Mechanical properties of polyethylene terephthalate under selected conditions and methods of preparation Semiannual progress report, period ending 31 Oct. 1967

Mechanical properties of polyethylene terephthalate under selected conditions and methods of preparatio

Modification of the 21-cm power spectrum by X-rays during the epoch of reionisation

We incorporate a contribution to reionization from X-rays within analytic and semi-numerical simulations of the 21-cm signal arising from neutral hydrogen during the epoch of reionization. We explore the impact that X-ray ionizations have on the power spectrum (PS) of 21-cm fluctuations by varying both the average X-ray MFP and the fractional contribution of X-rays to reionization. In general, prior to the epoch when the intergalactic medium is dominated by ionized regions (H {\sevensize II} regions), X-ray-induced ionization enhances fluctuations on spatial scales smaller than the X-ray MFP, provided that X-ray heating does not strongly supress galaxy formation. Conversely, at later times when \H2 regions dominate, small-scale fluctuations in the 21-cm signal are suppressed by X-ray ionization. Our modelling also shows that the modification of the 21-cm signal due to the presence of X-rays is sensitive to the relative scales of the X-ray MFP, and the characteristic size of \H2 regions. We therefore find that X-rays imprint an epoch and scale-dependent signature on the 21-cm PS, whose prominence depends on fractional X-ray contribution. The degree of X-ray heating of the IGM also determines the extent to which these features can be discerned. We show that the MWA will have sufficient sensitivity to detect this modification of the PS, so long as the X-ray photon MFP falls within the range of scales over which the array is most sensitive ($\sim0.1$ Mpc$^{-1}$). In cases in which this MFP takes a much smaller value, an array with larger collecting area would be required.Comment: 15 pages, 6 figures, Accepted for publication in MNRAS X-ray heating contribution now adde

The Impact of HI in Galaxies on 21-cm Intensity Fluctuations During the Reionisation Epoch

We investigate the impact of neutral hydrogen (HI) in galaxies on the statistics of 21-cm fluctuations using analytic and semi-numerical modelling. Following the reionisation of hydrogen the HI content of the Universe is dominated by damped absorption systems (DLAs), with a cosmic density in HI that is observed to be constant at a level equal to ~2% of the cosmic baryon density from z~1 to z~5. We show that extrapolation of this constant fraction into the reionisation epoch results in a reduction of 10-20% in the amplitude of 21-cm fluctuations over a range of spatial scales. The assumption of a different percentage during the reionisation era results in a proportional change in the 21-cm fluctuation amplitude. We find that consideration of HI in galaxies/DLAs reduces the prominence of the HII region induced shoulder in the 21-cm power spectrum (PS), and hence modifies the scale dependence of 21-cm fluctuations. We also estimate the 21cm-galaxy cross PS, and show that the cross PS changes sign on scales corresponding to the HII regions. From consideration of the sensitivity for forthcoming low-frequency arrays we find that the effects of HI in galaxies/DLAs on the statistics of 21-cm fluctuations will be significant with respect to the precision of a PS or cross PS measurement. In addition, since overdense regions are reionised first we demonstrate that the cross-correlation between galaxies and 21-cm emission changes sign at the end of the reionisation era, providing an alternative avenue to pinpoint the end of reionisation. The sum of our analysis indicates that the HI content of the galaxies that reionise the universe will need to be considered in detailed modelling of the 21-cm intensity PS in order to correctly interpret measurements from forthcoming low-frequency arrays.Comment: 11 pages, 6 figures. Submitted to MNRA

Custom-molded foot-orthosis intervention and multi-segment medial foot kinematics during walking

Context: Foot-orthosis (FO) intervention to prevent and treat numerous lower extremity injuries is widely accepted clinically. However, the results of quantitative gait analyses have been equivocal. The foot models used, participants receiving intervention, and orthoses used might contribute to the variability. Objective: To investigate the effect of a custom-molded FO intervention on multisegment medial foot kinematics during walking in participants with low-mobile foot posture. Design: Crossover study. Setting: University biomechanics and ergonomics laboratory. Patients or Other Participants: Sixteen participants with low-mobile foot posture (7 men, 9 women) were assigned randomly to 1 of 2 FO groups. Intervention(s): After a 2-week period to break in the FOs, individuals participated in a gait analysis that consisted of 5 successful walking trials (1.3 to 1.4 m/s) during no-FO and FO conditions. Main Outcome Measure(s): Three-dimensional displacements during 4 subphases of stance (loading response, mid- stance, terminal stance, preswing) were computed for each multisegment foot model articulation. Results: Repeated-measures analyses of variance (ANO- VAs) revealed that rearfoot complex dorsiflexion displacement during midstance was greater in the FO than the no-FO condition (F114 = 5.24, P=.O4, partial r|2 = 0.27). Terminal stance repeated-measures ANOVA results revealed insert-by-insert condition interactions for the first metatarsophalangeal ¡oint complex (F114=7.87, P=.O1, partial if = 0.36). However, additional follow-up analysis did not reveal differences between the no-FO and FO conditions for the balanced traditional ortho- sis (F, 14 = 4.32, P = .O8, partial if = 0.38) or full-contact orthosis (F1i14 = 4.10, P=.O8, partial if = 0.37). Conclusions: Greater rearfoot complex dorsiflexion during midstance associated with FO intervention may represent improved foot kinematics in people with low-mobile foot postures. Furthermore, FO intervention might partially correct dysfunctional kinematic patterns associated with low-mobile foot postures.

Subtraction of Bright Point Sources from Synthesis Images of the Epoch of Reionization

Bright point sources associated with extragalactic AGN and radio galaxies are an important foreground for low frequency radio experiments aimed at detecting the redshifted 21cm emission from neutral hydrogen during the epoch of reionization. The frequency dependence of the synthesized beam implies that the sidelobes of these sources will move across the field of view as a function of observing frequency, hence frustrating line-of-sight foreground subtraction techniques. We describe a method for subtracting these point sources from dirty maps produced by an instrument such as the MWA. This technique combines matched filters with an iterative centroiding scheme to locate and characterize point sources in the presence of a diffuse background. Simulations show that this technique can improve the dynamic range of EOR maps by 2-3 orders of magnitude.Comment: 11 pages, 8 figures, 1 table, submitted to PAS

Nanoimprinted superlattice metallic photonic crystal as ultraselective solar absorber

A two-dimensional superlattice metallic photonic crystal (PhC) and its fabrication by nanoimprint lithography on tantalum substrates are presented. The superior tailoring capacity of the superlattice PhC geometry is used to achieve spectrally selective solar absorption optimized for high-temperature and high-efficiency solar-energy-conversion applications. The scalable fabrication route by nanoimprint lithography allows for a high-throughput and high-resolution replication of this complex pattern over large areas. Despite the high fill factor, the pattern of polygonal cavities is accurately replicated into a resist that hardens under ultraviolet radiation over an area of 10  mm². In this way, cavities of 905 nm and 340 nm width are achieved with a period of 1 μm. After pattern transfer into tantalum via a deep reactive ion-etching process, the achieved cavities are 2.2 μm deep, separated by 85–95 nm wide ridges with vertical sidewalls. The room-temperature reflectance spectra of the fabricated samples show excellent agreement with simulated results, with a high spectral absorptance approaching blackbody absorption in the range from 300 to 1900 nm and a steep cutoff. The calculated solar absorptivity of this superlattice PhC is 96% and its thermal transfer efficiency is 82.8% at an operating temperature of 1500 K and an irradiance of 1000  kW/m².United States. Army Research Office (W911NF-13-D-0001)United States. Department of Energy (DE-SC0001299

Phase-field approach to polycrystalline solidification including heterogeneous and homogeneous nucleation

Advanced phase-field techniques have been applied to address various aspects of polycrystalline solidification including different modes of crystal nucleation. The height of the nucleation barrier has been determined by solving the appropriate Euler-Lagrange equations. The examples shown include the comparison of various models of homogeneous crystal nucleation with atomistic simulations for the single component hard-sphere fluid. Extending previous work for pure systems (Gránásy L, Pusztai T, Saylor D and Warren J A 2007 Phys. Rev. Lett. 98 art no 035703), heterogeneous nucleation in unary and binary systems is described via introducing boundary conditions that realize the desired contact angle. A quaternion representation of crystallographic orientation of the individual particles (outlined in Pusztai T, Bortel G and Gránásy L 2005 Europhys. Lett. 71 131) has been applied for modeling a broad variety of polycrystalline structures including crystal sheaves, spherulites and those built of crystals with dendritic, cubic, rhombododecahedral, truncated octahedral growth morphologies. Finally, we present illustrative results for dendritic polycrystalline solidification obtained using an atomistic phase-field model

Selected-area small-angle electron diffraction

Selected-area electron diffraction capable of resolving spacings up to 2000 Å from first-order discrete reflections has been achieved using a standard, double-condenser electron microscope. The technique allows photographing of the selected area, at sufficient magnification, that gives rise to the small-angle scattering pattern, in addition to the normal capabilities of obtaining related wide-angle diffraction and wide-angle and small-angle dark-field micrographs. Most, but not all, of the results of discrete and diffuse, small-angle electron diffraction studies from a large variety of specimens including drawn, annealed polyethylene, latex particles, evaporated gold particles, grating replicas, and slit edges have been explained on the basis of the structures observed in the corresponding electron micrographs. Small-angle electron diffraction is found to be more sensitive to defects in the packing of the scattering centres than small-angle X-ray scattering.Peer Reviewedhttp://deepblue.lib.umich.edu/bitstream/2027.42/44682/1/10853_2004_Article_BF00562952.pd