Double dynamical regime of confined water

The Van Hove self correlation function of water confined in a silica pore is calculated from Molecular Dynamics trajectories upon supercooling. At long time in the $\alpha$ relaxation region we found that the behaviour of the real space time dependent correlators can be decomposed in a very slow, almost frozen, dynamics due to the bound water close to the substrate and a faster dynamics of the free water which resides far from the confining surface. For free water we confirm the evidences of an approach to a crossover mode coupling transition, previously found in Q space. In the short time region we found that the two dynamical regimes are overimposed and cannot be distinguished. This shows that the interplay between the slower and the faster dynamics emerges in going from early times to the $\alpha$ relaxation region, where a layer analysis of the dynamical properties can be performed.Comment: 6 pages with 9 figures. RevTeX. Accepted for pulbication in J. Phys. Cond. Mat

The relaxation dynamics of a simple glass former confined in a pore

We use molecular dynamics computer simulations to investigate the relaxation dynamics of a binary Lennard-Jones liquid confined in a narrow pore. We find that the average dynamics is strongly influenced by the confinement in that time correlation functions are much more stretched than in the bulk. By investigating the dynamics of the particles as a function of their distance from the wall, we can show that this stretching is due to a strong dependence of the relaxation time on this distance, i.e. that the dynamics is spatially very heterogeneous. In particular we find that the typical relaxation time of the particles close to the wall is orders of magnitude larger than the one of particles in the center of the pore.Comment: 9 pages of Latex, 4 figure

Spectral estimates of solar radiation intercepted by corn canopies

Reflectance factor data were acquired with a Landsat band radiometer throughout two growing seasons for corn (Zea mays L.) canopies differing in planting dates, populations, and soil types. Agronomic data collected included leaf area index (LAI), biomass, development stage, and final grain yields. The spectral variable, greenness, was associated with 78 percent of the variation in LAI over all treatments. Single observations of LAI or greenness have limited value in predicting corn yields. The proportions of solar radiation intercepted (SRI) by these canopies were estimated using either measured LAI or greenness. Both SRI estimates, when accumulated over the growing season, accounted for approximately 65 percent of the variation in yields. Models which simulated the daily effects of weather and intercepted solar radiation on growth had the highest correlations to grain yields. This concept of estimating intercepted solar radiation using spectral data represents a viable approach for merging spectral and meteorological data for crop yield models

Discovery of the Narrow-Line Seyfert 1 galaxy Mkn 335 in an historical low X-ray flux state

We report the discovery of the Narrow-Line Seyfert 1 galaxy Mkn 335 in an extremely low X-ray state. A comparison of Swift observations obtained in May and June/July 2007 with all previous X-ray observations between 1971 to 2006 show the AGN to have diminished in flux by a factor of more than 30, the lowest X-ray flux Mkn 335 has ever been observed in. The Swift observations show an extremely hard X-ray spectrum at energies above 2 keV. Possible interpretations include partial covering absorption or X-ray reflection from the disk. In this letter we consider the partial covering interpretation. The Swift observations can be well fit by a strong partial covering absorber with varying absorption column density N_H= 1-4 x 10^{23} cm-2 and a covering fraction f_c=0.9 - 1. When corrected for intrinsic absorption, the X-ray flux of Mkn 335 varies by only factors of 4-6. In the UV Mkn 335 shows variability in the order of 0.2 mag. We discuss the similarity of Mkn 335 with the highly variable NLS1 WPVS007, and speculate about a possible link between NLS1 galaxies and broad-absorption line quasars.Comment: ApJ Letter accepted; 8 pages, 2 figures; The new version has three more sentences in the introduction and three references added to the discussio

Elimination of the chirp of optical pulses through cascaded nonlinearities in periodically poled lithium niobate waveguides

We propose and demonstrate a novel method for the elimination of arbitrary frequency chirp from short optical pulses. The technique is based on the combination of two cascaded second-order nonlinearities in two individual periodically poled lithium niobate waveguides

Liquid-liquid coexistence in the phase diagram of a fluid confined in fractal porous materials

Multicanonical ensemble sampling simulations have been performed to calculate the phase diagram of a Lennard-Jones fluid embedded in a fractal random matrix generated through diffusion limited cluster aggregation. The study of the system at increasing size and constant porosity shows that the results are independent from the matrix realization but not from the size effects. A gas-liquid transition shifted with respect to bulk is found. On growing the size of the system on the high density side of the gas-liquid coexistence curve it appears a second coexistence region between two liquid phases. These two phases are characterized by a different behaviour of the local density inside the interconnected porous structure at the same temperature and chemical potential.Comment: 5 pages, 4 figures. To be published in Europhys. Letter