1,213 research outputs found
Motion by Stopping: Rectifying Brownian Motion of Non-spherical Particles
We show that Brownian motion is spatially not symmetric for mesoscopic
particles embedded in a fluid if the particle is not in thermal equilibrium and
its shape is not spherical. In view of applications on molecular motors in
biological cells, we sustain non-equilibrium by stopping a non-spherical
particle at periodic sites along a filament. Molecular dynamics simulations in
a Lennard-Jones fluid demonstrate that directed motion is possible without a
ratchet potential or temperature gradients if the asymmetric non-equilibrium
relaxation process is hindered by external stopping. Analytic calculations in
the ideal gas limit show that motion even against a fluid drift is possible and
that the direction of motion can be controlled by the shape of the particle,
which is completely characterized by tensorial Minkowski functionals.Comment: 11 pages, 5 figure
Power Utility Maximization in Discrete-Time and Continuous-Time Exponential Levy Models
Consider power utility maximization of terminal wealth in a 1-dimensional
continuous-time exponential Levy model with finite time horizon. We discretize
the model by restricting portfolio adjustments to an equidistant discrete time
grid. Under minimal assumptions we prove convergence of the optimal
discrete-time strategies to the continuous-time counterpart. In addition, we
provide and compare qualitative properties of the discrete-time and
continuous-time optimizers.Comment: 18 pages, to appear in Mathematical Methods of Operations Research.
The final publication is available at springerlink.co
Structural basis for a distinct catalytic mechanism in Trypanosoma brucei tryparedoxin peroxidase
Trypanosoma brucei, the causative agent of African sleeping sickness, encodes three cysteine homologues (Px I-III) of classical selenocysteine-containing glutathione peroxidases. The enzymes obtain their reducing equivalents from the unique trypanothione (bis(glutathionyl)spermidine)/tryparedoxin system. During catalysis, these tryparedoxin peroxidases cycle between an oxidized form with an intramolecular disulfide bond between Cys(47) and Cys(95) and the reduced peroxidase with both residues in the thiol state. Here we report on the three-dimensional structures of oxidized T. brucei Px III at 1.4A resolution obtained by x-ray crystallography and of both the oxidized and the reduced protein determined by NMR spectroscopy. Px III is a monomeric protein unlike the homologous poplar thioredoxin peroxidase (TxP). The structures of oxidized and reduced Px III are essentially identical in contrast to what was recently found for TxP. In Px III, Cys(47), Gln(82), and Trp(137) do not form the catalytic triad observed in the selenoenzymes, and related proteins and the latter two residues are unaffected by the redox state of the protein. The mutational analysis of three conserved lysine residues in the vicinity of the catalytic cysteines revealed that exchange of Lys(107) against glutamate abrogates the reduction of hydrogen peroxide, whereas Lys(97) and Lys(99) play a crucial role in the interaction with tryparedoxin
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Impacts of enhanced weathering on biomass production for negative emission technologies and soil hydrology
Limiting global mean temperature changes to well below 2 °C likely requires a rapid and large-scale deployment of negative emission technologies (NETs). Assessments so far have shown a high potential of biomass-based terrestrial NETs, but only a few assessments have included effects of the commonly found nutrient-deficient soils on biomass production. Here, we investigate the deployment of enhanced weathering (EW) to supply nutrients to areas of afforestation-reforestation and naturally growing forests (AR) and bioenergy grasses (BG) that are deficient in phosphorus (P), besides the impacts on soil hydrology. Using stoichiometric ratios and biomass estimates from two established vegetation models, we calculated the nutrient demand of AR and BG. Insufficient geogenic P supply limits C storage in biomass. For a mean P demand by AR and a lowgeogenic-P-supply scenario, AR would sequester 119 Gt C in biomass; for a high-geogenic-P-supply and low-AR-Pdemand scenario, 187 Gt C would be sequestered in biomass; and for a low geogenic P supply and high AR P demand, only 92 GtC would be accumulated by biomass. An average amount of ∼ 150 Gt basalt powder applied for EW would be needed to close global P gaps and completely sequester projected amounts of 190 Gt C during the years 2006-2099 for the mean AR P demand scenario (2-362 Gt basalt powder for the low-AR-P-demand and for the high-AR-P-demand scenarios would be necessary, respectively). The average potential of carbon sequestration by EW until 2099 is ∼ 12 GtC (∼ 0:2-∼ 27 Gt C) for the specified scenarios (excluding additional carbon sequestration via alkalinity production). For BG, 8 kg basaltm2 a1 might, on average, replenish the exported potassium (K) and P by harvest. Using pedotransfer functions, we show that the impacts of basalt powder application on soil hydraulic conductivity and plant-Available water, to close predicted P gaps, would depend on basalt and soil texture, but in general the impacts are marginal. We show that EW could potentially close the projected P gaps of an AR scenario and nutrients exported by BG harvest, which would decrease or replace the use of industrial fertilizers. Besides that, EW ameliorates the soil's capacity to retain nutrients and soil pH and replenish soil nutrient pools. Lastly, EW application could improve plant-Available-water capacity depending on deployed amounts of rock powder - adding a new dimension to the coupling of land-based biomass NETs with EW. © 2020 Royal Society of Chemistry. All rights reserved
Density of states of a type-II superconductor in a high magnetic field: Impurity effects
We have calculated the density of states of a dirty but
homogeneous superconductor in a high magnetic field. We assume a dilute
concentration of scalar impurities and find how behaves as one
crosses from the weak scattering to the strong scattering limit. At low
energies, for small values of the impurity
concentration and scattering strength. When the disorder becomes stronger than
some critical value, a finite density of states is created at the Fermi
surface. These results are a consequence of the gapless nature of the
quasiparticle excitation spectrum in a high magnetic field.Comment: 20 pages in RevTeX, 4 figures, to appear in Phys. Rev. B (July 1,
1997
Ginzburg-Landau-Gor'kov Theory of Magnetic oscillations in a type-II 2-dimensional Superconductor
We investigate de Haas-van Alphen (dHvA) oscillations in the mixed state of a
type-II two-dimensional superconductor within a self-consistent Gor'kov
perturbation scheme. Assuming that the order parameter forms a vortex lattice
we can calculate the expansion coefficients exactly to any order. We have
tested the results of the perturbation theory to fourth and eight order against
an exact numerical solution of the corresponding Bogoliubov-de Gennes
equations. The perturbation theory is found to describe the onset of
superconductivity well close to the transition point . Contrary to
earlier calculations by other authors we do not find that the perturbative
scheme predicts any maximum of the dHvA-oscillations below . Instead we
obtain a substantial damping of the magnetic oscillations in the mixed state as
compared to the normal state. We have examined the effect of an oscillatory
chemical potential due to particle conservation and the effect of a finite
Zeeman splitting. Furthermore we have investigated the recently debated issue
of a possibility of a sign change of the fundamental harmonic of the magnetic
oscillations. Our theory is compared with experiment and we have found good
agreement.Comment: 39 pages, 8 figures. This is a replacement of supr-con/9608004.
Several sections changed or added, including a section on the effect of spin
and the effect of a conserved number of particles. To be published in Phys.
Rev.
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