Computations of Axisymmetric Flows in Hypersonic Shock Tubes

A time-accurate two-dimensional fluid code is used to compute test times in shock tubes operated at supersonic speeds. Unlike previous studies, this investigation resolves the finer temporal details of the shock-tube flow by making use of modern supercomputers and state-of-the-art computational fluid dynamic solution techniques. The code, besides solving the time-dependent fluid equations, also accounts for the finite rate chemistry in the hypersonic environment. The flowfield solutions are used to estimate relevant shock-tube parameters for laminar flow, such as test times, and to predict density and velocity profiles. Boundary-layer parameters such as bar-delta(sub u), bar-delta(sup *), and bar-tau(sub w), and test time parameters such as bar-tau and particle time of flight t(sub f), are computed and compared with those evaluated by using Mirels' correlations. This article then discusses in detail the effects of flow nonuniformities on particle time-of-flight behind the normal shock and, consequently, on the interpretation of shock-tube data. This article concludes that for accurate interpretation of shock-tube data, a detailed analysis of flowfield parameters, using a computer code such as used in this study, must be performed

Testing a Simplified Version of Einstein's Equations for Numerical Relativity

Solving dynamical problems in general relativity requires the full machinery of numerical relativity. Wilson has proposed a simpler but approximate scheme for systems near equilibrium, like binary neutron stars. We test the scheme on isolated, rapidly rotating, relativistic stars. Since these objects are in equilibrium, it is crucial that the approximation work well if we are to believe its predictions for more complicated systems like binaries. Our results are very encouraging.Comment: 9 pages (RevTeX 3.0 with 6 uuencoded figures), CRSR-107

Numerical simulations of the flow in the HYPULSE expansion tube

Axisymmetric numerical simulations with finite-rate chemistry are presented for two operating conditions in the HYPULSE expansion tube. The operating gas for these two cases is nitrogen and the computations are compared to experimental data. One test condition is at a total enthalpy of 15.2 MJ/Kg and a relatively low static pressure of 2 kPa. This case is characterized by a laminar boundary layer and significant chemical nonequilibrium in the acceleration gas. The second test condition is at a total enthalpy of 10.2 MJ/Kg and a static pressure of 38 kPa and is characterized by a turbulent boundary layer. For both cases, the time-varying test gas pressure predicted by the simulations is in good agreement with experimental data. The computations are also found to be in good agreement with Mirels' correlations for shock tube flow. It is shown that the nonuniformity of the test gas observed in the HYPULSE expansion tube is strongly linked to the boundary layer thickness. The turbulent flow investigated has a larger boundary layer and greater test gas nonuniformity. In order to investigate possibilities of improving expansion tube flow quality by reducing the boundary layer thickness, parametric studies showing the effect of density and turbulent transition point on the test conditions are also presented. Although an increase in the expansion tube operating pressure level would reduce the boundary layer thickness, the simulations indicate that the reduction would be less than what is predicted by flat plate boundary layer correlations

Photodissociation of Non-Covalent Peptide-Crown Ether Complexes

Highly chromogenic 18-crown-6-dipyrrolylquinoxaline coordinates primary amines of peptides, forming non-covalent complexes that can be transferred to the gas-phase by electrospray ionization. The appended chromogenic crown ether facilitates efficient energy transfer to the peptide upon ultraviolet irradiation in the gas phase, resulting in diagnostic peptide fragmentation. Collisional-activated dissociation and infrared multiphoton dissociation of these non-covalent complexes result only in their disassembly with the charge retained on either the peptide or crown ether, yielding no sequence ions. Upon UV photon absorption the intermolecular energy transfer is facilitated by the fast activation timescale of ultraviolet photodissociation (<10 ns) and by the collectively strong hydrogen bonding between the crown ether and peptide, thus allowing effective transfer of energy to the peptide moiety before disruption of the intermolecular hydrogen bonds

An enigmatic group of arctic island caribou and the potential implications for conservation of biodiversity

We investigated the status of caribou classified as Rangifer tarandus pearyi by DNA analyses, with an emphasis on those large-bodied caribou identified as ultra pearyi that were collected in summer 1958 on Prince of Wales Island, south-central Canadian Arctic Archipelago. Our comparative assessment reveals that the ultra pearyi from Prince of Wales Island belong to a group of pearyi and are not hybrids of pearyi x groenlandicus, as we found for the caribou occurring on nearby Banks Island and northwest Victoria Island. The ultra pearyi from Prince of Wales Island cluster with high arctic pearyi and are separated genetically from the caribou populations that we sampled on the low Canadian Arctic Islands and the Canadian mainland. Our findings reveal biodiversity below the level of subspecies or regional designations. These results support the position that to retain the biodiversity present among caribou populations on the Canadian Arctic Islands, conservation efforts should be targeted at the smaller scale level of the geographic population, rather than on a wider regional or subspecific range-wide basis

Calibration of chron C29r: New high-precision geochronologic and paleomagnetic constraints from the Hell Creek region, Montana

The mass extinction at the Cretaceous- Paleogene boundary marks one of the most important biotic turnover events in Earth history. Yet, despite decades of study, the causes of the Cretaceous-Paleogene boundary crises remain under debate. An important tool that has the capacity to greatly improve our understanding of the events around the Cretaceous-Paleogene boundary is the geomagnetic polarity time scale (GPTS). The GPTS is used for age control in numerous Cretaceous-Paleogene boundary studies, including the timing of Deccan Traps volcanism, a majority of studies in marine sections, and studies on climate and ecological change across the Cretaceous-Paleogene boundary. The current calibration of the GPTS for circum- Cretaceous-Paleogene boundary polarity chrons (C30n-C28n) from the Geologic Time Scale draws heavily on astronomical tuning and uses a 40Ar/39Ar age for the Cretaceous- Paleogene boundary as a tie point that has since been shown to be 200 ka too old. Furthermore, complex sedimentation has been recorded in marine sections immediately following the Cretaceous-Paleogene boundary, which can possibly obscure orbital signals and complicate cyclostratigraphic interpretation. An independent test of the cyclostratigraphy for this time period is imperative for confidence in the astronomical time scale. Further, polarity reversal ages given in the GPTS do not include uncertainty estimates, making them unsuitable for quantitative chronometry. Recent calibrations have been attempted using U/Pb geochronology on zircons; however, U/Pb zircon dates may be biased by pre-eruptive zircon residence times of tens to hundreds of thousands of years. In this study, we provide constraints on the timing and duration of the most important circum-Cretaceous-Paleogene boundary chron, chron C29r, using high-precision 40Ar/39Ar geochronology and magnetostratigraphy on fluvial sediments from the Hell Creek region, Montana. Here, we show results for 14 new magnetostratigraphic sections, and 18 new high-precision 40Ar/39Ar dates, which together provide six independent constraints on the age of the C29r/C29n reversal and two constraints on the C30n/ C29r reversal. Together, these results show that the duration of C29r was 587 ± 53 ka, consistent with the most recent Geologic Time Scale calibration and previous U-Pb age models. We further present new geochronologic data for the Cretaceous-Paleogene boundary that provide the most precise date yet, of 66.052 ± 0.008/0.043 Ma. Integration of our results into the extensive paleontological framework for this region further provides important constraints on rates of terrestrial faunal change across the Cretaceous-Paleogene boundary

Offsetting of CO₂ emissions by air capture in mine tailings at the Mount Keith Nickel Mine, Western Australia: Rates, controls and prospects for carbon neutral mining

The hydrated Mg-carbonate mineral, hydromagnesite [Mg₅(CO₃)₄(OH)₂•4H₂O], precipitates within mine tailings at the Mount Keith Nickel Mine, Western Australia as a direct result of mining operations. We have used quantitative mineralogical data and δ¹³C, δ¹⁸O and F¹⁴C isotopic data to quantify the amount of CO₂fixation and identify carbon sources. Our radiocarbon results indicate that at least 80% of carbon stored in hydromagnesite has been captured from the modern atmosphere. Stable isotopic results indicate that dissolution of atmospheric CO₂ into mine tailings water is kinetically limited, which suggests that the current rate of carbon mineralization could be accelerated. Reactive transport modeling is used to describe the observed variation in tailings mineralogy and to estimate rates of CO₂ fixation. Based on our assessment, approximately 39,800 t/yr of atmospheric CO₂ are being trapped and stored in tailings at Mount Keith. This represents an offsetting of approximately 11% of the mine's annual greenhouse gas emissions. Thus, passive sequestration via enhanced weathering of mineral waste can capture and store a significant amount of CO₂. Recommendations are made for changes to tailings management and ore processing practices that have potential to accelerate carbonation of tailings and further reduce or completely offset the net greenhouse gas emissions at Mount Keith and many other mines