Interaction-range effects and universality in the BCS-BEC crossover of spin-orbit-coupled Fermi gases

We explore the evolution of an ultracold quantum gas of interacting fermions crossing from a Bardeen-Cooper-Schrieffer (BCS) superfluidity to a Bose-Einstein condensation (BEC) of molecular bosons in the presence of a tunable-range interaction among the fermions and of an artificial magnetic field, which can be used to simulate a pseudo-spin-orbit coupling (SOC) and to produce topological states. We find that the crossover is affected by a competition between the finite range of the interaction and the SOC and that the threshold λB for the topological transition is affected by the interactions only in the small pair size, BEC-like, regime. Below λB, we find persistence of universal behavior in the critical temperature, chemical potential, and condensate fraction, provided that the pair correlation length is used as a driving parameter. Above threshold, universality is lost in the regime of large pair sizes. Here, the limiting ground state departs from a weakly interacting BCS-like one so that a different description is required. Our results can be relevant in view of current experiments with cold atoms in optical cavities, where tunable-range effective atomic interactions can be engineered

Factors affectingwater drainage long-time series in the salinized low-lying coastal area of Ravenna (Italy)

The low-lying coastal area of Ravenna (North-eastern Italy), like the majority of delta and coastal zones around the world, is affected by groundwater salinization due to natural processes (such as low topography, natural land subsidence, seawater encroachment along estuaries, etc.) and anthropogenic activities (i.e., increased anthropogenic subsidence rate, sea level rise, geofluids extraction, and drainage). Among all factors causing aquifer salinization, water drainage plays an important role in lowering the hydraulic head and favouring saltwater seepage in the Ravenna coastal aquifer. A network of drainage canals and water pumping stations first allowed for the reclamation of the low-lying territory and today are fundamental to keep land and infrastructures dry and maintain effective soil depth for agriculture practices. The aim of this work is to identify and assess factors affecting water drainage long-time series (1971-2017) of the most important mechanical drainage basin in this low-lying coastal area. Statistical analyses of drainage, climate, and land use change datasets help constrain the relative weight of each single factor potentially causing an increase of water drainage through time. The results show that, among these factors, subsidence rates and seepage processes are the most significant. The data trends also indicate that the climate, especially in terms of precipitation amount and extreme events, played no important role during the studied time interval. The process of infiltration soil capacity loss due to urbanization and consequent soil sealing probably has a small secondary effect. Moreover, an increase in pumping through time will exacerbate aquifer salinization and compromise freshwater availability in the coastal area

Evolution of salinity and water table level of the phreatic coastal aquifer of the Emilia Romagna region (Italy)

The coastal aquifers of the Mediterranean region are highly susceptible to seawater intrusion due to a combination of challenges such as land subsidence, high aquifer permeability, urbanization, drainage, and an unsustainable use of water during the dry summer months. The present study is focused on a statistical analysis of groundwater data to evaluate the spatial changes of water level and electrical conductivity in the coastal phreatic aquifer of the Emilia-Romagna (Northeast Italy) for the period from 2009 to 2018. Data from 35 wells distributed across the entire regional coastal area are used to establish a temporal trend, as well as correlations between salinity, water table level, and rainfall. Water table and salinity distribution maps for the entire study area are discussed regarding surface geology and water management. Most of the wells are in the beach wedge sand unit, which allows for easy connectivity between groundwater and surface water. Surface water and groundwater salinization are enhanced along the surface water bodies connected to the sea. The lowest water table level occurs in the western and northern parts of the study area, because of the semiconfined behavior of the aquifer. Only in the northernmost, close to the Po River, and in the southernmost parts of the study area does the groundwater remain fresh for the whole period considered due to river aquifer recharge. In the rest of the region, the thickness of freshwater lenses, where present, is less than 4.5 m. The existence of a water table level below sea level and high saline water at the bottom of the aquifer in most of the study area suggest that the aquifer is in unstable hydrodynamic conditions and groundwater quality is not fit for human consumption or for irrigation. This study is the first to provide a regional overview of the state of groundwater level and salinization within the coastal aquifer of the Emilia-Romagna Region; it also suggests that, overall, the salinization trend has slightly decreased from 2009 to 2018

Potentially Toxic Elements (PTEs) Distribution in Drainage Canal Sediments of a Low-Lying Coastal Area

This study examines the accumulation, distribution, and mobility of Potentially Toxic Elements (PTEs) in the sediments of a low-lying coastal drainage network (Ravenna, Italy). The aim is to understand the geochemical processes occurring between drainage water and canal bed sediments and assess factors affecting and driving PTE distribution and enrichment in these environments. A geochemical database resulting from the analysis of 203 drainage sediment samples was analyzed using Principal Component Analysis and compared to undisturbed near-surface sediment samples from the same depth and depositional environment. The results reveal PTEs exceeding national regulation limits. Distance from the sea, electrical conductivity of drainage water, and fertilizer use were identified as the main driving factors. The primary mechanisms for PTE precipitation (As, Co, Mo) and subsequent enrichment in the sediments is attributed to the absorption on Fe- and Mn-oxyhydroxides (HFO and HMO), particularly in high salinity areas near the coast. While Cu, Zn, Pb, Cr, and V also have affinity for HFO and HMO, their adsorption efficiency decreases due to the competition with salt-derived cations during ongoing salinization processes. Anthropogenic sources, including agriculture, hunting activities, traffic dust, and railways, contribute to the local abundance of other elements (Cr, Ni, Cu, Zn, Pb, and Sn). This paper's significant progress lies in assessing the concurrent interactions of chemical and physical processes that drive PTE distribution and accumulation in reclaimed low-lying coastal plains. The findings are significant for assessing PTE accumulation risks and sediment toxicity in coastal areas affected by water salinization, drainage, and subsidence, providing valuable information to water management institutions globally.This study investigates the presence of harmful substances called Potentially Toxic Elements (PTEs) in the sediment of the drainage canals in Ravenna's coastal area (Northern Italy). Researchers want to understand how these substances accumulate and spread in the sediment and what factors influence their distribution. They collected sediment samples from the bottom of the drainage canals and compared them to natural sediment samples. The results show that the PTE levels exceed the national and international limits. The distance from the sea, the water salinity, and the fertilizers are found to be the main factors affecting the distribution of PTEs. The researchers also discover that some PTEs (Arsenic, Cobalt, and Molybdenum) are absorbed by certain minerals in the sediment, especially in areas with high salinity close to the coast. However, other harmful elements, like copper, zinc, lead, chromium, and vanadium are not as strongly absorbed due to competition with salt-related substances. The abundance of other elements like chromium, nickel, copper, zinc, lead, and tin come from human activities like agriculture, hunting, traffic, and railways. These findings are important for understanding the risks associated with these substances in the sediment, particularly in low-lying coastal areas that have been reclaimed for human use.First study on Potentially Toxic Elements (PTEs) enrichment in drainage canal sediments of reclaimed low-lying coastal area Key roles of (i) Fe- and Mn-oxyhydroxides in PTE enrichments and (ii) salt-derived cations in adsorption efficiency Distance from the sea, salinity of drainage water, and use of fertilizers are the main factors affecting the distribution and enrichment of PTE

An Evaluation of Immersive Infographics for News Reporting: Quantifying the Effect of Mobile AR Concrete Scales Infographics on Volume Understanding

Augmented Reality (AR) allows us to represent information in the user's own environment and, therefore, convey a visceral feeling of its true physical scale. Journalists increasingly leverage this opportunity through immersive infographics, an extension of conventional infographics reliant on familiar references to convey volumes, heights, weights, and sizes. Our goal is to measure the contribution of immersive mobile AR concrete scales infographics to the user's understanding of the information scale. We focus on infographics powered by tablet-based mobile AR, given its current much more widespread use for news consumption compared to headset-based AR. We designed and implemented a study apparatus containing three alternative representation methods (textual analogies, image infographic, and AR infographic) for three different pieces of news with different characteristics and scales. In a controlled user study, we asked 26 participants to represent the expected volume of the information in the real world with the help of an AR mobile application. We also compared their subjective feelings when interacting with the different representations. While both image and AR infographics led to significantly better comprehension than textual analogies alone across different kinds of news, AR infographics led, on average, to a 31.8% smaller volume estimation error than static ones. Our findings indicate that mobile AR concrete scales infographics can contribute to news reporting by increasing readers' abilities to comprehend volume information

Structural control on carbon emissions at the Nirano mud volcanoes – Italy

The Nirano Salse in Italy is a well-studied site where natural gas seepage (NGS) and other hydrocarbon fluids and gases are emitted at the earth's surface. A novel integrated approach is applied to define a comprehensive structural interpretation of the gas seepage and flow dynamic in the mud volcano system of the Nirano Salse Regional Nature Reserve (Modena, Northern Apennines). The paper investigates the relationship between gas emissions and local structures, particularly faults and fractures, in the shallow subsurface (down to 500–600 m depth) to understand the control that structures have on fluid ascent from deep leaky hydrocarbon traps. We performed continuous monitoring of mud levels within vents; carried out geological surveys to characterize the main stratigraphic and structural discontinuities; measured the carbon emissions (CH4 and CO2) seepage both from volcanoes and the surrounding soil by a portable gas fluxmeter; and integrated the results with available geophysical surveys. The authors argue that the transgressive Pleistocene-Pliocene Argille Azzurre Formation hides the complex and highly structured pre-Pliocene geology of the area, in which faults and fractures act as pathways for deep fluid ascent. The emissions are aligned along a NE-SW trend at the intersection of a NE-SW fracture system and NW-SE-oriented normal faults, which are both associated to the local tensional stress field of a likely left-lateral strike-slip transfer structure or in the extrados of a fold. By examining both natural gas macroseepage and diffuse flux, it is shown that local structures control the fluid ascent and contribute to the emission of hydrocarbon gases and fluids at the Earth's surface. Understanding the structural control of carbon emissions at the Nirano Salse is also important for evaluating the carbon budget at the site, particularly in areas where there are detectable surface emissions. The study has implications for geologic, environmental, and economic issues, including hydrocarbon exploration, hazard assessment, and impact on the atmospheric carbon budget. Furthermore, the outcomes have an important implication to evaluate the potential for dangerous abrupt mud eruptions, and the site safety in proximity to the mud volcanoes

Dune belt restoration effectiveness assessed by UAV topographic surveys (northern Adriatic coast, Italy)

Unoccupied aerial vehicle (UAV) monitoring surveys are used to assess a dune restoration project in the protected natural area of the Bevano River mouth on the northern Adriatic coast (Ravenna, Italy). The impacts of the installed fences to aid dune development are quantified in terms of sand volume and vegetation cover changes over 5 years using a systematic data processing workflow based on structure-from-motion (SfM) photogrammetry and the Geomorphic Change Detection (GCD) toolset applied to two drone surveys in 2016 and 2021. Accuracy assessment is performed using statistical analysis between ground-truth and model elevation data. Results show that the fence proves to be effective in promoting recovery and growth since significant sand deposition was observed along the dune foot and front – a total area of 3799 m2, volume of 1109 m3, and average depositional depth of 0.29 m. Progradation of around 3–5 m of the foredune and embryo development were also evident. There was a decrease in blowout features of about 155 m2 due to increased deposition and vegetation colonization. There was also an average percent increase of 160 % on wave-induced driftwood and/or debris along the beach and of 9.6 % vegetation within the fence based on the cover analysis on selected transects. Erosion of around 1439 m2 is apparent mostly at the northern portion of the structure, which could be accounted for by the aerodynamic and morphodynamic conditions around the fence and its configuration to trap sediments and efficiency in doing so. Overall, dune fencing coupled with limiting debris cleaning along the protected coast was effective. The proposed workflow can aid in creating transferable guidelines to stakeholders in integrated coastal zone management (ICZM) implementation on Mediterranean low-lying sandy coasts

Assessment of seasonal changes in water chemistry of the ridracoli water reservoir (Italy): Implications for water management

The Ridracoli artificial basin is the main water reservoir of the Emilia-Romagna region (Northeast Italy). The reservoir was made by construction of a dam on the Bidente River in 1982. It is used as the main drinking water supply of the region and for hydropower production. The physical and chemical parameterseters (temperature, pH, electrical conductivity, and dissolved oxygen) of shallow water are continuously monitored whereas vertical depth profiles of water chemical data (major anions and cations, as well as heavy metals) are available on a bimonthly base. The dataset used in this research is related to the years 2015 and 2016. Data show that the reservoir is affected by an alternation of water stratification and mixing processes due to seasonal change in water temperature, density, and the reservoir water level. In late summer and winter months, the water column is stratified with anoxic conditions at the bottom. During the spring, on the other hand, when storage is at its maximum, water recirculation and mixing occur. The reservoir is characterized by a dynamic system in which precipitation, dissolution, and adsorption processes at the bottom affect water quality along the reservoir depth column. The temperature stratification and anoxic conditions at the reservoir bottom influence the concentration and mobility of some heavy metals (i.e., Fe and Mn) and, consequently, the quality of water that reaches the treatment and purification plant. This study is relevant for water resource management of the reservoir. Assessing the seasonal changes in water quality along the reservoir water column depth is fundamental to plan water treatment operations and optimize their costs. The reservoir assessment allows one to identify countermeasures to avoid or overcome the high concentrations of heavy metals and the stratification problem (i.e., artificial mixing of the water column, new water intakes at different depths operating at different times of the year, blowers, etc.)

Driving and limiting factors of CH4 and CO2 emissions from coastal brackish-water wetlands in temperate regions

Coastal wetlands play a fundamental role in mitigating climate change thanks to their ability to store large amounts of organic carbon in the soil. However, degraded freshwater wetlands are also known to be the first natural emitter of methane (CH4). Salinity is known to inhibit CH4 production, but its effect in brackish ecosystems is still poorly understood. This study provides a contribution to understanding how environmental variables may affect greenhouse gas (GHG) emissions in coastal temperate wetlands. We present the results of over 1 year of measurements performed in four wetlands located along a salinity gradient on the northeast Adriatic coast near Ravenna, Italy. Soil properties were determined by coring soil samples, while carbon dioxide (CO2) and CH4 fluxes from soils and standing waters were monitored monthly by a portable gas flux meter. Additionally, water levels and surface and groundwater physical–chemical parameters (temperature, pH, electrical conductivity, and sulfate concentrations of water) were monitored monthly by multiparametric probes. We observed a substantial reduction in CH4 emissions when water depth exceeded the critical threshold of 50 cm. Regardless of the water salinity value, the mean CH4 flux was 5.04 g m−2 d−1 in freshwater systems and 12.27  g m−2 d−1 in brackish ones. In contrast, when water depth was shallower than 50 cm, CH4 fluxes reached an average of 196.98  g m−2 d−1 in freshwater systems, while non-significant results are available for brackish/saline waters. Results obtained for CO2 fluxes showed the same behavior described for CH4 fluxes, even though they were statistically non-significant. Temperature and irradiance strongly influenced CH4 emissions from water and soil, resulting in higher rates during summer and spring

Temperature-Dependent Nitrous Oxide/Carbon Dioxide Preferential Adsorption in a Thiazolium-Functionalized NU-1000 Metal-Organic Framework

Solvent-assisted ligand incorporation (SALI) of the ditopic linker 5-carboxy-3-(4-carboxybenzyl)thiazolium bromide [(H2PhTz)Br] into the zirconium metal-organic framework NU-1000 [Zr6O4(OH)8(H2O)4(TBAPy)2, where NU = Northwestern University and H4TBAPy = 1,3,6,8-tetrakis(p-benzoic-acid)pyrene], led to the SALIed NU-1000-PhTz material of minimal formula [Zr6O4(OH)6(H2O)2(TBAPy)2(PhTz)]Br. NU-1000-PhTz has been thoroughly characterized in the solid state. As confirmed by powder X-ray diffraction, this material keeps the same three-dimensional architecture of NU-1000 and the dicarboxylic extra linker bridges adjacent [Zr6] nodes ca. 8 Å far apart along the crystallographic c-axis. The functionalized MOF has a BET specific surface area of 1560 m2/g, and it is featured by a slightly higher thermal stability than its parent material (Tdec = 820 vs. 800 K, respectively). NU-1000-PhTz has been exploited for the capture and separation of two pollutant gases: carbon dioxide (CO2) and nitrous oxide (N2O). The high thermodynamic affinity for both gases [isosteric heat of adsorption (Qst) = 25 and 27 kJ mol-1 for CO2 and N2O, respectively] reasonably stems from the strong interactions between these (polar) "stick-like"molecules and the ionic framework. Intriguingly, NU-1000-PhTz shows an unprecedented temperature-dependent adsorption capacity, loading more N2O in the 298 K ≤ T ≤ 313 K range but more CO2 at temperatures falling out of this range. Grand canonical Monte Carlo simulations of the adsorption isotherms confirmed that the preferential adsorption sites of both gases are the triangular channels (micropores) in close proximity to the polar pillar. While CO2 interacts with the thiazolium ring in an "end-on"fashion through its O atoms, N2O adopts a "side-on"configuration through its three atoms simultaneously. These findings open new horizons in the discovery of functional materials that may discriminate between polluting gases through selective adsorption at different temperatures