The Effect of SEBS/Halloysite Masterbatch Obtained in Different Extrusion Conditions on the Properties of Hybrid Polypropylene/Glass Fiber Composites for Auto Parts

Masterbatches from a linear poly[styrene-b-(ethylene-co-butylene)-b-styrene] (SEBS) and halloysite nanotubes (HNT-QM) were obtained in different conditions of temperature and shear using two co-rotating twin-screw extruders. The influence of screw configuration and melt processing conditions on the morpho-structural, thermal and mechanical properties of masterbatches at macro and nanoscale was studied. A good dispersion of halloysite nanotubes and better thermal stability and tensile and nanomechanical properties were obtained at a lower temperature profile and higher screw speed. The effect of masterbatches, the best and worst alternatives, on the properties of a polypropylene (PP)–glass fiber (GF) composite was also evaluated. Double hardness, tensile strength and modulus and four times higher impact strength were obtained for PP/GF composites containing masterbatches compared to pristine PP. However, the masterbatch with the best properties led further to enhanced mechanical properties of the PP/GF composite. A clear difference between the effects of the two masterbatches was obtained by nanoindentation and nanoscratch tests. These analyses proved to be useful for the design of polymer composites for automotive parts, such as bumpers or door panels. This study demonstrated that setting-up the correct processing conditions is very important to obtain the desired properties for automotive applications

Performance analysis of slope and frequency modulated carrier PWM methods for grid connected converters

A detailed analysis of two Pulse-Width Modulation (PWM) methods is performed in this paper for grid connected converters. The considered methods are: sinusoidal carrier regulated by the slope of a trapezoidal waveform PWM (SLPWM) and frequency modulated triangular carrier PWM (HIPWM-FMTC). The analysis of the two PWM methods is realized with four performance indicators: standard and weighted total harmonic distortion (THD and WTHD), fulfillment of the grid connection requirements and minimum pulse width. The results are compared with those obtained for the Space Vector Modulation (SVPWM) and Selective Harmonic Elimination PWM (SHE-PWM). Experimental results are presented for a 1 kVA inverter prototype to validate the paper conclusions

Room Temperature Ferromagnetic Mn:Ge(001)

We report the synthesis of a room temperature ferromagnetic Mn-Ge system obtained by simple deposition of manganese on Ge(001), heated at relatively high temperature (starting with 250 °C). The samples were characterized by low energy electron diffraction (LEED), scanning tunneling microscopy (STM), high resolution transmission electron microscopy (HRTEM), X-ray photoelectron spectroscopy (XPS), superconducting quantum interference device (SQUID), and magneto-optical Kerr effect (MOKE). Samples deposited at relatively elevated temperature (350 °C) exhibited the formation of ~5–8 nm diameter Mn5Ge3 and Mn11Ge8 agglomerates by HRTEM, while XPS identified at least two Mn-containing phases: the agglomerates, together with a Ge-rich MnGe~2.5 phase, or manganese diluted into the Ge(001) crystal. LEED revealed the persistence of long range order after a relatively high amount of Mn (100 nm) deposited on the single crystal substrate. STM probed the existence of dimer rows on the surface, slightly elongated as compared with Ge–Ge dimers on Ge(001). The films exhibited a clear ferromagnetism at room temperature, opening the possibility of forming a magnetic phase behind a nearly ideally terminated Ge surface, which could find applications in integration of magnetic functionalities on semiconductor bases. SQUID probed the co-existence of a superparamagnetic phase, with one phase which may be attributed to a diluted magnetic semiconductor. The hypothesis that the room temperature ferromagnetic phase might be the one with manganese diluted into the Ge crystal is formulated and discussed

The Nanomechanical and Tribological Properties of Polyamide/Hydrotalcite Nanocomposites

In specific fields of the industry (e.g., aircraft and automotive industry), plastic materials with high performance (improved scratch resistance, fire resistance, thermal stability, and high mechanical properties) are required. [...