Entanglement in finite spin rings with noncollinear Ising interaction

We investigate the entanglement properties of finite spin rings, with noncollinear Ising interaction between nearest neighbours. The orientations of the Ising axes are determined either by the spin position within the ring (model A) or by the direction of the bond (model B). In both cases, the considered spin Hamiltonians have a point group symmetry, rather than a translation invariance, as in spin rings with collinear Ising interaction. The ground state of these models exhibit remarkable entanglement properties, resembling GHZ-like states in the absence of an applied magnetic field (model B). Besides, the application of an homogeneous magnetic field allows to modify qualitatively the character of the ground state entanglement, switching from multipartite to pairwise quantum correlations (both models A and B)

Towards the chemical tuning of entanglement in molecular nanomagnets

Antiferromagnetic spin rings represent prototypical realizations of highly correlated, low-dimensional systems. Here we theoretically show how the introduction of magnetic defects by controlled chemical substitutions results in a strong spatial modulation of spin-pair entanglement within each ring. Entanglement between local degrees of freedom (individual spins) and collective ones (total ring spins) are shown to coexist in exchange-coupled ring dimers, as can be deduced from general symmetry arguments. We verify the persistence of these features at finite temperatures, and discuss them in terms of experimentally accessible observables.Comment: 5 pages, 4 figure

Mechanisms of decoherence in weakly anisotropic molecular magnets

Decoherence mechanisms in crystals of weakly anisotropic magnetic molecules, such as V15, are studied. We show that an important decohering factor is the rapid thermal fluctuation of dipolar interactions between magnetic molecules. A model is proposed to describe the influence of this source of decoherence. Based on the exact solution of this model, we show that at relatively high temperatures, about 0.5 K, the quantum coherence in a V15 molecule is not suppressed, and, in principle, can be detected experimentally. Therefore, these molecules may be suitable prototype systems for study of physical processes taking place in quantum computers.Comment: 4 pages RevTeX, 1 figure (PostScript

Spin-Electric Coupling in Molecular Magnets

We study the triangular antiferromagnet Cu$_3$ in external electric fields, using symmetry group arguments and a Hubbard model approach. We identify a spin-electric coupling caused by an interplay between spin exchange, spin-orbit interaction, and the chirality of the underlying spin texture of the molecular magnet. This coupling allows for the electric control of the spin (qubit) states, e.g. by using an STM tip or a microwave cavity. We propose an experimental test for identifying molecular magnets exhibiting spin-electric effects.Comment: 5 pages, 3 figure

Spin electric effects in molecular antiferromagnets

Molecular nanomagnets show clear signatures of coherent behavior and have a wide variety of effective low-energy spin Hamiltonians suitable for encoding qubits and implementing spin-based quantum information processing. At the nanoscale, the preferred mechanism for control of quantum systems is through application of electric fields, which are strong, can be locally applied, and rapidly switched. In this work, we provide the theoretical tools for the search for single molecule magnets suitable for electric control. By group-theoretical symmetry analysis we find that the spin-electric coupling in triangular molecules is governed by the modification of the exchange interaction, and is possible even in the absence of spin-orbit coupling. In pentagonal molecules the spin-electric coupling can exist only in the presence of spin-orbit interaction. This kind of coupling is allowed for both $s=1/2$ and $s=3/2$ spins at the magnetic centers. Within the Hubbard model, we find a relation between the spin-electric coupling and the properties of the chemical bonds in a molecule, suggesting that the best candidates for strong spin-electric coupling are molecules with nearly degenerate bond orbitals. We also investigate the possible experimental signatures of spin-electric coupling in nuclear magnetic resonance and electron spin resonance spectroscopy, as well as in the thermodynamic measurements of magnetization, electric polarization, and specific heat of the molecules.Comment: 31 pages, 24 figure

Spin-wave analysis of the transverse-field Ising model on the checkerboard lattice

The ground state properties of the S=1/2 transverse-field Ising model on the checkerboard lattice are studied using linear spin wave theory. We consider the general case of different couplings between nearest neighbors (J1) and next-to-nearest neighbors (J2). In zero field the system displays a large degeneracy of the ground state, which is exponential in the system size (for J1=J2) or in the system's linear dimensions (for J2>J1). Quantum fluctuations induced by a transverse field are found to be unable to lift this degeneracy in favor of a classically ordered state at the harmonic level. This remarkable fact suggests that a quantum-disordered ground state can be instead promoted when non-linear fluctuations are accounted for, in agreement with existing results for the isotropic case J1=J2. Moreover spin-wave theory shows sizable regions of instability which are further candidates for quantum-disordered behavior.Comment: 12 pages, 13 figure

Endocytoscopic imaging and tattooing: a caveat

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Fast quantum noise in Landau-Zener transition

We show by direct calculation starting from a microscopic model that the two-state system with time-dependent energy levels in the presence of fast quantum noise obeys the master equation. The solution of master equation is found analytically and analyzed in a broad range of parameters. The fast transverse noise affects the transition probability during much longer time (the accumulation time) than the longitudinal one. The action of the fast longitudinal noise is restricted by the shorter Landau-Zener time, the same as in the regular Landau-Zener process. The large ratio of time scales allows solving the Landau-Zener problem with longitudinal noise only, then solving the same problem with the transverse noise only and matching the two solutions. The correlation of the longitudinal and transverse noise renormalizes the Landau-Zener transition matrix element and can strongly enhance the survival probability, whereas the transverse noise always reduces it. Both longitudinal and transverse noise reduce the coherence. The decoherence time is inverse proportional to the noise intensity. If the noise is fast, its intensity at which the multi-quantum processes become essential corresponds to a deeply adiabatic regime. We briefly discuss possible applications of the general theory to the problem of the qubit decoherence and to the spin relaxation of molecular magnets.Comment: 12 pages, 8 figure

Proton NMR for Measuring Quantum-Level Crossing in the Magnetic Molecular Ring Fe10

The proton nuclear spin-lattice relaxation rate 1/T1 has been measured as a function of temperature and magnetic field (up to 15 T) in the molecular magnetic ring Fe10. Striking enhancement of 1/T1 is observed around magnetic field values corresponding to a crossing between the ground state and the excited states of the molecule. We propose that this is due to a cross-relaxation effect between the nuclear Zeeman reservoir and the reservoir of the Zeeman levels of the molecule. This effect provides a powerful tool to investigate quantum dynamical phenomena at level crossing.Comment: Four pages, to appear in Phys.Rev.Let