Теоретичні аспекти процесу реструктуризації в умовах антикризового управління

У статті розкрито сутність поняття "реструктуризація", окреслено чинники, які викликають необхідність реструктуризаційних змін, визначено цілі та види реструктуризації, а також запропоновано ряд перспективних напрямів та відповідних заходів її проведення.Essence of concept "restructuring" is exposed in the article, outlined factors which cause the necessity of restrukturizaciynikh changes, certainly aims and types of restructuring, and also the row of perspective directions and proper measures of its leadthrough is offered

Mechanical and Thermal Properties of Polyvinyl Chloride Plasticized with Natural Fatty Acid Esters

From an industrial point of view, the use of new nontoxic and biodegradable plasticizers coming from natural resources is an interesting alternative to traditional plasticizers based on phthalates. In this study, two types of epoxidized fatty acids esters (EFAE) with different molecular weights have been used in order to produce flexible PVC with low toxicity. Different amounts of EFAE 201 and 401 have been considered in this study. Mechanical and thermal properties have been determined and morphology of fracture surface has been studied by scanning electron microscopy.This work was supported by the "Ministerio de Ciencia e Innovacion" [Grant number IPT-310000-2010-37] and the "Universitat Politecnica de Valencia" [Grant number PAID 06-10 Ref: 003-300].Fenollar Gimeno, OÁ.; García Sanoguera, D.; Sánchez Nacher, L.; Boronat Vitoria, T.; López Martínez, J.; Balart Gimeno, RA. (2013). Mechanical and Thermal Properties of Polyvinyl Chloride Plasticized with Natural Fatty Acid Esters. Polymer-Plastics Technology and Engineering. 52(8):761-767. https://doi.org/10.1080/03602559.2013.763352S761767528Zhao, R., Neighbour, G., Deutz, P., & McGuire, M. (2012). Materials selection for cleaner production: An environmental evaluation approach. Materials & Design, 37, 429-434. doi:10.1016/j.matdes.2012.01.014Biedermann-Brem, S., Biedermann, M., Fiselier, K., & Grob, K. (2005). Compositional GC-FID analysis of the additives to PVC, focusing on the gaskets of lids for glass jars. Food Additives and Contaminants, 22(12), 1274-1284. doi:10.1080/02652030500309426Braun, D. (2001). PVC ? origin, growth, and future. Journal of Vinyl and Additive Technology, 7(4), 168-176. doi:10.1002/vnl.10288Summers, J. W. (1997). A review of vinyl technology. Journal of Vinyl and Additive Technology, 3(2), 130-139. doi:10.1002/vnl.10179Islam, R., Islam, T., Nigar, F., Saha, S., Tapash, A., Sharmin, N., … Zaman, H. U. (2011). Fabrication and Mechanical Characterization of Jute Fabrics: Reinforced Polyvinyl Chloride/Polypropylene Hybrid Composites. International Journal of Polymeric Materials, 60(8), 576-590. doi:10.1080/00914037.2010.531822Khan, R. A., Sharmin, N., Khan, M. A., Das, A. K., Dey, K., Saha, S., … Saha, M. (2011). Comparative Studies of Mechanical and Interfacial Properties Between Jute Fiber/PVC and E-Glass Fiber/PVC Composites. Polymer-Plastics Technology and Engineering, 50(2), 153-159. doi:10.1080/03602559.2010.531422Hassan, A., Akbari, A., Hing, N. K., & Ratnam, C. T. (2012). Mechanical and Thermal Properties of ABS/PVC Composites: Effect of Particles Size and Surface Treatment of Ground Calcium Carbonate. Polymer-Plastics Technology and Engineering, 51(5), 473-479. doi:10.1080/03602559.2011.651242Zhu, G., Liu, Y., & Wang, F. (2012). Surface Morphology and Properties of Rigid Poly(γ-benzylL-glutamate) Membrane Modified by Flexible Poly(Vinyl Chloride). International Journal of Polymeric Materials, 61(10), 737-747. doi:10.1080/00914037.2011.610044KAWAMURA, Y., KANNO, S., MUTSUGA, M., & TANAMOTO, K. (2006). Determination of Epoxidized Soybean Oil in Bottled Foods. Journal of the Food Hygienic Society of Japan (Shokuhin Eiseigaku Zasshi), 47(6), 243-248. doi:10.3358/shokueishi.47.243Marcilla, A., Garcia, S., & Garcia-Quesada, J. C. (2008). Migrability of PVC plasticizers. Polymer Testing, 27(2), 221-233. doi:10.1016/j.polymertesting.2007.10.007Wang, Q., & Storm, B. K. (2005). Separation and analysis of low molecular weight plasticizers in poly(vinyl chloride) tubes. Polymer Testing, 24(3), 290-300. doi:10.1016/j.polymertesting.2004.12.002Llop, C., Manrique, A., Navarro, R., Mijangos, C., & Reinecke, H. (2011). Control of the migration behavior of slip agents in polyolefin-based films. Polymer Engineering & Science, 51(9), 1763-1769. doi:10.1002/pen.21963Pedersen, G. A., Jensen, L. K., Fankhauser, A., Biedermann, S., Petersen, J. H., & Fabech, B. (2008). Migration of epoxidized soybean oil (ESBO) and phthalates from twist closures into food and enforcement of the overall migration limit. Food Additives & Contaminants: Part A, 25(4), 503-510. doi:10.1080/02652030701519088Jimenez, A., Lopez, J., Iannoni, A., & Kenny, J. M. (2001). Formulation and mechanical characterization of PVC plastisols based on low-toxicity additives. Journal of Applied Polymer Science, 81(8), 1881-1890. doi:10.1002/app.1621Shea, K. M. (2003). Pediatric Exposure and Potential Toxicity of Phthalate Plasticizers. PEDIATRICS, 111(6), 1467-1474. doi:10.1542/peds.111.6.1467Boudhani, H., Lainé, C., Fulchiron, R., Bounor-Legaré, V., & Cassagnau, P. (2009). Viscoelasticity and mechanical properties of reactive PVC plastisols. Polymer Engineering & Science, 49(6), 1089-1098. doi:10.1002/pen.21356Wang, M. Y., Zhou, N. Q., & Wen, S. P. (2009). The Effect of Concentrations of Modifying Agent and Plasticizer on Cell Morphology of PVC Microcellular Foam. Polymer-Plastics Technology and Engineering, 48(3), 303-309. doi:10.1080/03602550802675678Yang, B., Bai, Y., & Cao, Y. (2010). Effects of inorganic nano-particles on plasticizers migration of flexible PVC. Journal of Applied Polymer Science, 115(4), 2178-2182. doi:10.1002/app.31310Kilinç, S., İyim, T. B., Emik, S., & Özgümüş, S. (2005). Recycling of Waste PET: Usage as Secondary Plasticizer for PVC. Polymer-Plastics Technology and Engineering, 44(8-9), 1379-1388. doi:10.1080/03602550500208228Audic, J.-L., Reyx, D., & Brosse, J.-C. (2003). Migration of additives from food grade polyvinyl chloride (PVC) films: Effect of plasticization by polymeric modifiers instead of conventional plasticizers. Journal of Applied Polymer Science, 89(5), 1291-1299. doi:10.1002/app.12240Fankhauser-Noti, A., Biedermann-Brem, S., & Grob, K. (2006). PVC plasticizers/additives migrating from the gaskets of metal closures into oily food: Swiss market survey June 2005. European Food Research and Technology, 223(4), 447-453. doi:10.1007/s00217-005-0223-7Sharma, V., & Kundu, P. P. (2008). Condensation polymers from natural oils. Progress in Polymer Science, 33(12), 1199-1215. doi:10.1016/j.progpolymsci.2008.07.004Benaniba, M. ., Belhaneche-Bensemra, N., & Gelbard, G. (2001). Stabilizing effect of epoxidized sunflower oil on the thermal degradation of poly(vinyl chloride). Polymer Degradation and Stability, 74(3), 501-505. doi:10.1016/s0141-3910(01)00170-7Atek, D., Belhaneche-Bensemra, N., & Turki, M. (2010). Migration of Epoxidized Sunflower Oil and Dioctyl Phthalate from Rigid and Plasticized Poly(vinyl chloride). International Journal of Polymeric Materials, 59(5), 342-352. doi:10.1080/00914030903478909Ghiou, N., & Benaniba, M. T. (2010). The Effect of Epoxidized Sunflower Oil on the Miscibility of Plasticized PVC/NBR Blends. 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Microviscosity of hydrophobically modified hydroxyethyl cellulose aqueous solutions

10.1016/j.jcis.2008.03.030Journal of Colloid and Interface Science3222678-680JCIS

Nonlinear rheology of aqueous solutions of hydrophobically modified hydroxyethyl cellulose with nonionic surfactant

10.1016/j.jcis.2007.07.065Journal of Colloid and Interface Science3162858-866JCIS