Out of plane effect on the superconductivity of Sr2-xBaxCuO3+d with Tc up to 98K

We comment on the paper published by W.B. Gao, Q.Q. Liu, L.X. Yang, Y.Yu, F.Y. Li, C.Q. Jin and S. Uchida in Phys. Rev. B 80, 094523 (2009) and give alternate explanations for the enhanced superconductivity. The enhanced onset Tc of 98K observed upon substituting Ba for Sr is attributed to optimal oxygen ordering rather than to the increase in volume. Comparison with La2CuO(4+x) samples suggest that the effect of disorder is overestimated

The Interstellar Medium of IRAS 08572+3915 NW: H3+ and Warm High Velocity CO

We confirm the first detection of the molecular ion H3+ in an extragalactic object, the highly obscured ultraluminous galaxy IRAS 08572+3915 NW. We also have detected absorption lines of the fundamental band of CO in this galaxy. The CO absorption consists of a cold component close to the systemic velocity and warm, highly blueshifted and redshifted components. The warm blueshifted component is remarkably strong and broad and extends at least to -350 km/s. Some analogies can be drawn between the H3+ and cold CO in IRAS08572+3915 NW and the same species seen toward the Galactic center. The profiles of the warm CO components are not those expected from a dusty torus of the type thought to obscure active galactic nuclei. They are probably formed close to the dust continuum surface near the buried and active nucleus and are probably associated with an unusual and energetic event there.Comment: 21 pages, 4 postscript figures, accepted by Ap

Seasonal Variability In The Ionosphere Of Uranus

Infrared ground-based observations using IRTF, UKIRT, and Keck II of Uranus have been analyzed as to identify the long-term behavior of the H-3(+) ionosphere. Between 1992 and 2008 there are 11 individual observing runs, each recording emission from the H-3(+) Q branch emission around 4 mu m through the telluric L' atmospheric window. The column-averaged rotational H-3(+) temperature ranges between 715 K in 1992 and 534 K in 2008, with the linear fit to all the run-averaged temperatures decreasing by 8 K year(-1). The temperature follows the fractional illumination curve of the planet, declining from solstice (1985) to equinox (2007). Variations in H-3(+) column density do not appear to be correlated to either solar cycle phase or season. The radiative cooling by H-3(+) is similar to 10 times larger than the ultraviolet solar energy being injected to the atmosphere. Despite the fact that the solar flux alone is incapable of heating the atmosphere to the observed temperatures, the geometry with respect to the Sun remains an important driver in determining the thermospheric temperature. Therefore, the energy source that heats the thermosphere must be linked to solar mechanisms. We suggest that this may be in the form of conductivity created by solar ionization of atmospheric neutrals and/or seasonally dependent magnetospherically driven current systems.STFC PP/E/000983/1, ST/G0022223/1RCUKGemini ObservatoryNational Aeronautics and Space Administration (NASA) NXX08A043G, NNX08AE38AAstronom

Overdoped Cuprates With High Temperature Superconducting Transitions

Evidence for High Tc cuprate superconductivity is found in a region of the phase diagram where non-superconducting Fermi liquid metals are expected. Cu valences estimated independently from both x-ray absorption near-edge structure (XANES) and bond valence sum (BVS) measurements are > 2.3 for structures in the homologous series (Cu0.75Mo0.25)Sr2(Y,Ce)sCu2O5+2s+{\delta} with s = 1, 2, 3, and 4. The s = 1 member, (Cu0.75Mo0.25)Sr2YCu2O7+{\delta}, 0 \leq {\delta} \leq 0.5, is structurally related to YBa2Cu3O7 in which 25% of the basal Cu cations [i.e. those in the chain layer] are replaced by Mo, and the Ba cations are replaced by Sr. After oxidation under high pressure the s = 1 member becomes superconducting with Tc = 88K. The Cu valence is estimated to be ~2.5, well beyond the ~2.3 value for which other High-Tc cuprates are considered to be overdoped Fermi liquids. The increase in valence is attributed to the additional 0.5 oxygen ions added per chain upon oxidation. The record short apical oxygen distance, at odds with current theory, suggests the possibility of a new pairing mechanism but further experiments are urgently needed to obtain more direct evidence. From the structural point of view the members with s \geq 2 are considered to be equivalent to single-layer cuprates. All have Tc ~ 56 K which is significantly higher than expected because they also have higher than expected Cu valences. The XANES-determined valences normalized to give values in the CuO2 layers are 2.24, 2.25, and 2.26 for s = 2, 3, and 4, while the BVS values determined for the valence in the CuO2 layer alone are 2.31-2.34 for the s = 2 and 3 members. No evidence for periodic ordering has been detected by electron diffraction and high resolution imaging studies. The possibility that the charge reservoir layers are able to screen long range coulomb interactions and thus enhance Tc is discussed

Absorption Line Survey of H3+ toward the Galactic Center Sources III. Extent of the Warm and Diffuse Clouds

We present follow-up observations to those of Geballe & Oka (2010), who found high column densities of H3+ ~100 pc off of the Galactic center (GC) on the lines of sight to 2MASS J17432173-2951430 (J1743) and 2MASS J17470898-2829561 (J1747). The wavelength coverages on these sightlines have been extended in order to observe two key transitions of H3+, R(3,3)l and R(2,2)l, that constrain the temperatures and densities of the environments. The profiles of the H3+ R(3,3)l line, which is due only to gas in the GC, closely matches the differences between the H3+ R(1,1)l and CO line profiles, just as it does for previously studied sightlines in the GC. Absorption in the R(2,2)l line of H3+ is present in J1747 at velocities between -60 and +100 km/s. This is the second clear detection of this line in the interstellar medium after GCIRS 3 in the Central Cluster. The temperature of the absorbing gas in this velocity range is 350 K, significantly warmer than in the diffuse clouds in other parts of the Central Molecular Zone. This indicates that the absorbing gas is local to Sgr B molecular cloud complex. The warm and diffuse gas revealed by Oka et al. (2005) apparently extends to ~100 pc, but there is a hint that its temperature is somewhat lower in the line of sight to J1743 than elsewhere in the GC. The observation of H3+ toward J1747 is compared with the recent Herschel observation of H2O+ toward Sgr B2 and their chemical relationship and remarkably similar velocity profiles are discussed.Comment: 6 pages, 3 figures, 2 tables, Accepted for publication in Publications of the Astronomical Society of Japa

Fundamental Vibrational Transitions of HCl Detected in CRL 2136

We would like to understand the chemistry of dense clouds and their hot cores more quantitatively by obtaining more complete knowledge of the chemical species present in them. We have obtained high-resolution infrared absorption spectroscopy at 3-4 um toward the bright infrared source CRL 2136. The fundamental vibration-rotation band of HCl has been detected within a dense cloud for the first time. The HCl is probably located in the warm compact circumstellar envelope or disk of CRL 2136. The fractional abundance of HCl is (4.9-8.7)e-8, indicating that approximately 20 % of the elemental chlorine is in gaseous HCl. The kinetic temperature of the absorbing gas is 250 K, half the value determined from infrared spectroscopy of 13CO and water. The percentage of chlorine in HCl is approximately that expected for gas at this temperature. The reason for the difference in temperatures between the various molecular species is unknown.Comment: 6 pages, 3 figures, A&A in pres

Detection of vibrational emissions from the helium hydride ion (HeH+^+) in the planetary nebula NGC 7027

We report the detection of emission in the v=1-0 P(1) (3.51629 micron) and P(2) (3.60776 micron) rovibrational lines of the helium hydride cation (HeH+) from the planetary nebula NGC 7027. These detections were obtained with the iSHELL spectrograph on NASA's Infrared Telescope Facility (IRTF) on Maunakea. The confirm the discovery of HeH+ reported recently by Guesten et al. (2019), who used the GREAT instrument on the SOFIA airborne observatory to observe its pure rotational J=1-0 transition at 149.137 micron. The flux measured for the HeH+ v=1-0 P(1) line is in good agreement with our model for the formation, destruction and excitation of HeH+ in NGC 7027. The measured strength of the J=1-0 pure rotational line, however, exceeds the model prediction significantly, as does that of the v=1-0 P(2) line, by factors of 2.9 and 2.3 respectively. Possible causes of these discrepancies are discussed. Our observations of NGC 7027, covering the 3.26 - 3.93 micron spectral region, have led to the detection of more than sixty spectral lines including nine rovibrational emissions from CH+. The latter are detected for the first time in an astronomical source.Comment: 49 pages, including 17 figures. Accepted for publication in Ap