HCO, c-C3H and CF+ : three new molecules in diffuse, translucent and "spiral-arm'' clouds

%methods {We used the EMIR receiver and FTS spectrometer at the IRAM 30m to construct absorption spectra toward bright extra-galactic background sources at 195 kHz spectral resolution ($\approx$ 0.6 \kms). We used the IRAM Plateau de Bure interferometer to synthesize absorption spectra of \hthcop\ and HCO toward the galactic HII region W49.} %results {HCO, \cc3h\ and CF\p\ were detected toward the blazars \bll\ and 3C111 having \EBV\ = 0.32 and 1.65 mag. HCO was observed in absorption from ``spiral-arm'' clouds in the galactic plane occulting W49. The complement of detectable molecular species in the 85 - 110 GHz absorption spectrum of diffuse/translucent gas is now fully determined at rms noise level $\delta_\tau \approx 0.002$ at \EBV\ = 0.32 mag (\AV\ = 1 mag) and $\delta_\tau$/\EBV\ $\approx\ 0.003$ mag$^{-1}$ overall.} %conclusions {As with OH, \hcop\ and \cch, the relative abundance of \cc3h\ varies little between diffuse and dense molecular gas, with N(\cc3h)/N({\it o-c}-\c3h2) $\approx$ 0.1. We find N(CF\p)/N(H$^{13}$CO\p) $\approx 5$, N(CF\p)/N(\cch) $\approx$ 0.005-0.01 and because N(CF\p) increases with \EBV\ and with the column densities of other molecules we infer that fluorine remains in the gas phase as HF well beyond \AV\ = 1 mag. We find N(HCO)/N(H$^{13}$CO\p) = 16 toward \bll, 3C111 and the 40 km/s spiral arm cloud toward W49, implying X(HCO) $\approx 10^{-9}$, about 10 times higher than in dark clouds. The behaviour of HCO is consistent with previous suggestions that it forms from C\p\ and \HH, even when \AV\ is well above 1 mag. The survey can be used to place useful upper limits on some species, for instance N(\hhco)/N(\HH CS) $>$ 32 toward 3C111, compared to 7 toward TMC-1, confirming the possibility of a gas phase formation route to \hhco.}Comment: A\%A in pres

Nascent bipolar outflows associated with the first hydrostatic core candidates Barnard 1b-N and 1b-S

In the theory of star formation, the first hydrostatic core (FHSC) phase is a critical step in which a condensed object emerges from a prestellar core. This step lasts about one thousand years, a very short time compared with the lifetime of prestellar cores, and therefore is hard to detect unambiguously. We present IRAM Plateau de Bure observations of the Barnard 1b dense molecular core, combining detections of H2CO and CH3OH spectral lines and dust continuum at 2.3" resolution (~ 500 AU). The two compact cores B1b-N and B1b-S are detected in the dust continuum at 2mm, with fluxes that agree with their spectral energy distribution. Molecular outflows associated with both cores are detected. They are inclined relative to the direction of the magnetic field, in agreement with predictions of collapse in turbulent and magnetized gas with a ratio of mass to magnetic flux somewhat higher than the critical value, \mu ~ 2 - 7. The outflow associated with B1b-S presents sharp spatial structures, with ejection velocities of up to ~ 7 kms from the mean velocity. Its dynamical age is estimated to be ~2000 yrs. The B1b-N outflow is smaller and slower, with a short dynamical age of ~1000 yrs. The B1b-N outflow mass, mass-loss rate, and mechanical luminosity agree well with theoretical predictions of FHSC. These observations confirm the early evolutionary stage of B1b-N and the slightly more evolved stage of B1b-S.Comment: 6 pages, 3 figure

The ionization fraction gradient across the Horsehead edge: An archetype for molecular clouds

The ionization fraction plays a key role in the chemistry and dynamics of molecular clouds. We study the H13CO+, DCO+ and HOC+ line emission towards the Horsehead, from the shielded core to the UV irradiated cloud edge, i.e., the Photodissociation Region (PDR), as a template to investigate the ionization fraction gradient in molecular clouds. We analyze a PdBI map of the H13CO+ J=1-0 line, complemented with IRAM-30m H13CO+ and DCO+ higher-J line maps and new HOC+ and CO+ observations. We compare self-consistently the observed spatial distribution and line intensities with detailed depth-dependent predictions of a PDR model coupled with a nonlocal radiative transfer calculation. The chemical network includes deuterated species, 13C fractionation reactions and HCO+/HOC+ isomerization reactions. The role of neutral and charged PAHs in the cloud chemistry and ionization balance is investigated. The detection of HOC+ reactive ion towards the Horsehead PDR proves the high ionization fraction of the outer UV irradiated regions, where we derive a low [HCO+]/[HOC+]~75-200 abundance ratio. In the absence of PAHs, we reproduce the observations with gas-phase metal abundances, [Fe+Mg+...], lower than 4x10(-9) (with respect to H) and a cosmic-rays ionization rate of zeta=(5+/-3)x10(-17) s(-1). The inclusion of PAHs modifies the ionization fraction gradient and increases the required metal abundance. The ionization fraction in the Horsehead edge follows a steep gradient, with a scale length of ~0.05 pc (or ~25''), from [e-]~10(-4) (or n_e ~ 1-5 cm(-3)) in the PDR to a few times ~10(-9) in the core. PAH^- anions play a role in the charge balance of the cold and neutral gas if substantial amounts of free PAHs are present ([PAH] >10(-8)).Comment: 13 pages, 7 figures, 6 tables. Accepted for publication in A&A (english not edited

The hyperfine structure in the rotational spectrum of CF+

Context. CF+ has recently been detected in the Horsehead and Orion Bar photo-dissociation regions. The J=1-0 line in the Horsehead is double-peaked in contrast to other millimeter lines. The origin of this double-peak profile may be kinematic or spectroscopic. Aims. We investigate the effect of hyperfine interactions due to the fluorine nucleus in CF+ on the rotational transitions. Methods. We compute the fluorine spin rotation constant of CF+ using high-level quantum chemical methods and determine the relative positions and intensities of each hyperfine component. This information is used to fit the theoretical hyperfine components to the observed CF+ line profiles, thereby employing the hyperfine fitting method in GILDAS. Results. The fluorine spin rotation constant of CF+ is 229.2 kHz. This way, the double-peaked CF+ line profiles are well fitted by the hyperfine components predicted by the calculations. The unusually large hyperfine splitting of the CF+ line therefore explains the shape of the lines detected in the Horsehead nebula, without invoking intricate kinematics in the UV-illuminated gas.Comment: 2 pages, 1 figure, Accepted for publication in A&

The IRAM-30m line survey of the Horsehead PDR: III. High abundance of complex (iso-)nitrile molecules in UV-illuminated gas

Complex (iso-)nitrile molecules, such as CH3CN and HC3N, are relatively easily detected in our Galaxy and in other galaxies. We constrain their chemistry through observations of two positions in the Horsehead edge: the photo-dissociation region (PDR) and the dense, cold, and UV-shielded core just behind it. We systematically searched for lines of CH3CN, HC3N, C3N, and some of their isomers in our sensitive unbiased line survey at 3, 2, and 1mm. We derived column densities and abundances through Bayesian analysis using a large velocity gradient radiative transfer model. We report the first clear detection of CH3NC at millimeter wavelength. We detected 17 lines of CH3CN at the PDR and 6 at the dense core position, and we resolved its hyperfine structure for 3 lines. We detected 4 lines of HC3N, and C3N is clearly detected at the PDR position. We computed new electron collisional rate coefficients for CH3CN, and we found that including electron excitation reduces the derived column density by 40% at the PDR position. While CH3CN is 30 times more abundant in the PDR than in the dense core, HC3N has similar abundance at both positions. The isomeric ratio CH3NC/CH3CN is 0.15+-0.02. In the case of CH3CN, pure gas phase chemistry cannot reproduce the amount of CH3CN observed in the UV-illuminated gas. We propose that CH3CN gas phase abundance is enhanced when ice mantles of grains are destroyed through photo-desorption or thermal-evaporation in PDRs, and through sputtering in shocks. (abridged)Comment: Accepted for publication in Astronomy & Astrophysic

High-velocity hot CO emission close to Sgr A*: Herschel/HIFI submillimeter spectral survey toward Sgr A*

The properties of molecular gas, the fuel that forms stars, inside the cavity of the circumnuclear disk (CND) are not well constrained. We present results of a velocity-resolved submillimeter scan (~480 to 1250 GHz}) and [CII]158um line observations carried out with Herschel/HIFI toward Sgr A*; these results are complemented by a ~2'x2' CO (J=3-2) map taken with the IRAM 30 m telescope at ~7'' resolution. We report the presence of high positive-velocity emission (up to about +300 km/s) detected in the wings of CO J=5-4 to 10-9 lines. This wing component is also seen in H2O (1_{1,0}-1_{0,1}) a tracer of hot molecular gas; in [CII]158um, an unambiguous tracer of UV radiation; but not in [CI]492,806 GHz. This first measurement of the high-velocity CO rotational ladder toward Sgr A* adds more evidence that hot molecular gas exists inside the cavity of the CND, relatively close to the supermassive black hole (< 1 pc). Observed by ALMA, this velocity range appears as a collection of CO (J=3-2) cloudlets lying in a very harsh environment that is pervaded by intense UV radiation fields, shocks, and affected by strong gravitational shears. We constrain the physical conditions of the high positive-velocity CO gas component by comparing with non-LTE excitation and radiative transfer models. We infer T_k~400 K to 2000 K for n_H~(0.2-1.0)x10^5 cm^-3. These results point toward the important role of stellar UV radiation, but we show that radiative heating alone cannot explain the excitation of this ~10-60 M_Sun component of hot molecular gas inside the central cavity. Instead, strongly irradiated shocks are promising candidates.Comment: Accepted for publication in A&A Letters ( this v2 includes corrections by language editor