4,709 research outputs found
Entanglement of dipolar coupling spins
Entanglement of dipole-dipole interacting spins 1/2 is usually investigated
when the energy of interaction with an external magnetic field (the Zeeman
energy) is greater than the energy of dipole interactions by three orders.
Under this condition only a non-equilibrium state of the spin system, realized
by pulse radiofrequence irradiations, results in entanglement. The present
paper deals with the opposite case: the dipolar interaction energy is the order
of magnitude or even larger than the Zeeman one. It was shown that entanglement
appears under the thermodynamic equilibrium conditions and the concurrence
reaches the maximum when the external field is directed perpendicular to the
vector connecting the nuclei. For this direction of the field and a system of
two spins with the Hamiltonian accounting the realistic dipole-dipole
interactions in low external magnetic field, the exact analytical expression
for concurrence was also obtained. The condition of the entanglement appearance
and the dependence of concurrence on the external magnetic field, temperature,
and dipolar coupling constant were studied.Comment: 9 pages, 5 figure
Low temperature MQ NMR dynamics in dipolar ordered state
We investigate analytically and numerically the Multiple Quantum (MQ) NMR
dynamics in dipolar ordered spin systems of nuclear spins 1/2 at a low
temperatures. We suggest two different methods of MQ NMR. One of them is based
on the measurement of the dipolar energy. The other method uses an additional
resonance ({\pi}/4)_{y}-pulse after the preparation period of the standard MQ
NMR experiment in solids and allows one to measure the Zeeman energy. The both
considered methods are sensitive to the contribution of remote spins in the
interaction and to the spin system structure. The QS method is sensitive to the
spin number in the molecule while the PS method gives very similar time
dependencies of the intensities of MQ coherences for different spin numbers. It
is shown that the use of the dipolar ordered initial state has the advantage of
exciting the highest order MQ coherences in clusters of 4m identical spins,
where m=1,2,3..., that is impossible to do with the standard MQ method. MQ NMR
methods based on the dipolar ordered initial states at low temperatures
complement the standard NMR spectroscopy for better studying structures and
dynamic processes in solids.Comment: 12 pages, 4 figures will be published in Solid State Nuclear Magnetic
Resonance (2013
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Multiple Quantum NMR and Entanglement Dynamics in Dipolar Coupling Spin
We investigate numerically the time dependence of the multiple quantum
coherences and entanglement in linear chains up to nine nuclear spins of 1/2
coupled by the dipole-dipole interactions. Two models are considered: (1) a
spin chain with nearest-neighbor dipole -dipole interactions; (2) a more
realistic model with interactions between all spins. It is shown that the
entangled states appear between remote particles which do not interact directly
(model 1), while the interaction between all spins (model 2) not always results
in entanglement between remote spins.Comment: 14 pages, 3 figures. accepted for publication in Physical Review
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