Sub-Zero Alteration in an Isotopically Heavy Brine Preserved in a Pristine H Chondrite Xenolith

Introduction: Brecciated H chondrites host a variety of xenoliths, including unshocked, phyllo- silicate-rich carbonaceous chondrites (CCs). The brecciated H chondrite Zag (H3-6) is one of two chondrites to host macroscopic (1 - 5mm), xenolithic crystals of halite (NaCl) with aqueous fluid inclusions and organics. A ~1cm CC xenolith in Zag (Zag clast) has mineralogy similar to CI chondrites, but it has a unique bulk oxygen isotopic composition among all meteorites ((exp 17)O = 1.49 0.04 , (exp 18)O = 22.38 0.17 ). The Zag clast encloses halite in its matrix, linking the coarse, matrix halite and the xenolith to the same parent object, suggested to be hydrovolcanically active. Its bulk C and N contents are the highest among chondrites and bulk (exp 15)N is similar to CR chondrites and Bells. Insoluble organic material (IOM) in the Zag clast has D and (exp 15)N hotspots, also similar to CR chondrites and Bells (C2-ung.). We provide further isotopic characterization of the Zag clast to constrain the formation temperature and origin of its primary and secondary components

Clasts in the CM2 carbonaceous chondrite Lonewolf Nunataks 94101: evidence for aqueous alteration prior to complex mixing

Clasts in the CM2 carbonaceous chondrite Lonewolf Nunataks (LON) 94101 have been characterized using scanning and transmission electron microscopy and electron microprobe analysis to determine their degrees of aqueous alteration, and the timing of alteration relative to incorporation of clasts into the host. The provenance of the clasts, and the mechanism by which they were incorporated and mixed with their host material are also considered. Results show that at least five distinct types of clasts occur in LON 94101, of which four have been aqueously altered to various degrees and one is largely anhydrous. The fact that they have had different alteration histories implies that the main part of aqueous activity occurred prior to the mixing and assimilation of the clasts with their host. Further, the presence of such a variety of clasts suggests complex mixing in a dynamic environment involving material from various sources. Two of the clasts, one containing approximately 46 vol% carbonate and the other featuring crystals of pyrrhotite up to approximately 1 mm in size, are examples of unusual lithologies and indicate concentration of chemical elements in discrete areas of the parent body(ies), possibly by flow of aqueous solutions

The solar oxygen-isotopic composition: Predictions and implications for solar nebula processes

The outer layers of the Sun are thought to preserve the average isotopic and chemical composition of the solar system. The solar O-isotopic composition is essentially unmeasured, though models based on variations in meteoritic materials yield several predictions. These predictions are reviewed and possible variations on these predictions are explored. In particular, the two-component mixing model of Clayton and Mayeda (1984) (slightly revised here) predicts solar compositions to lie along an extension of the calcium-aluminum-rich inclusion (CAI) ^(16)O line between (δ^(18)O, δ^(17)O) = (16.4, 11.4)%0 and (12.3, 7.5)%0. Consideration of data from ordinary chondrites suggests that the range of predicted solar composition should extend to slightly lower δ^(18)O values. The predicted solar composition is critically sensitive to the solid/gas ratio in the meteorite-forming region, which is often considered to be significantly enriched over solar composition. A factor of two solid/gas enrichment raises the predicted solar (δ^(18)O, δ^(17)O) values along an extension of the CAI ^(16)O line to (33, 28)%0. The model is also sensitive to the nebular O gas phase. If conversion of most of the gaseous O from CO to H_2O occurred at relatively low temperatures and was incomplete at the time of CM aqueous alteration, the predicted nebular gas composition (and hence the solar composition) would be isotopically heavier along a slope 1/2 line. The likelihood of having a single solid nebular O component is discussed. A distribution of initial solid compositions along the CAI ^(16)O line (rather than simply as an end-member) would not significantly change the predictions above in at least one scenario. Even considering these variations within the mixing model, the predicted range of solar compositions is distinct from that expected if the meteoritic variations are due to non-mass-dependent fractionation. Thus, a measurement of the solar O composition to a precision of several permil would clearly distinguish between these theories and should clarify a number of other important issues regarding solar system formation

Al-Mg systematics of CAIs, POI, and ferromagnesian chondrules from Ningqiang

We have made aluminum-magnesium isotopic measurements on 4 melilite-bearing calcium-aluminum-rich inclusions (CAIs), 1 plagioclase-olivine inclusion (POI), and 2 ferromagnesian chondrules from the Ningqiang carbonaceous chondrite. All of the CAIs measured contain clear evidence for radiogenic ^(26)Mg^* from the decay of ^(26)Al (τ = 1.05 Ma). Although the low Al/Mg ratios of the melilites introduce large uncertainties, the inferred initial ^(26)Al/^(27)Al ratios for the CAIs are generally consistent with the value of 5 x 10^(−5). There is clear evidence of ^(26)Al^* in one POI and two chondrules, but with considerable uncertainties in the value of (^(26)Al/^(27)Al)0. The (^(26)Al/^(27)Al)_0 ratios for the POI and the chondrules are 0.3–0.6 x 10^(−5), roughly an order of magnitude lower than the canonical value. Ningqiang shows very little evidence of metamorphism as a bulk object and the (^(26)Al/^(27)Al)_0 ratios in its refractory inclusions and chondrules are consistent with those found in other unmetamorphosed chondrites of several different classes. Our observations and those of other workers support the view that ^(26)Al was widely and approximately homogeneously distributed throughout the condensed matter of the solar system. The difference in (^(26)Al/^(27)Al)0 between CAIs and less refractory materials seems reasonably interpreted in terms of a ∼2 million year delay between the formation of CAIs and the onset of formation of less refractory objects. The POI shows clear differences in ^(25)Mg/^(24)Mg between its constituent spinels and olivine, which confirms that they are partially reprocessed material from different sources that were rapidly quenched

Isotopes of H, N, and O in H Chondrite Xenoliths

Brecciated H chrondites host a variety of xenoliths, including unshocked, phyllosilate-rich carbonaceous chondrites (CCs) [1-2]. The brecciated H chondrite Zag (H3-6) is one of two chondrites to host macroscopic (1 - 5mm), xenolithic crystals of halite (NaCl) with aqueous fluid inclusions and organics [3-4]. A ~1cm CC xenolith in Zag (Zag clast) also encloses halite in its matrix, linking the halite and the xenolith to the same parent object. The Zag clast has mineralogy similar to CI chondrites, but it has a unique bulk oxygen isotopic composition among all meteorites (17O = 1.49 0.04 , 18O = 22.38 0.17 ) and is therefore derived from a uniquely sampled parent object [5-6]. Organics have high bulk D and 15N values with isotopic "hotspots" similar to organics in CR chondrites and Bells (C2-ung.) [6-7]. Bulk 15N is also similar to CRs and Bells [7]. We provide further isotopic characterization of the Zag clast to constrain the formation temperature and origin of its primary and secondary components

An Ion Microprobe Study of CAIs from CO3 Meteorites

When attempting to interpret the history of Ca, Al-rich inclusions (CAIs) it is often difficult to distinguish between primary features inherited from the nebula and those produced during secondary processing on the parent body. We have undertaken a systematic study of CAIs from 10 CO chondrites, believed to represent a metamorphic sequence [e.g., 1], with the goal of distinguishing primary and secondary features. ALHA 77307 (3.0), Colony (3.0), Kainsaz (3.1), Felix (3.2), ALH 82101 (3.3), Omans (3.3), Lancé (3.4), ALHA 77003 (3.5), Warrenton (3.6), and Isna (3. 7) were examined by SEM and optical microscopy. We have identified 141 CAIs within these samples, and studied in detail the petrology of 34 inclusions

Do SiC grains in Orgueil differ from those in Murchison?

Studies of individual presolar SiC grains have shown that most are enriched in Si-29, Si-30, and C-13, and depleted in N-15, compared to solar-system abundances and that many have large excesses of Mg-26, most plausibly from in situ decay of Al-26. Stone et al., observed that Si from a family of platy SiC grains define a linear array on a 3-isotope plot that does not pass through normal solar-system Si. In contrast, Si-isotope data from over 100 3-4 micron SiC grains from Murchison from an elongate ellipse enclosing the Stone et al. linear array but also including 'normal' solar-system Si. To investigate whether this difference in Si isotopes indicates different populations of SiC in the two meteorites and to improve the characterization of Orgueil SiC, we used the PANURGE ion microprobe to measure Si, C, N, and Mg isotopes and Al and Na concentrations in a suite of 2-5 micron SiC grains from a new sample of Orgueil

128Xe and 130Xe: Testing He-shell burning in AGB stars

The s-process branching at 128I has been investigated on the basis of new, precise experimental (n,g) cross sections for the s-only isotopes 128Xe and 130Xe. This branching is unique, since it is essentially determined by the temperature- and density-sensitive stellar decay rates of 128I and only marginally affected by the specific stellar neutron flux. For this reason it represents an important test for He-shell burning in AGB stars. The description of the branching by means of the complex stellar scenario reveals a significant sensitivity to the time scales for convection during He shell flashes, thus providing constraints for this phenomenon. The s-process ratio 128Xe/130Xe deduced from stellar models allows for a (9+-3)% p-process contribution to solar 128Xe, in agreement with the Xe-S component found in meteoritic presolar SiC grains.Comment: 24 pages, 9 figures, accepted for publication in Astophysical Journa