10,954 research outputs found
Safely dissolvable and healable active packaging films based on alginate and pectin
Extensive usage of long-lasting petroleum based plastics for short-lived application such as packaging has raised concerns regarding their role in environmental pollution. In this research, we have developed active, healable, and safely dissolvable alginate-pectin based biocomposites that have potential applications in food packaging. The morphological study revealed the rough surface of these biocomposite films. Tensile properties indicated that the fabricated samples have mechanical properties in the range of commercially available packaging films while possessing excellent healing effciency. Biocomposite films exhibited higher hydrophobicity properties compared to neat alginate films. Thermal analysis indicated that crosslinked biocomposite samples possess higher thermal stability in temperatures below 120 °C, while antibacterial analysis against E. coli and S. aureus revealed the antibacterial properties of the prepared samples against different bacteria. The fabricated biodegradable multi-functional biocomposite films possess various imperative properties, making them ideal for utilization as packaging material
Emergence of weight-topology correlations in complex scale-free networks
Different weighted scale-free networks show weights-topology correlations
indicated by the non linear scaling of the node strength with node
connectivity. In this paper we show that networks with and without
weight-topology correlations can emerge from the same simple growth dynamics of
the node connectivities and of the link weights. A weighted fitness network is
introduced in which both nodes and links are assigned intrinsic fitness. This
model can show a local dependence of the weight-topology correlations and can
undergo a phase transition to a state in which the network is dominated by few
links which acquire a finite fraction of the total weight of the network.Comment: (4 pages,3 figures
Validation of the English and Chinese versions of the Quick-FLIC quality of life questionnaire.
A useful measure of quality of life should be easy and quick to complete. Recently, we reported the development and validation of a shortened Chinese version of the Functional Living Index-Cancer (FLIC), which we called the Quick-FLIC. In the present study of 327 English-speaking and 221 Chinese-speaking cancer patients, we validated the English version of the Quick-FLIC and further assessed the Chinese version. The 11 Quick-FLIC items were administered alongside the 11 remaining items of the full FLIC, but there appeared to be little context effect. Validity of the English version of the Quick-FLIC was attested by its strong correlation with two other measures of quality of life, and its ability to detect differences between patients with different performance status and treatment status (each P<0.001). Its internal consistency (alpha=0.86) and test-retest reliability (intraclass correlation=0.76) were also satisfactory. The measure was responsive to changes in performance status (P<0.001). The Chinese version showed similar characteristics. The Quick-FLIC behaved in ways that are highly comparable with the FLIC, even though the Quick-FLIC comprised only 11 items whereas the FLIC comprised 22. Further research is required to see whether the use of shorter instruments can improve data quality and response rates, but the fact that shorter instruments place less burden on the patients is itself inherently important
Waiting time dynamics of priority-queue networks
We study the dynamics of priority-queue networks, generalizations of the
binary interacting priority queue model introduced by Oliveira and Vazquez
[Physica A {\bf 388}, 187 (2009)]. We found that the original AND-type protocol
for interacting tasks is not scalable for the queue networks with loops because
the dynamics becomes frozen due to the priority conflicts. We then consider a
scalable interaction protocol, an OR-type one, and examine the effects of the
network topology and the number of queues on the waiting time distributions of
the priority-queue networks, finding that they exhibit power-law tails in all
cases considered, yet with model-dependent power-law exponents. We also show
that the synchronicity in task executions, giving rise to priority conflicts in
the priority-queue networks, is a relevant factor in the queue dynamics that
can change the power-law exponent of the waiting time distribution.Comment: 5 pages, 3 figures, minor changes, final published versio
Cluster size dependence of high-order harmonic generation
We investigate high-order harmonic generation (HHG) from noble gas clusters
in a supersonic gas jet. To identify the contribution of harmonic generation
from clusters versus that from gas monomers, we measure the high-order harmonic
output over a broad range of the total atomic number density in the jet (from
3*10^16 cm^{-3} to 3x10^18 cm{-3}) at two different reservoir temperatures (303
K and 363 K). For the firrst time in the evaluation of the harmonic yield in
such measurements, the variation of the liquid mass fraction, g, versus
pressure and temperature is taken into consideration, which we determine,
reliably and consistently, to be below 20% within our range of experimental
parameters. By comparing the measured harmonic yield from a thin jet with the
calculated corresponding yield from monomers alone, we find an increased
emission of the harmonics when the average cluster size is less than 3000.
Using g, under the assumption that the emission from monomers and clusters add
up coherently, we calculate the ratio of the average single-atom response of an
atom within a cluster to that of a monomer and find an enhancement of around 10
for very small average cluster size (~200). We do not find any dependence of
the cut-off frequency on the composition of the cluster jet. This implies that
HHG in clusters is based on electrons that return to their parent ions and not
to neighbouring ions in the cluster. To fully employ the enhanced average
single-atom response found for small average cluster sizes (~200), the nozzle
producing the cluster jet must provide a large liquid mass fraction at these
small cluster sizes for increasing the harmonic yield. Moreover, cluster jets
may allow for quasi-phase matching, as the higher mass of clusters allows for a
higher density contrast in spatially structuring the nonlinear medium.Comment: 16 pages, 6 figure
Platelet reactivity is independent of left atrial wall deformation in patients with atrial fibrillation
It has been documented recently that left atrial (LA) deformation in AF patients (while in AF) is predictive of subsequent stroke risk. Additionally, diminished LA deformation during AF correlates with the presence of LA blood stasis. Given that endothelial function is dependent on laminar blood flow, the present study sought to investigate the effect of diminished LA deformation (during AF) on platelet reactivity and inflammation in AF patients. Patients (n = 17) hospitalised with AF underwent echocardiography (while in AF) for determination of peak positive LA strain (LASp). Whole blood impedance aggregometry was used to measure extent of ADP-induced aggregation and subsequent inhibitory response to the nitric oxide (NO) donor, sodium nitroprusside. Platelet thioredoxin-interacting protein (Txnip) content was determined by immunohistochemistry. LASp tended (p = 0.078) to vary inversely with CHA2DS2VASc scores. However, mediators of inflammation (C-reactive protein, Txnip) did not correlate significantly with LASp nor did extent of ADP-induced platelet aggregation or platelet NO response. These results suggest that the thrombogenic risk associated with LA stasis is independent of secondary effects on platelet aggregability or inflammation.Nathan Procter, Vincent Goh, Gnanadevan Mahadevan, Simon Stewart, and John Horowit
Single-shot fluctuations in waveguided high-harmonic generation
For exploring the application potential of coherent soft x-ray (SXR) and
extreme ultraviolet radiation (XUV) provided by high-harmonic generation, it is
important to characterize the central output parameters. Of specific importance
are pulse-to-pulse (shot-to-shot) fluctuations of the high-harmonic output
energy, fluctuations of the direction of the emission (pointing instabilities),
and fluctuations of the beam divergence and shape that reduce the spatial
coherence. We present the first single-shot measurements of waveguided
high-harmonic generation in a waveguided (capillary-based) geometry. Using a
capillary waveguide filled with Argon gas as the nonlinear medium, we provide
the first characterization of shot-to-shot fluctuations of the pulse energy, of
the divergence and of the beam pointing. We record the strength of these
fluctuations vs. two basic input parameters, which are the drive laser pulse
energy and the gas pressure in the capillary waveguide. In correlation
measurements between single-shot drive laser beam profiles and single-shot
high-harmonic beam profiles we prove the absence of drive laser
beam-pointing-induced fluctuations in the high-harmonic output. We attribute
the main source of high-harmonic fluctuations to ionization-induced nonlinear
mode mixing during propagation of the drive laser pulse inside the capillary
waveguide
Fairness Beyond Disparate Treatment & Disparate Impact: Learning Classification without Disparate Mistreatment
Automated data-driven decision making systems are increasingly being used to
assist, or even replace humans in many settings. These systems function by
learning from historical decisions, often taken by humans. In order to maximize
the utility of these systems (or, classifiers), their training involves
minimizing the errors (or, misclassifications) over the given historical data.
However, it is quite possible that the optimally trained classifier makes
decisions for people belonging to different social groups with different
misclassification rates (e.g., misclassification rates for females are higher
than for males), thereby placing these groups at an unfair disadvantage. To
account for and avoid such unfairness, in this paper, we introduce a new notion
of unfairness, disparate mistreatment, which is defined in terms of
misclassification rates. We then propose intuitive measures of disparate
mistreatment for decision boundary-based classifiers, which can be easily
incorporated into their formulation as convex-concave constraints. Experiments
on synthetic as well as real world datasets show that our methodology is
effective at avoiding disparate mistreatment, often at a small cost in terms of
accuracy.Comment: To appear in Proceedings of the 26th International World Wide Web
Conference (WWW), 2017. Code available at:
https://github.com/mbilalzafar/fair-classificatio
Impacts of hydrophilic nanofillers on separation performance of thin film nanocomposite reverse osmosis membrane
The membrane technology is still considered a costly method to produce potable water. In view of this, RO membrane with enhanced water permeability without trade-off in salt rejection is desirable as it could further reduce the cost for water desalination. In this study, thin film nanocomposite (TFN) membranes containing 0.05 or 0.10 w/v% hydrophilic nanofillers in polyamide layer were synthesized via interfacial polymerization of piperazine and trimesoyl chloride monomers. The resultant TFN membranes were characterized and compared with a control thin film composite (TFC) membrane. Results from the filtration experiments showed that TFN membranes exhibited higher water permeability, salt rejection and fouling resistance compared to that of the TFC membrane. Excessive amount of nanofillers incorporated in the membrane PA layer however negatively affected the cross-linking in the polymer matrix, thus deteriorating the membrane salt rejection. TFN membrane containing 0.05 w/v% of nanofillers showed better performances than the TFC membrane, recording a pure water flux of 11.2 L/m2∙he membsalt rejection of 95.4%, 97.3% and 97.5% against NaCl, Na2SO4 and MgSO4, respectively
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