The use of Planetary Nebulae precursors in the study of Diffuse Interstellar Bands

We present the first results of a systematic search for Diffuse Interstellar Bands in a carefully selected sample of post-AGB stars observed with high resolution optical spectroscopy. These stars are shown to be ideal targets to study this old, intriguing astrophysical problem. Our results suggest that the carrier(s) of these bands may not be present in the circumstellar environments of these evolved stars. The implications of the results obtained on the identification of the still unknown carrier(s) are discussed.Comment: 4 pages, 2 figures, proceedings of the conference 'Planetary Nebulae as Astrophysical Tools', held in Gdansk, Poland (June 28 - July 2, 2005

Spectroscopy of the post-AGB star HD 101584(IRAS 11385-5517)

From an analysis of the spectrum (4000\AA to 8800\AA) of HD~101584 it is found that most of the neutral and single ionized metallic lines are in emission. The forbidden emission lines of [OI] 6300\AA and 6363\AA and [CI] 8727\AA are detected, which indicate the presence of a very low excitation nebula. The H$\alpha$, FeII 6383\AA, NaI D$_{1}$, D$_{2}$ lines and the CaII IR triplet lines show P-Cygni profiles indicating a mass outflow. The H$\alpha$ line shows many velocity components in the profile. The FeII 6383\AA also has almost the same line profile as the H$\alpha$ line indicating that they are formed in the same region. From the spectrum synthesis analysis we find the atmospheric parameters to be T$_{eff}$=8500K, log g=1.5, V$_{turb}$=13km~s$^{-1}$ and [Fe/H]=0.0. From an analysis of the absorption lines the photospheric abundances of some of the elements are derived. Carbon and nitrogen are found to be overabundant. From the analysis of Fe emission lines we derived T$_{exi}$=6100K$\pm$200 for the emission line region.Comment: To appear in A&A, 15 pages, 11 figure

Why are massive O-rich AGB stars in our Galaxy not S-stars?

We present the main results derived from a chemical analysis carried out on a large sample of galactic O-rich AGB stars using high resolution optical spectroscopy (R~40,000-50,000) with the intention of studying their lithium abundances and/or possible s-process element enrichment. Our chemical analysis shows that some stars are lithium overabundant while others are not. The observed lithium overabundances are interpreted as a clear signature of the activation of the so-called ``Hot Bottom Burning'' (HBB) process in massive galactic O-rich AGB stars, as predicted by the models. However, these stars do not show the zirconium enhancement (taken as a representative for the s-process element enrichment) associated to the third dredge-up phase following thermal pulses. Our results suggest that the more massive O-rich AGB stars in our Galaxy behave differently from those in the Magellanic Clouds, which are both Li- and s-process-rich (S-type stars). Reasons for this unexpected result are discussed. We conclude that metallicity is probably the main responsible for the differences observed and suggest that it may play a more important role than generally assumed in the chemical evolution of AGB stars.Comment: 4 pages, 2 figures, to appear in the proceedings of the conference "Planetary Nebulae as astronomical tools" held in Gdansk, Poland, jun 28/jul 02, 200

Infrared Study of Fullerene Planetary Nebulae

We present a study of 16 PNe where fullerenes have been detected in their Spitzer spectra. This large sample of objects offers an unique opportunity to test conditions of fullerene formation and survival under different metallicity environments as we are analyzing five sources in our own Galaxy, four in the LMC, and seven in the SMC. Among the 16 PNe under study, we present the first detection of C60 (possibly also C70) fullerenes in the PN M 1-60 as well as of the unusual 6.6, 9.8, and 20 um features (possible planar C24) in the PN K 3-54. Although selection effects in the original samples of PNe observed with Spitzer may play a potentially significant role in the statistics, we find that the detection rate of fullerenes in C-rich PNe increases with decreasing metallicity (5% in the Galaxy, 20% in the LMC, and 44% in the SMC). CLOUDY photoionization modeling matches the observed IR fluxes with central stars that display a rather narrow range in effective temperature (30,000-45,000 K), suggesting a common evolutionary status of the objects and similar fullerene formation conditions. The observed C60 intensity ratios in the Galactic sources confirm our previous finding in the MCs that the fullerene emission is not excited by the UV radiation from the central star. CLOUDY models also show that line- and wind-blanketed model atmospheres can explain many of the observed [NeIII]/[NeII] ratios by photoionization suggesting that possibly the UV radiation from the central star, and not shocks, are triggering the decomposition of the circumstellar dust grains. With the data at hand, we suggest that the most likely explanation for the formation of fullerenes and graphene precursors in PNe is that these molecular species are built from the photo-chemical processing of a carbonaceous compound with a mixture of aromatic and aliphatic structures similar to that of HAC dust.Comment: Accepted for publication in ApJ (43 pages, 11 figures, and 4 tables). Small changes to fit the proof-corrected article to be published in Ap