Polymorphic phase boundary in piezoelectric oxides

The design of phase boundaries has now become a consolidated strategy to improve the functional properties of piezoelectric oxides because of the unique properties that may be obtained in their vicinity. In particular, polymorphic phase boundaries (PPBs) have attracted significant interest in recent years because they represent a significant breakthrough in terms of enhanced piezoelectric activity of lead-free piezoelectric oxides. PPBs are temperature-driven phase transitions where both intrinsic and extrinsic contributions maximize, thereby enhancing the macroscopic properties of piezoelectric materials. This tutorial discusses potassium–sodium–niobate-based systems as model materials to reveal some of the most relevant advances in the design of PPBs through compositional modifications. We focus on how PPBs can be modulated by engineered doping and also discuss the direct relation between PPBs and the enhancement of piezoelectric activity. Finally, we briefly describe the main experimental techniques for detecting PPBs.Postprint (author's final draft

Neoclassical Growth, Environment and Technological Change: The Environmental Kuznets Curve

The paper investigates socially optimal patterns of economic growth and environmental quality in a neoclassical growth model with endogenous technological progress. In the model, the environmental quality affects positively not only to utility but also to production. However, cleaner technologies can be used in the economy whether a part of the output is used in environmentally oriented R&D. In this framework, if the initial level of capital is low then the shadow price of a cleaner technology is low relative to the cost of developing it given by the marginal utility of consumption and it is not worth investing in R&D. Thus, there will be a first stage of growth based only on the accumulation of capital with a decreasing environmental quality until the moment that pollution is great enough to make profitable the investment in R&D. After this turning point, if the new technologies are efficient enough, the economy can evolve along a balanced growth path with an increasing environmental quality. The result is that the optimal investment pattern supports an environmental Kuznets curve.Neoclassical Growth Model, Endogenous Technological Progress, External Effects, Environmental Kuznets Curve

Assessing Judicial Efficiency of Egyptian First Instance Courts: A DEA Analysis

Egypt started a recent judicial reform program in 2007, which can be considered the first ever since the establishment of the National Egyptian Judicial System in 1952. It focuses mainly on solving organizational problems within First Instance Courts (FIC), as they form the active cell of the Egyptian judicial system. However the efficiency of FICs is still doubtable to a large extent. This paper provides for the first time an efficiency analysis of 22 FICs in Egypt using the technique of Data Envelop Analysis (DEA). The main strength of this study is to consider the number of computers per court, as none of the previous papers on court efficiency has included a capital variable when defining their court production function before. Our results show that there are no significant differences observed in terms of management efficiency between the civil and criminal FICs, however criminal FICs districts are superior with respect to their corresponding civil districts in terms of program efficiency.Egyptian Judicial System; Efficiency; Data envelopment analysis

HCO3- enrichment causes cytosolic NO3- efflux in Posidonia oceanica leaf cells

Posidonia oceanica is a seagrass, the only group of vascular plants to colonize the marine environment. Seawater is an extreme yet stable environment, characterized by high salinity, alkaline pH and low availability of essential nutrients, such as nitrate or phosphate. In addition, in aquatic environments the supply of CO2 for the photosynthesis is limited by diffusion and therefore many aquatic plants use HCO3- as the inorganic carbon source for photosynthesis. Previous results have shown that Na+ -dependent transport systems operate on the plasma membrane of P. oceanica mesophyll leaf cells for the high-affinity NO3-, Pi or amino acids uptake. Also, a direct transport of HCO3- driven by H+ has been found in this species that provides inorganic carbon for photosynthesis and could be a significant component of a carbon concentrating mechanism in this species. Interestingly, this HCO3- direct uptake caused the efflux of chloride from the cytosol, probably through S-type anion channels, pointing that other anions could also be removed from the cytosol. This hypothesis could be relevant in the case of NO3-, since the decrease of cytosolic NO3- in response to HCO3- enrichment could limit N-assimilation. Here we analyse the effect of HCO3- increase on NO3- uptake and cytosolic homeostasis in P. oceanica. Enrichment of natural seawater with 3 mM HCO3- evokes the on-going decrease of cytosolic NO3-, from 5.7 ± 0.2 to 4.8 ± 0.7 mM after 40 min of treatment. The incubation of P. oceanica leaf pieces in 3 mM HCO3- NSW causes an initial increase of NO3- concentration in the medium. Maximum efflux (21 nmol NO3- gFM-1 min-1) occurs within the first minute of incubation. Then, external NO3- is depleted from the medium at lower net uptake rate than the value observed in non HCO3- -enriched natural seawater. These results fit the hypothesis that HCO3- enrichment causes the nitrogen loose and could impair nitrogen assimilation promoting N biomass impoverishment.Universidad de Málaga. Campus de Excelencia Internacional Andalucía Tech. Spanish MINECO, projects BFU2017-85117-R and BIO2016-81957-RED

Na+-dependent NO3- uptake in leaf cells of the seagrass Posidonia oceanica (L.) Delile

Posidonia oceanica (L.) Delile is an endemic Mediterranean seagrass of recognized ecological significance and, as other seagrasses, this species has secondarily adapted to live in the marine environment. In this alkaline medium with a high Na+ concentration (0.5 M), the high inwardly directed electrochemical potential gradient for sodium is used in the seagrass Zostera marina to energize the uptake of nitrate1 and phosphate that usually occur at concentration below 10 µM. Here we summarize several evidences for the operation of a sodium-dependent high-affinity nitrate transport system at the plasma membrane of the mesophyll leaf cells of P. oceanica. Leaf cells of P. oceanica possess a H+-ATPase as a primary pump, exhibit a plasma membrane potential (Em) of -174 ± 10 mV and show reduced Na+ permeability. The addition of micromolar nitrate concentrations induces membrane depolarizations that show saturation kinetics. Curve fitting of the values renders a semisaturation constant (Km) of 21.3 ± 6.6 μM and a maximum depolarization (Dmax) of 7 ± 1 mV. In dark conditions, Dmax decreases by fifty percent but no significant effect is observed on the Km value. On the other hand, nitrate induced depolarizations show sodium dependence. The depolarizations induced by 100 µM NO3- in media containing increasing Na+ concentrations (from 0 to 250 mM) show saturation kinetics, rendering a Km value of 16 ± 5 mM Na+. Moreover, the depolarization induced by 100 µM NO3- is accompanied by a simultaneous increase of cytosolic sodium, measured by Na+-sensitive microelectrodes, of 0.4 ± 0.2 mM above the resting cytosolic sodium concentration (17 ± 2 mM). Finally, nitrate uptake rates, measured in depletion experiments, decreases by 50% and 80% in dark conditions and in the absence of Na+, respectively, compared with control conditions (0.5 M Na+ and light). All together, these results strongly suggest that NO3- uptake in P. oceanica leaf cells is mediated by a high-affinity nitrate carrier that uses Na+ as the driving ion. 1 Rubio et al. (2005). J. Exp. Bot, 412: 613-622. Project Funding: CTM 2011-30356. (MEC)Universidad de Málaga. Campus de Excelencia Internacional Andalucía Tech

Symmetry reduction induced by anyon condensation: a tensor network approach

Topological ordered phases are related to changes in the properties of their quasi-particle excitations (anyons). We study these relations in the framework of projected entanglement pair states (\textsf{PEPS}) and show how condensing and confining anyons reduces a local gauge symmetry to a global on-site symmetry. We also study the action of this global symmetry over the quasiparticle excitations. As a byproduct, we observe that this symmetry reduction effect can be applied to one-dimensional systems as well, and brings about appealing physical interpretations on the classification of phases with symmetries using matrix product states (\textsf{MPS}). The case of $\mathbb{Z}_2$ on-site symmetry is studied in detail.Comment: 21+5 pages, 15+3 figures. Introduction and conclusions enlarged, references and figure added, minor typos corrected, appendix about dyons adde

Effect of elevated inorganic carbon on the cytosolic homeostasis of NO3- in the marine angiosperm Posidonia oceanica (L.) Delile

The marine angiosperm Posidonia oceanica is a mediterranean endemism of great ecological significance. As other marine plants, P. oceanica has adapted secondarily to the marine environment and develop anew different mechanisms to colonize it. Among others, this plant has developed a plasma membrane system for the direct uptake of bicarbonate. In this work we have developed both NO3- and Cl- selective microelectrodes for the continuous monitoring of the intracellular (cytosolic) NO3- and Cl-. In the light, leaf mesophyll cells show a cytosolic NO3- concentration of 5.7±0.2 mM (n=10), while in the dark cytosolic NO3- raises up to 8.7±1.1 mM; these values are in the range of concentrations quoted for Arabidopsis thaliana (Cookson et al., 2005). The enrichment of natural seawater (NSW) with 3 mM NaHCO3 caused a decrease of the cytosolic NO3- concentration of 1 mM and a decrease of the cytosolic concentration of Cl- of 3.5 mM. The saturation of NSW with 1000 µL CO2 L-1 produced a lower diminution of the cytosolic NO3- (0.3 mM). In the presence of 0.1 mM of the plasma membrane permeable inhibitor of the carbonic anhydrase (EZ) the diminution of cytosolic NO3- caused by the same concentration of CO2 was much lower, 0.1 mM. The addition of inorganic carbon, either HCO3- or CO2, has an effect on the cytosolic mechanisms for anionic homeostasis, one of which is the opening of the slow anion channels. These channels are permeable to NO3- and Cl- and could elicit the efflux of these ions. In P. oceanica, the response in the presence of EZ points out that the inorganic carbon species that cause the NO3-/Cl- efflux is HCO3-. This effect could contribute to plant biomass N dilution observed in elevated CO2. References: Cookson et al. 2005. Plant Physiology 138, 1097–1105.Universidad de Málaga. Campus de Excelencia Internacional Andalucía Tec

Bringing Optical Communications to the General Public: an Innovative Bachelor Thesis

The United Nations “International year of light 2015” strives to highlight the importance of optical technologies in our everyday lives. Fibre optic communication is one such technology: the growth of internet and its associated services are enabled by the vast transmission bandwidth provided by optical networks. However, the general public is not well aware of the optical and electronic fundamentals of the underlying transmission systems. Here we present the development of a bachelor thesis in Telecommunication Engineering in which a small-scale fibre-optic link is built and the electronics required to transmit music over this link are implemented. The resulting system demonstrates, in a very intuitive way, how information is transmitted over an optical fibre.Universidad de Málaga. Campus de Excelencia Internacional Andalucía Tech