FOULING DURING THE USE OF ‘FRESH’ WATER AS COOLANT- THE DEVELOPMENT OF A ‘USER GUIDE’

IHS ESDU recently published its latest ‘User Guide’ to fouling in heat exchange systems, for systems with fresh water as the coolant. ESDU 07006 [1] is the third in a group, following the development of the Crude Oil Fouling User Guide [2] issued in 2000 and the Seawater Fouling User Guide [3] issued in 2004. ESDU 07006 was developed by IHS ESDU over a period of five years under the guidance of the Oil Industry Fouling Working Party, a collaborative team of oil refiners, heat transfer equipment and services suppliers and Universities. It provides designers and operators of cooling water facilities with a practical source of guidance on the occurrence, the mechanisms and the mitigation of fresh water fouling in these systems. IHS ESDU’s Oil Industry Fouling Working Party was formed in recognition of the huge economic and environmental importance of heat exchanger fouling and the potential benefits that can accrue from better understanding of mitigation strategies. Work is now underway on reboiler and FCCU fouling. The development of the User Guide ESDU 07006 is discussed in this paper and its technical content is summarized

Effect of vessel wettability on the foamability of "ideal" surfactants and "real-world" beer heads

The ability to tailor the foaming properties of a solution by controlling its chemical composition is highly desirable and has been the subject of extensive research driven by a range of applications. However, the control of foams by varying the wettability of the foaming vessel has been less widely reported. This work investigates the effect of the wettability of the side walls of vessels used for the in situ generation of foam by shaking aqueous solutions of three different types of model surfactant systems (non-ionic, anionic and cationic surfactants) along with four different beers (Guinness Original, Banks’s Bitter, Bass No 1 and Harvest Pale). We found that hydrophilic vials increased the foamability only for the three model systems but increased foam stability for all foams except the model cationic system. We then compared stability of beer foams produced by shaking and pouring and demonstrated weak qualitative agreement between both foam methods. We also showed how wettability of the glass controls bubble nucleation for beers and champagne and used this effect to control exactly where bubbles form using simple wettability patterns

Breaking quantum linearity: constraints from human perception and cosmological implications

Resolving the tension between quantum superpositions and the uniqueness of the classical world is a major open problem. One possibility, which is extensively explored both theoretically and experimentally, is that quantum linearity breaks above a given scale. Theoretically, this possibility is predicted by collapse models. They provide quantitative information on where violations of the superposition principle become manifest. Here we show that the lower bound on the collapse parameter lambda, coming from the analysis of the human visual process, is ~ 7 +/- 2 orders of magnitude stronger than the original bound, in agreement with more recent analysis. This implies that the collapse becomes effective with systems containing ~ 10^4 - 10^5 nucleons, and thus falls within the range of testability with present-day technology. We also compare the spectrum of the collapsing field with those of known cosmological fields, showing that a typical cosmological random field can yield an efficient wave function collapse.Comment: 13 pages, LaTeX, 3 figure

Spectral Measures and Generating Series for Nimrep Graphs in Subfactor Theory II: SU(3)

We complete the computation of spectral measures for SU(3) nimrep graphs arising in subfactor theory, namely the SU(3) ADE graphs associated with SU(3) modular invariants and the McKay graphs of finite subgroups of SU(3). For the SU(2) graphs the spectral measures distill onto very special subsets of the semicircle/circle, whilst for the SU(3) graphs the spectral measures distill onto very special subsets of the discoid/torus. The theory of nimreps allows us to compute these measures precisely. We have previously determined spectral measures for some nimrep graphs arising in subfactor theory, particularly those associated with all SU(2) modular invariants, all subgroups of SU(2), the torus, SU(3), and some SU(3) graphs.Comment: 38 pages, 21 figure

Locality and topology with fat link overlap actions

We study the locality and topological properties of fat link clover overlap (FCO) actions. We find that a small amount of fattening (2-4 steps of APE or 1 step of HYP) already results in greatly improved properties compared to the Wilson overlap (WO). We present a detailed study of the localisation of the FCO and its connection to the density of low modes of $A^\dagger A$. In contrast to the Wilson overlap, on quenched gauge backgrounds we do not find any dependence of the localization of the FCO on the gauge coupling. This suggests that the FCO remains local in the continuum limit. The FCO also faithfully reproduces the zero mode wave functions of typical lattice instantons, not like the Wilson overlap. After a general discussion of different lattice definitions of the topological charge we also show that the FCO together with the Boulder charge are likely to satisfy the index theorem in the continuum limit. Finally, we present a high statistics computation of the quenched topological susceptibility with the FCO action.Comment: 19 pages, LaTe

Density functional study of elastic and vibrational properties of the Heusler-type alloys Fe2_2VAl and Fe2_2VGa

The structural and elastic properties as well as phonon-dispersion relations of the Heusler-type alloys Fe$_2$VAl and Fe$_2$VGa are computed using density-functional and density-functional perturbation theory within the generalized-gradient approximation. The calculated equilibrium lattice constants agree well with the experimental values. The elastic constants of Fe$_2$VAl and Fe$_2$VGa are predicted for the first time. From the elastic constants the shear modulus, Young's modulus, Poisson's ratio, sound velocities and Debye temperatures are obtained. By analyzing the ratio between the bulk and shear modulii, we conclude that both Fe$_2$VAl and Fe$_2$VGa are brittle in nature. The computed phonon-dispersion relation shows that both compounds are dynamically stable in the L1$_2$ structure without any imaginary phonon frequencies. The isomer shifts of Fe in the two compounds are discussed in terms of the Fe s partial density of states, which reveal larger ionicity/less hybridization in Fe$_2$VGa than in Fe$_2$VAl. For the same reason the Cauchy pressure is negative in Fe$_2$VAl but positive in Fe$_2$VGaComment: 14 pages, 3 figure

Ab-initio study of model guanine assemblies: The role of pi-pi coupling and band transport

Several assemblies of guanine molecules are investigated by means of first-principle calculations. Such structures include stacked and hydrogen-bonded dimers, as well as vertical columns and planar ribbons, respectively, obtained by periodically replicating the dimers. Our results are in good agreement with experimental data for isolated molecules, isolated dimers, and periodic ribbons. For stacked dimers and columns, the stability is affected by the relative charge distribution of the pi orbitals in adjacent guanine molecules. pi-pi coupling in some stacked columns induces dispersive energy bands, while no dispersion is identified in the planar ribbons along the connections of hydrogen bonds. The implications for different materials comprised of guanine aggregates are discussed. The bandstructure of dispersive configurations may justify a contribution of band transport (Bloch type) in the conduction mechanism of deoxyguanosine fibres, while in DNA-like configurations band transport should be negligible.Comment: 21 pages, 6 figures, 3 tables, to be published in Phys. Rev.