Randomly Charged Polymers, Random Walks, and Their Extremal Properties

Motivated by an investigation of ground state properties of randomly charged polymers, we discuss the size distribution of the largest Q-segments (segments with total charge Q) in such N-mers. Upon mapping the charge sequence to one--dimensional random walks (RWs), this corresponds to finding the probability for the largest segment with total displacement Q in an N-step RW to have length L. Using analytical, exact enumeration, and Monte Carlo methods, we reveal the complex structure of the probability distribution in the large N limit. In particular, the size of the longest neutral segment has a distribution with a square-root singularity at l=L/N=1, an essential singularity at l=0, and a discontinuous derivative at l=1/2. The behavior near l=1 is related to a another interesting RW problem which we call the "staircase problem". We also discuss the generalized problem for d-dimensional RWs.Comment: 33 pages, 19 Postscript figures, RevTe

A Model Ground State of Polyampholytes

The ground state of randomly charged polyampholytes is conjectured to have a structure similar to a necklace, made of weakly charged parts of the chain, compacting into globules, connected by highly charged stretched `strings'. We suggest a specific structure, within the necklace model, where all the neutral parts of the chain compact into globules: The longest neutral segment compacts into a globule; in the remaining part of the chain, the longest neutral segment (the 2nd longest neutral segment) compacts into a globule, then the 3rd, and so on. We investigate the size distributions of the longest neutral segments in random charge sequences, using analytical and Monte Carlo methods. We show that the length of the n-th longest neutral segment in a sequence of N monomers is proportional to N/(n^2), while the mean number of neutral segments increases as sqrt(N). The polyampholyte in the ground state within our model is found to have an average linear size proportional to sqrt(N), and an average surface area proportional to N^(2/3).Comment: 8 two-column pages. 5 eps figures. RevTex. Submitted to Phys. Rev.

The Phase Diagram of Crystalline Surfaces

We report the status of a high-statistics Monte Carlo simulation of non-self-avoiding crystalline surfaces with extrinsic curvature on lattices of size up to $128^2$ nodes. We impose free boundary conditions. The free energy is a gaussian spring tethering potential together with a normal-normal bending energy. Particular emphasis is given to the behavior of the model in the cold phase where we measure the decay of the normal-normal correlation function.Comment: 9 pages latex (epsf), 4 EPS figures, uuencoded and compressed. Contribution to Lattice '9

Synergetic modelling of the Russian Federation’s energy system parameters

The energy system in any country is the basis of the whole economy. The level of its development largely determines the quantity and quality of economic entities, periods of economic growth, fall and stagnation. A high percentage of the power-deficient municipalities in the Russian Federation shows the substantive issues in this sphere that carries a threat to the energy security of the state. One of the promising trends for enhancing the energy security is the renewable energy sources (RES). Their use has the obvious benefits: it provides electricity to power-deficient and inaccessible areas, contributes to the introduction and spread of new technologies, thus solving the important social and economic problem. At that, it is important to determine the optimum ratio using of the recovery of renewable and conventional energy sources (CES). One of the main challenges in this regard is to build a model that adequately reflects the ratio of renewable and conventional energy sources in the Russian energy system. The paper presents the results of a synergistic approach to the construction of such a model. The Lotka- Volterra model was the main instrument used, which allowed to study a behavior pattern of the considered systems on the basis of the simplified regularities. It was found that the best possible qualitative “jump” in the Russian energy sector was in 2008. The calculations allowed to investigate the behavior of the Russian energy system with the variation of the initial conditions and to assess the validity of the targets for the share of electricity produced through the use of renewable energy in the total electric power of the country

Collapse of Randomly Self-Interacting Polymers

We use complete enumeration and Monte Carlo techniques to study self--avoiding walks with random nearest--neighbor interactions described by $v_0q_iq_j$, where $q_i=\pm1$ is a quenched sequence of ``charges'' on the chain. For equal numbers of positive and negative charges ($N_+=N_-$), the polymer with $v_0>0$ undergoes a transition from self--avoiding behavior to a compact state at a temperature $\theta\approx1.2v_0$. The collapse temperature $\theta(x)$ decreases with the asymmetry $x=|N_+-N_-|/(N_++N_-)$Comment: 8 pages, TeX, 4 uuencoded postscript figures, MIT-CMT-

A coding problem for pairs of subsets

Let $X$ be an $n$--element finite set, $0<k\leq n/2$ an integer. Suppose that $\{A_1,A_2\}$ and $\{B_1,B_2\}$ are pairs of disjoint $k$-element subsets of $X$ (that is, $|A_1|=|A_2|=|B_1|=|B_2|=k$, $A_1\cap A_2=\emptyset$, $B_1\cap B_2=\emptyset$). Define the distance of these pairs by $d(\{A_1,A_2\} ,\{B_1,B_2\})=\min \{|A_1-B_1|+|A_2-B_2|, |A_1-B_2|+|A_2-B_1|\}$. This is the minimum number of elements of $A_1\cup A_2$ one has to move to obtain the other pair $\{B_1,B_2\}$. Let $C(n,k,d)$ be the maximum size of a family of pairs of disjoint subsets, such that the distance of any two pairs is at least $d$. Here we establish a conjecture of Brightwell and Katona concerning an asymptotic formula for $C(n,k,d)$ for $k,d$ are fixed and $n\to \infty$. Also, we find the exact value of $C(n,k,d)$ in an infinite number of cases, by using special difference sets of integers. Finally, the questions discussed above are put into a more general context and a number of coding theory type problems are proposed.Comment: 11 pages (minor changes, and new citations added

Probability distributions for polymer translocation

We study the passage (translocation) of a self-avoiding polymer through a membrane pore in two dimensions. In particular, we numerically measure the probability distribution Q(T) of the translocation time T, and the distribution P(s,t) of the translocation coordinate s at various times t. When scaled with the mean translocation time , Q(T) becomes independent of polymer length, and decays exponentially for large T. The probability P(s,t) is well described by a Gaussian at short times, with a variance that grows sub-diffusively as t^{\alpha} with \alpha~0.8. For times exceeding , P(s,t) of the polymers that have not yet finished their translocation has a non-trivial stable shape.Comment: 5 pages, 4 figure

Ground States of Two-Dimensional Polyampholytes

We perform an exact enumeration study of polymers formed from a (quenched) random sequence of charged monomers $\pm q_0$, restricted to a 2-dimensional square lattice. Monomers interact via a logarithmic (Coulomb) interaction. We study the ground state properties of the polymers as a function of their excess charge $Q$ for all possible charge sequences up to a polymer length N=18. We find that the ground state of the neutral ensemble is compact and its energy extensive and self-averaging. The addition of small excess charge causes an expansion of the ground state with the monomer density depending only on $Q$. In an annealed ensemble the ground state is fully stretched for any excess charge $Q>0$.Comment: 6 pages, 6 eps figures, RevTex, Submitted to Phys. Rev.

Collineation group as a subgroup of the symmetric group

Let $\Psi$ be the projectivization (i.e., the set of one-dimensional vector subspaces) of a vector space of dimension $\ge 3$ over a field. Let $H$ be a closed (in the pointwise convergence topology) subgroup of the permutation group $\mathfrak{S}_{\Psi}$ of the set $\Psi$. Suppose that $H$ contains the projective group and an arbitrary self-bijection of $\Psi$ transforming a triple of collinear points to a non-collinear triple. It is well-known from \cite{KantorMcDonough} that if $\Psi$ is finite then $H$ contains the alternating subgroup $\mathfrak{A}_{\Psi}$ of $\mathfrak{S}_{\Psi}$. We show in Theorem \ref{density} below that $H=\mathfrak{S}_{\Psi}$, if $\Psi$ is infinite.Comment: 9 page