Preliminary results of corrosion monitoring studies of carbon steel overpack exposed to supercontainer concrete buffer

The supercontainer (SC) is the reference concept for the postconditioning of vitrified high level radioactive waste and spent fuel in Belgium. It is designed with a concrete buffer completely surrounding a carbon steel overpack. A half-scale (HST-2) experiment was set up to measure the instantaneous uniform corrosion rate, representative of the initial oxic phase, in situ. The test setup has the same diameter as a full size SC, but it is limited in height to approximately half of a real SC. The corrosion rate of carbon steel is measured in four ways: weight loss measurements (carbon steel coupons), corrosion sensor based on linear polarisation resistance, corrosion sensor based on multisine electrochemical impedance spectroscopy and corrosion sensor based on single sine electrochemical impedance spectroscopy coupled to a unique analytical method. This paper presents the preliminary results of the corrosion rates measured with these independent methods.Fil: Kursten, B.. SCK•CEN; BélgicaFil: Druyts, F.. SCK•CEN; BélgicaFil: Areias, L.. SCK•CEN; BélgicaFil: Ingelgem, Y. van. Vrije Unviversiteit Brussel; BélgicaFil: De Wilde, D.. Vrije Unviversiteit Brussel; BélgicaFil: G. Nieubourg. Vrije Unviversiteit Brussel; BélgicaFil: Duffó, Gustavo Sergio. Comisión Nacional de Energía Atómica. Gerencia del Área de Energía Nuclear. Unidad de Actividad de Materiales (CAC); Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas; ArgentinaFil: Bataillon, C.. Commissariat à l'Énergie Atomique. Laboratoire d’Etude de la Corrosion Aqueuse; Franci