Local electromagnetic properties of magnetic pnictides: A comparative study probed by NMR measurement

75As and 31P NMR studies are performed in PrCoAsO and NdCoPO respectively. The Knight shift data in PrCoAsO indicate the presence of an antiferromagnetic interaction between the 4f moments along the c axis in the ferromagnetic state of Co 3d moments. We propose a possible spin structure in this system. The 75As quadrupolar coupling constant, $\nu_Q$ increases continuously with the decrease of temperature and is found to vary linearly with the intrinsic spin susceptibility, Kiso. This indicates a possibility of the presence of a coupling between charge density and spin density fluctuations. Further, 31P NMR Knight shift and spin lattice relaxation rate (1/T1) in the paramagnetic state of NdCoPO indicate that the differences between LaCoPO and NdCoPO with SmCoPO are due to the decrement of inter layer separation and not due to the moments of 4f electrons. Nuclear spin lattice relaxation time (T1) in NdCoPO shows weak anisotropy at 300 K. Using self consistent renormalization (SCR)theory of itinerant ferromagnet, it is shown that in the ab plane, the spin fluctuations are three dimensional ferromagnetic in nature. From SCR theory the important spin fluctuation parameters ($T_0$, $T_A$, $\bar{F}_1$) are evaluated. The similarities and dissimilarities of the NMR results in As and P based systems, with different rare earths have also been discussed.Comment: 18 pages,13 figures, accepted for publication in J. Phys. Condens. Matte

Study of electron spin dynamics in grain aligned LaCoPO: an itinerant ferromagnet

139La NMR study was performed in grain aligned (c|| H0) sample of LaCoPO and polycrystalline LaFePO. Knight shift is isotropic and temperature independent in LaFePO. It is strongly temperature dependent and anisotropic in LaCoPO. The spin-lattice relaxation rate in LaCoPO clearly reveals the existence of 3D spin fluctuations both in the paramagnetic and ferromagnetic state over and above the dominant 2D spin fluctuations in the paramagnetic state, observed earlier from 31P NMR measurements in the same oriented sample. The spin fluctuation parameters in LaCoPO determined from 139La NMR relaxation and magnetization data, using the self consistent renormalization (SCR) theory, are in close agreement and follow the universal Rhodes-Wohlfarth curve.Comment: Accepted in PR

Long-range and short-range magnetic correlations, and microscopic origin of net magnetization in the spin-1 trimer chain compound CaNi3P4O14

Spin-spin correlations and microscopic origin of net magnetization in the spin-1 trimer chain compound CaNi3P4O14 have been investigated by powder neutron diffraction. The present study reveals a 3D long-range magnetic ordering below 16 K where the magnetic structure consists of ferromagnetic trimers that are coupled ferromagnetically along the spin-chain. The moment components along the a and c axes arrange antiferromagnetically. Our study establishes that the uncompensated moment components along the b axis result in a net magnetization per unit cell. The magnetic structure, determined in the present study, is in agreement with the results of recent first principles calculation; however, it is in contrast to a fascinating experimental prediction of ferrimagnetic ordering based on the periodicity of the exchange interactions in CaNi3P4O14. Our study also confirms the presence of broad diffuse magnetic scattering, due to 1D short-range spin-spin correlations, over a wide temperature range below ~50 K down to a temperature well below the Tc. Total neutron scattering analysis by the RMC method reveals that the dominating spin-spin correlation above Tc is ferromagnetic and along the b axis. The nearest neighbour spin-spin correlations along the a and c axes are found to be weakly antiferromagnetic. The nature of the trimer spin structure of the short-range state is similar to that of the 3D long-range ordered state. The present investigation of microscopic nature of the magnetic ground state also explains the condition required for the 1/3 magnetization plateau to be observed in the trimer spin-chains. In spite of the S=1 trimer chain system, the present compound CaNi3P4O14 is found to be a good realization of 3D magnet below the Tc=16 K with full ordered moment values of ~2 mu_B/Ni2+ (1.98 and 1.96 mu_B/Ni2+ for two Ni sites, respectively) at 1.5 K.Comment: 10 pages, 8 figure

Crossover of the dimensionality of 3d spin fluctuations in LaCoPO

dc magnetization and 31^P spin lattice relaxation rate in the polycrystalline sample of LaCoPO suggest a spin fluctuation dominated ferromagnetically ordered state. Moreover, NMR data clearly indicate a crossover from 2D to 3D spin fluctuations across T_C. In contrast to isotropic hyperfine field, H_hf at the 31^P site in LaFePO, H_hf is anisotropic in LaCoPO. The data of spin lattice relaxation rate also exhibit anisotropic spin fluctuation. The anisotropy vanishes near T_C

Interaction effects of region-level GDP per capita and age on labour market transition rates in Italy

Abstract The aim of this paper is to measure the effect of the interaction between age for the population of males and females aged 18 to 74 and region-level GDP per capita on labour market transition probabilities in Italy. We compare different occupational states in a sample of males and females who remained in their region of residence at two points in time (12 months apart). We estimate the transition probabilities using a flexible hierarchical logit model with interaction effects between worker age and region-level GDP per capita. We apply this model using longitudinal data from the Italian Labour Force Survey that cover the 2004–2013 period. We find empirical support for the assumption that people in the same age cohort have different labour market opportunities based on the level of GDP per capita in their region of residence. These differences are particularly relevant among younger workers

The long-run behaviour of the terms of trade between primary commodities and manufactures : a panel data approach

This paper examines the Prebisch and Singer hypothesis using a panel of twenty-four commodity prices from 1900 to 2010. The modelling approach stems from the need to meet two key concerns: (i) the presence of cross-sectional dependence among commodity prices; and (ii) the identification of potential structural breaks. To address these concerns, the Hadri and Rao (Oxf Bull Econ Stat 70:245–269, 2008) test is employed. The findings suggest that all commodity prices exhibit a structural break whose location differs across series, and that support for the Prebisch and Singer hypothesis is mixed. Once the breaks are removed from the underlying series, the persistence of commodity price shocks is shorter than that obtained in other studies using alternative methodologies.info:eu-repo/semantics/publishedVersio