Processing eutectics in space

The investigations of directional solidification have indicated the necessity of establishing a secure foundation in earth-based laboratory processing in order to properly assess low-gravity processing. Emphasis was placed on evaluating the regularity of microstructure of the rod-like eutectic Al-Al3Ni obtained under different conditions of growth involving the parameters of thermal gradient, solidification rate, and interfacial curvature. In the case of Al-Al3Ni, where the Al3Ni phase appears as facets rods, solidification rate was determined to be a controlling parameter. Zone melting of thin eutectic films showed that for films of the order of 10 to 20 micrometers thick, the extra surface energy appears to act to stabilize a regular microstructure. The results suggest that the role of low-gravity as provided in space-laboratory processing of materials is to be sought in the possibility of generating a higher thermal gradient in the solidifying ingot for a given power input-output arrangement than can be obtained under normal one-g processes

Processing eutectics in space

Experimental work is reported which was directed toward obtaining interface shape control while a numerical thermal analysis program was being made operational. An experimental system was developed in which the solid-liquid interface in a directionally solidified aluminum-nickel eutectic could be made either concave to the melt or convex to the melt. This experimental system provides control over the solid-liquid interface shape and can be used to study the effect of such control on the microstructure. The SINDA thermal analysis program, obtained from Marshall Space Flight Center, was used to evaluate experimental directional solidification systems for the aluminum-nickel and the aluminum-copper eutectics. This program was applied to a three-dimensional ingot, and was used to calculate the thermal profiles in axisymmetric heat flow. The results show that solid-liquid interface shape control can be attained with physically realizable thermal configurations and the magnitudes of the required thermal inputs were indicated

Processing eutectics in space

Studies which have been done in an earth-based laboratory environment have generally not yielded specimens with the degree of perfection required of the eutectic microstructure to provide test data to evaluate their nonstructural applications. It has been recognized that the low-g environment of an orbiting space laboratory provides a unique environment to re-examine the process of solidification with the goal of producing better microstructures. The objective of this program is to evaluate the feasibility of using the space environment for producing eutectics with microstructures which can be of value on earth. In carrying out this objective, evaluative investigations were carried out on the technology of solidification in a 1-g environment to provide sound baseline data for planning space laboratory experiments

Coatings for graphite fibers

Graphite fibers released from composites during burning or an explosion caused shorting of electrical and electronic equipment. Silicon carbide, silica, silicon nitride and boron nitride were coated on graphite fibers to increase their electrical resistances. Resistances as high as three orders of magnitude higher than uncoated fiber were attained without any significant degradation of the substrate fiber. An organo-silicone approach to produce coated fibers with high electrical resistance was also used. Celion 6000 graphite fibers were coated with an organo-silicone compound, followed by hydrolysis and pyrolysis of the coating to a silica-like material. The shear and flexural strengths of composites made from high electrically resistant fibers were considerably lower than the shear and flexural strengths of composites made from the lower electrically resistant fibers. The lower shear strengths of the composites indicated that the coatings on these fibers were weaker than the coating on the fibers which were pyrolyzed at higher temperature

Study of high resistance inorganic coatings on graphite fibers

Coatings made of boron, silicon carbide, silica, and silica-like materials were studied to determine their ability to increase resistance of graphite fibers. The most promising results were attained by chemical vapor depositing silicon carbide on graphite fiber followed by oxidation, and drawing graphite fiber through ethyl silicate followed by appropriate heat treatments. In the silicon carbide coating studies, no degradation of the graphite fibers was observed and resistance values as high as three orders of magnitude higher than that of the uncoated fiber was attained. The strength of a composite fabricated from the coated fiber had a strength which compared favorably with those of composites prepared from uncoated fiber. For the silica-like coated fiber prepared by drawing the graphite fiber through an ethyl silicate solution followed by heating, coated fiber resistances about an order of magnitude greater than that of the uncoated fiber were attained. Composites prepared using these fibers had flexural strengths comparable with those prepared using uncoated fibers, but the shear strengths were lower

Research study on materials processing in space, M566 experiment

Specimens of the aluminum-33 wt% copper eutectic partially melted and resolidified in the low effective gravity of the orbiting Skylab were examined and characterized with respect to microstructural defects and thermal conductivity values. The results obtained were compared with similar evaluations of ground-based simulation melt-resolidification experiments and as-prepared unidirectionally solidified specimens. Thermal conductivity data and electrical resistivity data at temperatures from 25 C to 400 C did not show significant differences between ground and space processed specimens. A methology of evaluating the defects in the Al-Al2Cu structure was implemented. A specimen from Skylab 3 showed signs of instability in growth and several grains were found in the ingot. The specimen from Skylab 4 did not show such marked instability in growth and was found to contain fewer defects than the ground-processed specimens. This agrees with data from Georgia Institute of Technology which showed that there were fewer defects in both their Skylab 3 and 4 specimens than in ground processed specimens

Developing a risk-informed decision-support system for earthquake early warning at a critical seaport

Earthquake early warning (EEW) systems are used to provide timely alerts on ongoing earthquakes, which can facilitate important risk-mitigation actions before potentially damaging seismic waves reach target sites. A major shortcoming of existing EEW approaches is that the earthquake-related conditions for activating alerts are not generally defined according to a formal decision-support system (DSS) that accounts for possible risk-based consequences of triggering/not triggering the alarm. This paper exploits a next-generation risk-informed EEW DSS, which incorporates Multi-Criteria Decision-Making for evaluating the optimal decision. The proposed DSS integrates engineering-driven loss predictions associated with issuing/not issuing an EEW alert during an event, also considering possible system malfunctions. The DSS is demonstrated for the strategic Gioia Tauro seaport, located in the region of Italy with the highest seismic hazard. Real-time seismic risk analyses are conducted for various earthquake scenarios, accounting for event-parameter uncertainties that are integral to any EEW process and considering the multicomponent nature of the port as a system of interconnected elements. The results of these analyses are used as input to the proposed EEW DSS along with end-user risk preferences, to evaluate the optimal decision in each case and to define a series of risk-informed EEW warning thresholds for the port

Enhanced dielectric response by disordered nanoscale/mesoscopic insulators

Enhancement of the dielectric response of insulators by disorder is theoretically proposed, where the quantum interference of electronic waves through the nanoscale/mesoscopic system and its change due to external perturbations control the polarization. In the disordered case with all the states being localized, the resonant tunneling, which is topologically protected, plays a crucial role, and enhances the dielectric response by a factor 30~40 compared with the pure case. Realization of this idea with accessible materials/structures is also discussed.Comment: 4 pages including 3 figures; minor revision; a high-resolution figure available at http://appi.t.u-tokyo.ac.jp/~sonoda/papers.htm

Resistivity in Co-doped Ba-122: comparison of thin films and single crystals

The temperature dependence of the resistivity of epitaxial Ba(Fe_(1-x)Co_x)2As2 thin films (with nominal doping x = 0.08, 0.10 and 0.15) has been analyzed and compared with analogous measurements on single crystals taken from literature. The rho(T) of thin films looks different from that of single crystals, even when the cobalt content is the same. All rho(T) curves can be fitted by considering an effective two-band model (with holes and electrons bands) in which the electrons are more strongly coupled with the bosons (spin fluctuations) than holes, while the effect of impurities is mainly concentrated in the hole band. Within this model the mediating boson has the same characteristic energy in single crystals and thin films, but the shape of the transport spectral function at low energy has to be very different, leading to a "hardening" of the electron-boson spectral function in thin films, associated with the strain induced by the substrate.Comment: 13 pages, 4 figure

Elastic effects of vacancies in strontium titanate: Short- and long-range strain fields, elastic dipole tensors, and chemical strain

We present a study of the local strain effects associated with vacancy defects in strontium titanate and report the first calculations of elastic dipole tensors and chemical strains for point defects in perovskites. The combination of local and long-range results will enable determination of x-ray scattering signatures that can be compared with experiments. We find that the oxygen vacancy possesses a special property -- a highly anisotropic elastic dipole tensor which almost vanishes upon averaging over all possible defect orientations. Moreover, through direct comparison with experimental measurements of chemical strain, we place constraints on the possible defects present in oxygen-poor strontium titanate and introduce a conjecture regarding the nature of the predominant defect in strontium-poor stoichiometries in samples grown via pulsed laser deposition. Finally, during the review process, we learned of recent experimental data, from strontium titanate films deposited via molecular-beam epitaxy, that show good agreement with our calculated value of the chemical strain associated with strontium vacancies.Comment: 14 pages, 11 figures, 4 table