Hydrogen Production by Formic Acid Decomposition over Ca Promoted Ni/SiO2 Catalysts: Effect of the Calcium Content

Formic acid, a major product of biomass processing, is regarded as a potential liquid carrier for hydrogen storage and delivery. The catalytic dehydrogenation of FA to generate hydrogen using heterogeneous catalysts is of great interest. Ni based catalysts supported on silica were synthesized by incipient wet impregnation. The eect of doping with an alkaline earth metal (calcium) wasstudied, and the solids were tested in the formic acid decomposition reaction to produce hydrogen.The catalysts were characterized by X-ray diraction (XRD), X-ray photoelectron spectroscopy (XPS), temperature-programmed reduction (TPR), Fourier transform infrared spectroscopy (FTIR), transmission electron microscopy (TEM), and programmed temperature surface reaction (TPSR).The catalyst doped with 19.3 wt.% of Ca showed 100% conversion of formic acid at 160 C, with a 92% of selectivity to hydrogen. In addition, all the tested materials were promising for their application, since they showed catalytic behaviors (conversion and selectivity to hydrogen) comparable to thoseof noble metals reported in the literature.Fil: Faroldi, Betina María Cecilia. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera". Universidad Nacional del Litoral. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera"; ArgentinaFil: Paviotti, María Aneley. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera". Universidad Nacional del Litoral. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera"; ArgentinaFil: Camino-Manjarrés, M.. Universidad de Salamanca; EspañaFil: González-Carrazán, S.. Universidad de Salamanca; EspañaFil: López-Olmos, C.. Consejo Superior de Investigaciones Científicas. Instituto de Catálisis y Petroleoquímica; EspañaFil: Rodríguez-Ramos, I.. Consejo Superior de Investigaciones Científicas. Instituto de Catálisis y Petroleoquímica; Españ

Hydrogen production by formic acid decomposition over ca promoted Ni/SiO2 Catalysts: effect of the calcium content

© The Author(s).Formic acid, a major product of biomass processing, is regarded as a potential liquid carrier for hydrogen storage and delivery. The catalytic dehydrogenation of FA to generate hydrogen using heterogeneous catalysts is of great interest. Ni based catalysts supported on silica were synthesized by incipient wet impregnation. The effect of doping with an alkaline earth metal (calcium) was studied, and the solids were tested in the formic acid decomposition reaction to produce hydrogen. The catalysts were characterized by X-ray diffraction (XRD), X-ray photoelectron spectroscopy (XPS), temperature-programmed reduction (TPR), Fourier transform infrared spectroscopy (FTIR), transmission electron microscopy (TEM), and programmed temperature surface reaction (TPSR). The catalyst doped with 19.3 wt.% of Ca showed 100% conversion of formic acid at 160 °C, with a 92% of selectivity to hydrogen. In addition, all the tested materials were promising for their application, since they showed catalytic behaviors (conversion and selectivity to hydrogen) comparable to those of noble metals reported in the literature.This research was supported by the Spanish Agencia Estatal de Investigación (AEI) under project CTQ-2017-89443-C3-3-R. CONICET Postdoctoral External Scholarship awarded to B. Faroldi is acknowledged.Peer reviewe