Geochemical Characterization of Groundwater in the Confined and Unconfined Aquifers of the Northern Italy

Having an accurate and easily accessible geochemical database is crucial for a correct groundwater management. Here, for the first time in Italy, chemico-physical data of groundwater collected by different Environmental Protection Agencies during the 2018 were integrated into a single database to assess the geochemical status of a wide and complex aquifer system. Data were assembled, reformatted, corrected, homogenized, and then grouped according to the aquifer type (phreatic, semi-confined, and confined) and the sampling seasons. A total of 3671 validated samples were classified into hydrochemical facies; inorganic N compounds and trace elements were also evaluated. The water were classified mainly as Ca-HCO3 and Ca-Mg-HCO3 (90%); locally, Na-HCO3, Mg-HCO3, Ca-SO4, Na-Cl, and Ca-Cl types were detected. In the phreatic aquifers, NO3 contamination and high concentrations of Na+, K+, and NH4+ were found and linked to anthropogenic sources, such as agricultural and livestock activities. Along the Adriatic coast, Na-Cl water confirmed saltwater intrusion phenomena. Landward, evaporitic rocks dissolution, and the upconing of relict marine water explained high EC, Na+, K+, Cl-, and SO42- concentrations. The dissolution of Fe-Mn oxide-hydroxides coupled with organic carbon oxidation under reducing environment justified high NH4+, Fe, Mn, and As recorded in the semi-confined and confined aquifers

Characterization of the lowland coastal aquifer of Comacchio (Ferrara, Italy): Hydrology, hydrochemistry and evolution of the system

This study delineates the actual hydrogeochemistry and the geological evolution of an unconfined coastal aquifer located in a lowland setting in order to understand the drivers of the groundwater salinization. Physical aquifer parameterization highlights a vertical hydraulic gradient due to the presence of a heavy drainage system, which controls the hydrodynamics of this coastal area, forcing groundwater to flow from the bottom toward the top of the aquifer. As a consequence, relict seawater in stable density stratification, preserved within low permeability sediments in the deepest portion of the aquifer, has been drawn upward. The hydrogeochemical investigations allow identifying the role of seepage and water-sediment interactions in the aquifer salinization process and in the modification of groundwater chemistry. Mixing between freshwater and saltwater occurs; however, it is neither the only nor the dominant process driving groundwater hydrochemistry. In the aquifer several concurring and competing water-sediment interactions - as NaCl solution, ion-exchange, calcite and dolomite dissolution/precipitation, oxidation of organic matter, and sulfate bacterial reduction - are triggered by or overlap freshwater-saltwater mixing The hyper-salinity found in the deepest portion of the aquifer cannot be associated with present seawater intrusion, but suggests the presence of salt water of marine origin, which was trapped in the inter-basin during the Holocene transgression. The results of this study contribute to a better understanding of groundwater dynamics and salinization processes in this lowland coastal aquifer. © 2013 Elsevier B.V

Mud flow dynamics at gas seeps - Nirano Salse, Italy

The Nirano Salse, known since the Roman Times, are one of the most beautiful and scenic mud volcanoes areas of Italy with thousands of visitors every year. In this work, we apply novel (for the context) hydrogeological techniques to characterize mud levels in the Salse by means of GPS-RTK positioning and continuous level logging within mud conduits. This is important to quantify the gas-liquid ratio in the conduits and evaluate the potential for dangerous abrupt mud eruptions. The results presented suggest that different mud levels in mud volcanoes clusters are due to the different gas-liquid ratio in the conduits and not necessarily exclude interconnection at depth, a hypothesis, on the other hand, that seems strengthened by mud level time series correlations. The presence of shallow aquifers at a depth of 5 to 30 m is also supported by our field data and allows us to delineate the boundaries of the shallow mud reservoir-pipes system and its overall shape. The shallow aquifers may provide a temporary storage for the ascending gas and when fluid pressure in these aquifers exceeds the tensional strength of the sedimentary rock, leakage of fluids to the surface would occur. In this case, if the gas-liquid ratio is high, mud volcanoes develop into tall gryphons and tend to have a discontinuous activity with sudden eruptions of mud after long periods of quiescence. This, together with the knowledge of shallow conduits localization has an important implication for site safety in proximity to the mud volcanoes. Our inferences based on mud level relationships to mud extrusion dynamics can be applied to lower risk in other mud volcanoes areas of the world with high geo-tourist visits, such as those of Trinidad, Azerbaijan, and Colombia

Dulcificação (freshening) de águas subterrâneas seguindo o avanço costeiro e recuperação de terras da Planície do Pó, Itália

Many coastal areas historically were inundated by seawater, but have since undergone land reclamation to enable settlements and farming. This study focuses on the coastal unconfined aquifer in the Po Plain near Ravenna, Italy. Freshwater is present as isolated thin (1–5 m) lenses on top of brackish to saline water. Historical maps show large areas of sea inundation until approximately 150–200 years ago when coastal progradation and construction of the drainage canals began. Since then, the aquifer has been freshening from recharge. A three-dimensional SEAWAT model is used to simulate a 200-year freshening history, starting with a model domain that is saturated with seawater, and applying recharge across the top model layer. Calibration to the observed concentrations for discrete depths within many monitoring wells is remarkably good. The current distribution of freshwater is largely controlled by the drainage network. Within and adjacent to the drains, the groundwater has high salinity due to up-coning of salt water. Between drains, the surface layers of the aquifer are fresh due to the flushing action of recharge. The modeling results are consistent with cation exchange processes revealed in the groundwater chemistry and with freshwater lenses identified in electrical resistivity soundings. © 2015 Springer-Verlag Berlin Heidelber