Intermolecular hydrogen bonding of the two independent molecules of N-3,5-dinitrobenzoyl-L-leucine

The title compound, C₁₃H₁₅N₃O₇, crystallizes as two independent molecules which differ in their conformation. Intermolecular hydrogen bonding between the amide and carboxylic acid groups as N-H...O=C interactions results in the formation of one-dimensional chains with N...O distances of 2.967 (6) and 3.019 (6) Å. Neighbouring chains are linked by C=O...H-O interactions to form a two-dimensional network, with O...O distances of 2.675 (6) and 2.778 (6) Å

Evidence for Partial Taylor Relaxation from Changes in Magnetic Geometry and Energy during a Solar Flare

Solar flares are powered by energy stored in the coronal magnetic field, a portion of which is released when the field reconfigures into a lower energy state. Investigation of sunspot magnetic field topology during flare activity is useful to improve our understanding of flaring processes. Here we investigate the deviation of the non-linear field configuration from that of the linear and potential configurations, and study the free energy available leading up to and after a flare. The evolution of the magnetic field in NOAA region 10953 was examined using data from Hinode/SOT-SP, over a period of 12 hours leading up to and after a GOES B1.0 flare. Previous work on this region found pre- and post-flare changes in photospheric vector magnetic field parameters of flux elements outside the primary sunspot. 3D geometry was thus investigated using potential, linear force-free, and non-linear force-free field extrapolations in order to fully understand the evolution of the field lines. Traced field line geometrical and footpoint orientation differences show that the field does not completely relax to a fully potential or linear force-free state after the flare. Magnetic and free magnetic energies increase significantly ~ 6.5-2.5 hours before the flare by ~ 10^31 erg. After the flare, the non-linear force-free magnetic energy and free magnetic energies decrease but do not return to pre-flare 'quiet' values. The post-flare non-linear force-free field configuration is closer (but not equal) to that of the linear force-free field configuration than a potential one. However, the small degree of similarity suggests that partial Taylor relaxation has occurred over a time scale of ~ 3-4 hours.Comment: Accepted for Publication in Astronomy & Astrophysics. 11 pages, 11 figure

Automated Coronal Hole Identification via Multi-Thermal Intensity Segmentation

Coronal holes (CH) are regions of open magnetic fields that appear as dark areas in the solar corona due to their low density and temperature compared to the surrounding quiet corona. To date, accurate identification and segmentation of CHs has been a difficult task due to their comparable intensity to local quiet Sun regions. Current segmentation methods typically rely on the use of single EUV passband and magnetogram images to extract CH information. Here, the Coronal Hole Identification via Multi-thermal Emission Recognition Algorithm (CHIMERA) is described, which analyses multi-thermal images from the Atmospheric Image Assembly (AIA) onboard the Solar Dynamics Observatory (SDO) to segment coronal hole boundaries by their intensity ratio across three passbands (171 \AA, 193 \AA, and 211 \AA). The algorithm allows accurate extraction of CH boundaries and many of their properties, such as area, position, latitudinal and longitudinal width, and magnetic polarity of segmented CHs. From these properties, a clear linear relationship was identified between the duration of geomagnetic storms and coronal hole areas. CHIMERA can therefore form the basis of more accurate forecasting of the start and duration of geomagnetic storms

Low frequency radio observations of bi-directional electron beams in the solar corona

The radio signature of a shock travelling through the solar corona is known as a type II solar radio burst. In rare cases these bursts can exhibit a fine structure known as `herringbones', which are a direct indicator of particle acceleration occurring at the shock front. However, few studies have been performed on herringbones and the details of the underlying particle acceleration processes are unknown. Here, we use an image processing technique known as the Hough transform to statistically analyse the herringbone fine structure in a radio burst at $\sim$20-90 MHz observed from the Rosse Solar-Terrestrial Observatory on 2011 September 22. We identify 188 individual bursts which are signatures of bi-directional electron beams continuously accelerated to speeds of 0.16$_{-0.10}^{+0.11} c$. This occurs at a shock acceleration site initially at a constant altitude of $\sim$0.6 R$_{\odot}$ in the corona, followed by a shift to $\sim$0.5 R$_{\odot}$. The anti-sunward beams travel a distance of 170$_{-97}^{+174}$ Mm (and possibly further) away from the acceleration site, while those travelling toward the sun come to a stop sooner, reaching a smaller distance of 112$_{-76}^{+84}$ Mm. We show that the stopping distance for the sunward beams may depend on the total number density and the velocity of the beam. Our study concludes that a detailed statistical analysis of herringbone fine structure can provide information on the physical properties of the corona which lead to these relatively rare radio bursts

Methyl 2-[(ferrocenylcarbonyl)amino]thiophene-3-carboxylate

The title compound, [Fe(C₅H₅)(C₁₂H₁₀NO₃S)], was synthesized from ferrocenecarboxylic acid and methyl 2-aminothiophene-3-carboxylate in modest yield. The substituted ring system is essentially planar through the amidothienylcarboxylate moiety, η⁵-(C₅H₄)CONH(C₄H₂S)CO₂Me, with the amido unit at an angle of 3.60 (7)° to the five-atom thienyl group, which is oriented at an angle of 3.17 (7)° to the ester moiety. The primary hydrogen bond is an intramolecular N-H...O=Ccarboxylate interaction [N...O 2.727 (2) Å], and the main intermolecular hydrogen bond involves a thienyl carboxylate and the carboxylate of a symmetry-related molecule [C...O 3.443 (3) Å]

(η5-Cyclopentadienyl)(2-naphthylethynyl)(triphenylphosphine-κP)nickel(II)

The title compound, [Ni(C₅H₅)(C₁₂H₇)(C₁₈H₁₅P)], does not contain strong hydrogen-bond donors or acceptors and the primary interactions are limited to those of the weak C-H...π(arene) type and mainly involving the arene rings

Light as a broad spectrum antimicrobial

Antimicrobial resistance is a significant and growing concern. To continue to treat even simple infections, there is a pressing need for new alternative and complementary approaches to antimicrobial therapy. One possible addition to the current range of treatments is the use of narrow-wavelength light as an antimicrobial, which has been shown to eliminate a range of common pathogens. Much progress has already been made with blue light but the potential of other regions of the electromagnetic spectrum is largely unexplored. In order that the approach can be fully and most effectively realized, further research is also required into the effects of energy dose, the harmful and beneficial impacts of light on eukaryotic tissues, and the role of oxygen in eliciting microbial toxicity. These and other topics are discussed within this perspective