17 research outputs found
Spectrometer for Hard X-Ray Free Electron Laser Based on Diffraction Focusing
X-ray free electron lasers (XFELs) generate sequences of ultra-short,
spatially coherent pulses of x-ray radiation. We propose the diffraction
focusing spectrometer (DFS), which is able to measure the whole energy spectrum
of the radiation of a single XFEL pulse with an energy resolution of . This is much better than for most modern x-ray
spectrometers. Such resolution allows one to resolve the fine spectral
structure of the XFEL pulse. The effect of diffraction focusing occurs in a
single crystal plate due to dynamical scattering, and is similar to focusing in
a Pendry lens made from the metamaterial with a negative refraction index. Such
a spectrometer is easier to operate than those based on bent crystals. We show
that the DFS can be used in a wide energy range from 5 keV to 20 keV.Comment: 9 pages, 8 figures, 2 table
Spatial properties of conjugated network in semicrystalline polymer thin films studied by intensity x-ray cross-correlation functions
We present results of x-ray study of spatial properties of
conjugated networks in polymer thin films. We applied the x-ray
cross-correlation analysis to x-ray scattering data from blends of
poly(3-hexylthiophene) (P3HT) and gold nanoparticles. The Fourier spectra of
the intensity cross-correlation functions for different films contain non-zero
components of orders and measuring the degree of structural order
in the system.Comment: 6 pages, 2 figures, Proceedings ICXOM22 Conference, 2-6 September
2013, Hamburg, German
Characterization of Spatial Coherence of Synchrotron Radiation with Non-Redundant Arrays of Apertures
We present a method to characterize the spatial coherence of soft X-ray
radiation from a single diffraction pattern. The technique is based on
scattering from non-redundant arrays (NRA) of slits and records the degree of
spatial coherence at several relative separations from one to 15 microns,
simultaneously. Using NRAs we measured the transverse coherence of the X-ray
beam at the XUV X-ray beamline P04 of the PETRA III synchrotron storage ring as
a function of different beam parameters. To verify the results obtained with
the NRAs additional Young's double pinhole experiments were conducted and show
good agreement.Comment: 15 pages, 6 figures, 2 tables, 42 reference
Diffraction based Hanbury Brown and Twiss interferometry performed at a hard x-ray free-electron laser
We demonstrate experimentally Hanbury Brown and Twiss (HBT) interferometry at
a hard X-ray Free Electron Laser (XFEL) on a sample diffraction patterns. This
is different from the traditional approach when HBT interferometry requires
direct beam measurements in absence of the sample. HBT analysis was carried out
on the Bragg peaks from the colloidal crystals measured at Linac Coherent Light
Source (LCLS). We observed high degree (80%) spatial coherence of the full beam
and the pulse duration of the monochromatized beam on the order of 11 fs that
is significantly shorter than expected from the electron bunch measurements.Comment: 32 pages, 10 figures, 2 table
Revealing three-dimensional structure of individual colloidal crystal grain by coherent x-ray diffractive imaging
We present results of a coherent x-ray diffractive imaging experiment
performed on a single colloidal crystal grain. The full three-dimensional (3D)
reciprocal space map measured by an azimuthal rotational scan contained several
orders of Bragg reflections together with the coherent interference signal
between them. Applying the iterative phase retrieval approach, the 3D structure
of the crystal grain was reconstructed and positions of individual colloidal
particles were resolved. As a result, an exact stacking sequence of hexagonal
close-packed layers including planar and linear defects were identified.Comment: 8 pages, 5 figure
Spontaneous supercrystal formation during a strain-engineered metal-insulator transition
Mott metal-insulator transitions possess electronic, magnetic, and structural
degrees of freedom promising next generation energy-efficient electronics. We
report a previously unknown, hierarchically ordered state during a Mott
transition and demonstrate correlated switching of functional electronic
properties. We elucidate in-situ formation of an intrinsic supercrystal in a
Ca2RuO4 thin film. Machine learning-assisted X-ray nanodiffraction together
with electron microscopy reveal multi-scale periodic domain formation at and
below the film transition temperature (TFilm ~ 200-250 K) and a separate
anisotropic spatial structure at and above TFilm. Local resistivity
measurements imply an intrinsic coupling of the supercrystal orientation to the
material's anisotropic conductivity. Our findings add an additional degree of
complexity to the physical understanding of Mott transitions, opening
opportunities for designing materials with tunable electronic properties
X-ray cross-correlation analysis of liquid crystal membranes in the vicinity of the hexatic-smectic phase transition
We present an x-ray study of liquid crystal membranes in the vicinity of the hexatic-smectic phase transitionby means of angular x-ray cross-correlation analysis. By applying two-point angular-intensity cross-correlation functions to the measured series of diffraction patterns the parameters of bond-orientational (BO) order in hexatic phase were directly determined. The temperature dependence of the positional correlation lengths was analyzed as well. The obtained correlation lengths show larger values for the higher-order Fourier components of BO order. These findings indicate a strong coupling between BO and positional order
Local structure of semicrystalline P3HT films probed by nanofocused coherent X-rays
The hidden structural properties of semicrystalline polymer films are revealed by nanofocused X-ray scattering studies. X-ray cross-correlation analysis (XCCA) is employed to diffraction patterns from blends of poly(3-hexylthiophene) (P3HT) with gold nanoparticles (AuNPs). Spatially resolved maps of orientational distribution of crystalline domains allow us to distinguish sample regions of predominant face-on morphology, with a continuous transition to edge-on morphology. The average size of crystalline domains was determined to be of the order of 10 nm. As compared to pristine P3HT film, the P3HT/AuNPs blend is characterized by substantial ordering of crystalline domains, which can be induced by Au nanoparticles. The inhomogeneous structure of the polymer film is clearly visualized on the spatially resolved nanoscale 2D maps obtained using XCCA. Our results suggest that the observed changes of the polymer matrix within crystalline regions can be attributed to nanoconfinement in the presence of gold nanoparticles. This journal i