4 research outputs found
High-Performance Flexible Perovskite Solar Cells by Using a Combination of Ultrasonic Spray-Coating and Low Thermal Budget Photonic Curing
Realizing the commercialization of
high-performance and robust perovskite solar cells urgently requires
the development of economically scalable processing techniques. Here
we report a high-throughput ultrasonic spray-coating (USC) process
capable of fabricating perovskite film-based solar cells on glass
substrates with a power conversion efficiency (PCE) as high as 13%.
Perovskite films with high uniformity, crystallinity, and surface
coverage are obtained in a single step. Moreover, we report USC processing
on TiO<sub>2</sub>/ITO-coated polyethylene terephthalate (PET) substrates
to realize flexible perovskite solar cells with a PCE as high as 8.1%
that are robust under mechanical stress. In this case, a photonic
curing technique was used to achieve a highly conductive TiO<sub>2</sub> layer on flexible PET substrates for the first time. The high device
performance and reliability obtained by this combination of USC processing
with optical curing appear very promising for roll-to-roll manufacturing
of high-efficiency, flexible perovskite solar cells
Synthesis of Millimeter-Size Hexagon-Shaped Graphene Single Crystals on Resolidified Copper
We present a facile method to grow millimeter-size, hexagon-shaped, monolayer, single-crystal graphene domains on commercial metal foils. After a brief <i>in situ</i> treatment, namely, melting and subsequent resolidification of copper at atmospheric pressure, a smooth surface is obtained, resulting in the low nucleation density necessary for the growth of large-size single-crystal graphene domains. Comparison with other pretreatment methods reveals the importance of copper surface morphology and the critical role of the melting–resolidification pretreatment. The effect of important growth process parameters is also studied to determine their roles in achieving low nucleation density. Insight into the growth mechanism has thus been gained. Raman spectroscopy and selected area electron diffraction confirm that the synthesized millimeter-size graphene domains are high-quality monolayer single crystals with zigzag edge terminations
Unraveling the Fundamental Mechanisms of Solvent-Additive-Induced Optimization of Power Conversion Efficiencies in Organic Photovoltaic Devices
The
realization of controllable morphologies of bulk heterojunctions
(BHJ) in organic photovoltaics (OPVs) is one of the key factors enabling
high-efficiency devices. We provide new insights into the fundamental
mechanisms essential for the optimization of power conversion efficiencies
(PCEs) with additive processing to PBDTTT-CF:PC<sub>71</sub>BM system.
We have studied the underlying mechanisms by monitoring the 3D nanostructural
modifications in BHJs and correlated the modifications with the optical
analysis and theoretical modeling of charge transport. Our results
demonstrate profound effects of diiodooctane (DIO) on morphology and
charge transport in the active layers. For small amounts of DIO (<3
vol %), DIO promotes the formation of a well-mixed donor–acceptor
compact film and augments charge transfer and PCE. In contrast, for
large amounts of DIO (>3 vol %), DIO facilitates a loosely packed
mixed morphology with large clusters of PC<sub>71</sub>BM, leading
to deterioration in PCE. Theoretical modeling of charge transport
reveals that DIO increases the mobility of electrons and holes (the
charge carriers) by affecting the energetic disorder and electric
field dependence of the mobility. Our findings show the implications
of phase separation and carrier transport pathways to achieve optimal
device performances
Surface-Induced Orientation Control of CuPc Molecules for the Epitaxial Growth of Highly Ordered Organic Crystals on Graphene
The epitaxial growth and preferred
molecular orientation of copper
phthalocyanine (CuPc) molecules on graphene has been systematically
investigated and compared with growth on Si substrates, demonstrating
the role of surface-mediated interactions in determining molecular
orientation. X-ray scattering and diffraction, scanning tunneling
microscopy, scanning electron microscopy, and first-principles theoretical
calculations were used to show that the nucleation, orientation, and
packing of CuPc molecules on films of graphene are fundamentally different
compared to those grown on Si substrates. Interfacial dipole interactions
induced by charge transfer between CuPc molecules and graphene are
shown to epitaxially align the CuPc molecules in a face-on orientation
in a series of ordered superstructures. At high temperatures, CuPc
molecules lie flat with respect to the graphene substrate to form
strip-like CuPc crystals with micrometer sizes containing monocrystalline
grains. Such large epitaxial crystals may potentially enable improvement
in the device performance of organic thin films, wherein charge transport,
exciton diffusion, and dissociation are currently limited by grain
size effects and molecular orientation