Thermodynamic and economic investigation of a screw expander-based direct steam generation solar cascade Rankine cycle system using water as thermal storage fluid

Solar electricity generation system (SEGS) which employs cascade steam-organic Rankine cycle (SORC) and steam screw expander (SE) is promising due to the high efficiency at moderate heat source temperature. This paper puts a special emphasis on heat storage and thermo-economic evaluation. Preferable operating temperature of the system is first clarified on the basis of SE characteristics. The temperature-dependent permissible stress of steam accumulator is modelled and the capital cost is investigated. Comparison between the direct steam generation (DSG) SEGS and an indirect one using thermal oil is made at a power capacity of 1 MW and storage of 6.5 h. The results indicate the DSG system has both thermodynamic and economic superiorities. The hot side temperature (THTH) of SORC generally does not exceed 250 °C to achieve an optimum solar thermal power efficiency. Given radiation of 750 W/m2, the maximum efficiency (ηT,mηT,m) is 14.3% with a corresponding THTH around 240 °C. The material cost of pressure vessels is 2.55 million RMB. For the indirect system, the optimal THTH is about 230 °C and ηT,mηT,m approximates to 13.2% and the estimated oil cost is 7.92 million RMB. It is recommended to adopt steam accumulators in the SE-driven SEGS

The study of a seasonal solar cchp system based on evacuated flat-plate collectors and organic rankine cycle

The demands of cooling, heating and electricity in residential buildings are varied with seasons. This article presented a seasonal solar combined cooling heating and power (CCHP) system based on evacuated flat-plate collectors and organic Rankine cycle. The heat collected by evacuated flat-plate collectors is used to drive the organic Rankine cycle unit in spring, autumn and winter, and drive the double-effect lithium bromide absorption chiller in summer. The organic Rankine cycle condensation heat is used to yield hot water in spring and autumn, whereas supply heating in winter. The system thermodynamic performance was analyzed. The results show that the system thermal efficiency in spring, autumn and winter, ηsys, I, increases as organic Rankine cycle evaporation temperature, T6, and evacuated flat-plate collectors outlet temperature, T2, decrease. The maximum ηsys, I of 67.0% is achieved when T6 = 80 °C and T2 =100 °C. In summer, the system thermal efficiency, ηsys, II, increases first and then decreases with the increment of T2. The maximum ηsys, II of 69.9% is obtained at T2 =136 °C. The system output performance in Beijing and Lanzhou is better than that in Hefei. The average output power, heating capacity, hot water and cooling capacity are 50-72 kWh per day, 989-1514 kWh per day, 49-57 ton per day and 1812-2311 kWh per day, respectively. The system exergy efficiency increases from 17.8-40.8% after integrating the organic Rankine cycle unit

High performance thermosets with tailored properties derived from methacrylated eugenol and epoxy-based vinyl ester

A renewable chemical, eugenol, is methacrylated to produce methacrylated eugenol (ME) employing the Steglich esterification reaction without any solvent. The resulting ME is used as a low viscosity comonomer to replace styrene in a commercial epoxy-based vinyl ester resin (VE). The volatility and viscosity of ME and styrene are compared. The effect of ME loadings and temperatures on viscosity of the VE-ME resin is investigated. Moreover, the thermo-mechanical properties, curing extent, and thermal stability of the fully cured VE-ME thermosets are systematically examined. The results indicate that ME is a monomer with low volatility and low viscosity, and therefore the incorporation of ME monomer in VE resins allows significant reduction of viscosity. Moreover, viscosity of the VE-ME resin can be tailored by adjusting ME loadings and processing temperature to meet commercial liquid molding technology requirements. The glass transition temperatures of VE-ME thermosets range from 139 to 199 °C. In addition, more than 95% of the monomer is incorporated and fixed in the crosslinked network structure of VE-ME thermosets. Overall, the developed ME monomer exhibits promising potential to replace styrene as an effective low viscosity comonomer. The VE-ME resins show great advantages for use in polymer matrices for high performance fiber-reinforced composites. This work showed great significance to the vinyl ester industry by providing detailed experimental support

A novel approach to thermal storage of direct steam generation solar power systems through two-step heat discharge

© 2018 Elsevier Ltd Steam accumulators are the only commercial solution for heat storage of direct steam generation (DSG) solar thermal power plants. Current accumulators have low storage capacity as the turbine suffers from inefficient off-design operation during heat discharge, thereby restricting the development of DSG technology. This work presents a novel approach to solving this problem by using two-stage accumulators and steam-organic Rankine cycles (RC-ORC). The system involves unique two-step heat discharge. Heat is initially released via water vaporization in a high temperature accumulator (HTA) to drive the RC-ORC, leading to an HTA temperature drop of approximately 30 °C. Water at a reduced temperature then flows from the HTA to a low temperature accumulator through a heat exchanger and the heat is used only to drive the ORC. Water temperature further drops by 130–190 °C. The fundamentals of the system are illustrated. A comparison with the conventional DSG system is conducted at a nominal power of 10 MW with an accumulator volume of 2500 m3. Thermodynamic performance of the system is investigated. The equivalent payback period (EPP) regarding the use of the second step heat discharge is estimated. Results indicate that the second step heat discharge can increase the storage capacity by 460%, with an EPP of less than 5 years in most cases. Overall, the proposed solution improves the cost-effectiveness of the DSG system

Inhibition of Aldose Reductase Activates Hepatic Peroxisome Proliferator-Activated Receptor-α and Ameliorates Hepatosteatosis in Diabetic db/db Mice

We previously demonstrated in streptozotocin-induced diabetic mice that deficiency or inhibition of aldose reductase (AR) caused significant dephosphorylation of hepatic transcriptional factor PPARα, leading to its activation and significant reductions in serum lipid levels. Herein, we report that inhibition of AR by zopolrestat or by a short-hairpin RNA (shRNA) against AR caused a significant reduction in serum and hepatic triglycerides levels in 10-week old diabetic db/db mice. Meanwhile, hyperglycemia-induced phosphorylation of hepatic ERK1/2 and PPARα was significantly attenuated in db/db mice treated with zopolrestat or AR shRNA. Further, in comparison with the untreated db/db mice, the hepatic mRNA expression of Aco and ApoA5, two target genes for PPARα, was increased by 93% (P < 0.05) and 73% (P < 0.05) in zopolrestat-treated mice, respectively. Together, these data indicate that inhibition of AR might lead to significant amelioration in hyperglycemia-induced dyslipidemia and nonalcoholic fatty liver disease

Experimental study of organic Rankine cycle in the presence of non-condensable gases

Non-condensable gases (NCGs) are inevitable in organic Rankine cycle (ORC) system, and they have adverse impacts. A small-scale ORC test platform using scroll expander and R123 was constructed to investigate the NCGs effect. The expander backpressure (i.e. condenser outlet pressure) and electricity output were examined on different conditions of NCGs mass fraction (xNCG), hot side temperature (Th) and condensation temperature (Tc). Two new parameters, namely reduced coefficient of pressure ratio (RCOPR) and filling ratio of reservoir (FROR), were proposed to reveal the mechanism of ORC performance degradation in the presence of NCGs. The results show that the partial pressure of NCGs (PNCG) in reservoir at work differed from that at static state. Unlike R123, NCGs were blocked by the reservoir and had no access to the pump. The accumulation of NCGs led to unexpected expander backpressure, which could be 0.68 bar higher than the saturation pressure when Th = 140 °C, Tc = 50 °C and xNCG = 1.3%. PNCG generally increased as FROR rose. The FROR changed with Th, Tc and R123 mass flow rate. The relative increment in electricity output of the ORC with xNCG = 1.3% over that with xNCG = 12% was significant, and could reach 114% when Th = 100 °C and Tc = 50 °C

Evaluate the validity of the empirical correlations of clearance and friction coefficients to improve a scroll expander semi-empirical model

This study presents a scroll expander modelling methodology for small scale power generation systems by combining scroll geometry and semi-empirical model. Although the semi-empirical model is quite popular, its dependence on several experimentally-determined scroll geometrical and operational parameters makes this approach inflexible for different capacities and operating conditions. Some studies have sought to improve its flexibility in terms of using different working fluids and more accurate empirical parameters, however, those improved models still depend on a considerable number of experimentally-obtained scroll parameters. Therefore, in this study, a practical methodology for a simpler semi-empirical model combined with the operational flexibility of the scroll geometry is presented. Firstly, the flow rates of mainstream and leakage flows are analysed, where a correlation between scroll clearance and pressure ratio is determined. Secondly, a simpler approach to the semi-empirical model of scroll expander is proposed, whereby dependent parameters have been reduced to two parameters by using scroll geometrical calculations. The model is further improved to predict the rotational speed and electricity output by considering the overall friction coefficient of the coupled expander-generator unit. The findings are then compared with the results of an experimental study. The results show that the effective clearance values between scrolls vary according to pressure ratios, increasing from to . Mass flow rate can be predicted within 10% deviation from the experimental results for the same inlet conditions and rotational speed at a transient state. Additionally, considering steady state conditions, modelling results show that the rotational speed and electricity output can also be predicted within 8% and 7.5% of deviation, respectively

Parallelism and non-parallelism in diabetic nephropathy and diabetic retinopathy

Diabetic nephropathy (DN) and diabetic retinopathy (DR), as microvascular complications of diabetes mellitus, are currently the leading causes of end-stage renal disease (ESRD) and blindness, respectively, in the adult working population, and they are major public health problems with social and economic burdens. The parallelism between the two in the process of occurrence and development manifests in the high overlap of disease-causing risk factors and pathogenesis, high rates of comorbidity, mutually predictive effects, and partial concordance in the clinical use of medications. However, since the two organs, the eye and the kidney, have their unique internal environment and physiological processes, each with specific influencing molecules, and the target organs have non-parallelism due to different pathological changes and responses to various influencing factors, this article provides an overview of the parallelism and non-parallelism between DN and DR to further recognize the commonalities and differences between the two diseases and provide references for early diagnosis, clinical guidance on the use of medication, and the development of new drugs