Zero-Valent Iron Nanoparticles for Soil and Groundwater Remediation

Zero-valent iron has been reported as a successful remediation agent for environmental issues, being extensively used in soil and groundwater remediation. The use of zero-valent nanoparticles have been arisen as a highly effective method due to the high specific surface area of zero-valent nanoparticles. Then, the development of nanosized materials in general, and the improvement of the properties of the nano-iron in particular, has facilitated their application in remediation technologies. As the result, highly efficient and versatile nanomaterials have been obtained. Among the possible nanoparticle systems, the reactivity and availability of zero-valent iron nanoparticles (NZVI) have achieved very interesting and promising results make them particularly attractive for the remediation of subsurface contaminants. In fact, a large number of laboratory and pilot studies have reported the high effectiveness of these NZVI-based technologies for the remediation of groundwater and contaminated soils. Although the results are often based on a limited contaminant target, there is a large gap between the amount of contaminants tested with NZVI at the laboratory level and those remediated at the pilot and field level. In this review, the main zero-valent iron nanoparticles and their remediation capacity are summarized, in addition to the pilot and land scale studies reported until date for each kind of nanomaterials.The authors thank administrations that collaborate to carry out this project: HAZITEK (Gobierno Vasco)

Zero-Valent Iron Nanoparticles for Soil and Groundwater Remediation

Zero-valent iron has been reported as a successful remediation agent for environmental issues, being extensively used in soil and groundwater remediation. The use of zero-valent nanoparticles have been arisen as a highly effective method due to the high specific surface area of zero-valent nanoparticles. Then, the development of nanosized materials in general, and the improvement of the properties of the nano-iron in particular, has facilitated their application in remediation technologies. As the result, highly efficient and versatile nanomaterials have been obtained. Among the possible nanoparticle systems, the reactivity and availability of zero-valent iron nanoparticles (NZVI) have achieved very interesting and promising results make them particularly attractive for the remediation of subsurface contaminants. In fact, a large number of laboratory and pilot studies have reported the high effectiveness of these NZVI-based technologies for the remediation of groundwater and contaminated soils. Although the results are often based on a limited contaminant target, there is a large gap between the amount of contaminants tested with NZVI at the laboratory level and those remediated at the pilot and field level. In this review, the main zero-valent iron nanoparticles and their remediation capacity are summarized, in addition to the pilot and land scale studies reported until date for each kind of nanomaterials.The authors thank administrations that collaborate to carry out this project: HAZITEK (Gobierno Vasco)

Development of new remediation technologies for contaminated soils based on the application of zero-valent iron nanoparticles and bioremediation with compost

This study aimed to develop new techniques for the remediation of contaminated soils based on the application of zero-valent iron nanoparticles (nZVI) and bioremediation with compost from organic wastes and a mixed technique of both. An assessment of the effectiveness of remediation in two soils contaminated with hydrocarbons and heavy metals was carried out, with the aim of looking for positive synergies by combining the two techniques, and demonstrating their viability on an industrial scale. The application of nZVI for in situ immobilization of As and Cr in two different soils (Soil I from a contaminated industrial site and Soil II, contaminated artificially) showed a decrease in the concentration of As in Soil I and Soil II, as well as a decrease in Cr concentration for Soil I and Soil II in the leachate of both soils. The addition of compost and nanoparticles under uncontrolled environmental conditions in biopiles was able to produce a decrease in the concentration of aliphatic hydrocarbons of up to 60% in the two soils. Especially, degradation and transformation of longer chains occurred. A significant reduction of ecotoxicity was observed throughout the process in the biopile of soil II, not reaching the LC50 even with 100% of the sample after the treatment, in both earthworm and seeds growth tests. [All rights reserved Elsevier]

Remediación de contaminantes persistentes mediante métodos híbridos

Los capítulos 5 y 6 están sujetos a confidencialidad por la autora. 249 p.El Estudio de la capacidad degradadora de las nanopartículas de hierro cerovalente frente a contaminantes recalcitrantes y difíciles de abordar mediante otras tecnologías como el lindano, de gran problemática a nivel mundial, los HAP, TPH y metales pesados, ha sido abordado en esta tésis mediante el empleo de nuevas formulaciones nanopartícula-polímero y de micropartículas en base hierro. La optimización o personalización de las propiedades de la superficie del nanohierro han servido para promover una mayor reactividad de las nanopartículas frente al lindano en disolución y frente a los HAP en el suelo, bajo unas condiciones específicas. Esta tesis incluye el desarrollo de un estudio a escala piloto en un suelo real contaminado. En este estudio se ha propuesto una nueva tecnología innovadora basada en el uso combinado de nanopartículas de hierro cerovalente y biorremediación en configuración de biopila dinámica para la degradación de contaminantes