to Acquire for Validation
Lysine-specific chemical crosslinking in combination with mass spectrometry is emerging as a tool for the structural characterization of protein complexes and protein-protein interactions. After tryptic digestion of crosslinked proteins there are thousands of peptides amenable to MSMS, of which only very few are crosslinked peptides of interest. Here we describe how the advantage offered by off-line LC-MALDI-TOF/TOF mass spectrometry is exploited in a two-step workflow to focus the MSMS-acquisition on crosslinks mainly. In a first step, MS-data are acquired and all the peak list files from the LC-separated fractions are merged by the FINDX software and screened for presence of crosslinks which are recognized as isotope-labeled doublet peaks. Information on the isotope doublet peak mass and intensity can be used as search constraints to reduce the number of false positives that match randomly to the observed peak masses. Based on the MS-data a precursor ion inclusion list is generated and used in a second step, where a restricted number of MSMS-spectra are acquired for crosslink validation. The decoupling of MS and MSMS and the peptide sorting with FINDX based on MS-data has the advantage that MSMS can be restricted to and focused on crosslinks of Type 2, which are of highest biological interest but often lowest in abundance. The LC-MALDI TOF/TOF workflow here described is applicable to protein multisubunit complexes and using 14N/15N mixed isotope strategy for the detection of inter-protein crosslinks within protein oligomers
Low-frequency excitations in glassy selenium: A comparison of neutron-scattering and molecular-dynamics results
A stature-specific concept for uncemented, primary total hip arthroplasty: 10-year results in 155 patients using two stem shapes and modular necks
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