Symmetry effects and equivalences in lattice models of hydrophobic interaction

We establish the equivalence of a recently introduced discrete model of the hydrophobic interaction, as well as its extension to continuous state variables, with the Ising model in a magnetic field with temperature-dependent strength. In order to capture the effect of symmetries of the solvent particles we introduce a generalized multi-state model. We solve this model - which is not of the Ising type - exactly in one dimension. Our findings suggest that a small increase in symmetry decreases the amplitude of the solvent-mediated part of the potential of mean force between solute particles and enhances the solubility in a very simple fashion. High symmetry decreases also the range of the attractive potential. This weakening of the hydrophobic effect observed in the model is in agreement with the notion that the effect is entropic in origin.Comment: 19 pages, 2 figure

Susceptibility amplitude ratios in the two-dimensional Potts model and percolation

The high-temperature susceptibility of the $q$-state Potts model behaves as $\Gamma|T-T_c|^{-\gamma}$ as $T\to T_c+$, while for $T\to T_c-$ one may define both longitudinal and transverse susceptibilities, with the same power law but different amplitudes $\Gamma_L$ and $\Gamma_T$. We extend a previous analytic calculation of the universal ratio $\Gamma/\Gamma_L$ in two dimensions to the low-temperature ratio $\Gamma_T/\Gamma_L$, and test both predictions with Monte Carlo simulations for $q=3$ and 4. The data for $q=4$ are inconclusive owing to large corrections to scaling, while for $q=3$ they appear consistent with the prediction for $\Gamma_T/\Gamma_L$, but not with that for $\Gamma/\Gamma_L$. A simple extrapolation of our analytic results to $q\to1$ indicates a similar discrepancy with the corresponding measured quantities in percolation. We point out that stronger assumptions were made in the derivation of the ratio $\Gamma/\Gamma_L$, and our work suggests that these may be unjustified.Comment: 17 pages, late

An assessment of artificial radionuclide transfer from Sellafield to South West Scotland

SIGLEAvailable from British Library Document Supply Centre- DSC:3614.604(DOE/RW--89.127) / BLDSC - British Library Document Supply CentreGBUnited Kingdo