53 research outputs found
Zeolite-dye micro lasers
We present a new class of micro lasers based on nanoporous molecular sieve
host-guest systems. Organic dye guest molecules of
1-Ethyl-4-(4-(p-Dimethylaminophenyl)-1,3-butadienyl)-pyridinium Perchlorat were
inserted into the 0.73-nm-wide channel pores of a zeolite AlPO-5 host. The
zeolitic micro crystal compounds where hydrothermally synthesized according to
a particular host-guest chemical process. The dye molecules are found not only
to be aligned along the host channel axis, but to be oriented as well. Single
mode laser emission at 687 nm was obtained from a whispering gallery mode
oscillating in a 8-m-diameter monolithic micro resonator, in which the
field is confined by total internal reflection at the natural hexagonal
boundaries inside the zeolitic microcrystals.Comment: Accepted for publication in Phys. Rev. Let
Spectral properties of quantized barrier billiards
The properties of energy levels in a family of classically pseudointegrable
systems, the barrier billiards, are investigated. An extensive numerical study
of nearest-neighbor spacing distributions, next-to-nearest spacing
distributions, number variances, spectral form factors, and the level dynamics
is carried out. For a special member of the billiard family, the form factor is
calculated analytically for small arguments in the diagonal approximation. All
results together are consistent with the so-called semi-Poisson statistics.Comment: 8 pages, 9 figure
(No) time for control: Frontal theta dynamics reveal the cost of temporally guided conflict anticipation
Electronic structure of small fullerenes : evidence for the high stability of C32
The electronic structure of small fullerenes determined experimentally by anion photoelectron spectroscopy is compared with calculations. A huge mass signal and a large gap of 1.3 eV comparable to the gap of C70 have been found for C32, indicating that this cluster is the most stable fullerene below C60. Also C36, C44, and C50 exhibit large gaps and surprisingly high stabilities. The criteria for the selection of clusters sufficiently stable to form a cluster material are discussed
Alignment of a Laser Dye in the Channels of the AlPO<sub>4</sub>-5 Molecular Sieve
Solid-state laser systems based on molecular sieves may not be far away. Here, the incorporation and linear alignment of a pyridine-based laser dye in the channels of AlPO4-5 is reported and the spectroscopic properties of the composite are investigated. A first indication that AlPO4-5–laser dye composite crystals show laser action is demonstrated for microcrystals with a highly intergrown shap
Ordered porous materials as media for the organization of matter on the nanoscale
Ordered porous inorganic compounds can now be synthesized with pore sizes between 0.3 nm and several tens of nanometers. The sharp pore size distribution of such materials and the ordered pore arrangement open possibilities for using them to organize matter on the nanometer scale. This overview highlights different aspects of this topic, using four selected examples: the spatial organization of molecules with high molecular hyperpolarizability to create a frequency-doubling element; the encapsulation of a laser dye which results in a new class of solid-state lasers; the encapsulation of small metal clusters in mesoporous ordered oxides; and the encapsulation of semiconductor clusters in such oxides
- …