Two-Photon Spectroscopy Between States of Opposite Parities

Magnetic- and electric-dipole two-photon absorption (MED-TPA), recently introduced as a new spectroscopic technique for studying transitions between states of opposite parities, is investigated from a theoretical point of view. A new approximation, referred to as {\it weak quasi-closure approximation}, is used together with symmetry adaptation techniques to calculate the transition amplitude between states having well-defined symmetry properties. Selection rules for MED-TPA are derived and compared to selection rules for parity-forbidden electric-dipole two-photon absorption (ED-TPA).Comment: 7 pages, Revtex File, to be published in Physical Review

Phase operators, temporally stable phase states, mutually unbiased bases and exactly solvable quantum systems

We introduce a one-parameter generalized oscillator algebra A(k) (that covers the case of the harmonic oscillator algebra) and discuss its finite- and infinite-dimensional representations according to the sign of the parameter k. We define an (Hamiltonian) operator associated with A(k) and examine the degeneracies of its spectrum. For the finite (when k < 0) and the infinite (when k > 0 or = 0) representations of A(k), we construct the associated phase operators and build temporally stable phase states as eigenstates of the phase operators. To overcome the difficulties related to the phase operator in the infinite-dimensional case and to avoid the degeneracy problem for the finite-dimensional case, we introduce a truncation procedure which generalizes the one used by Pegg and Barnett for the harmonic oscillator. This yields a truncated generalized oscillator algebra A(k,s), where s denotes the truncation order. We construct two types of temporally stable states for A(k,s) (as eigenstates of a phase operator and as eigenstates of a polynomial in the generators of A(k,s)). Two applications are considered in this article. The first concerns physical realizations of A(k) and A(k,s) in the context of one-dimensional quantum systems with finite (Morse system) or infinite (Poeschl-Teller system) discrete spectra. The second deals with mutually unbiased bases used in quantum information.Comment: Accepted for publication in Journal of Physics A: Mathematical and Theoretical as a pape

Aggregation number distributions and mesoglobules in dilute solutions of diblock and triblock copolymers

We investigate the aggregation number and size distributions for inter-molecular clusters of amphiphilic diblock and triblock copolymers in poor solvent at very low concentrations. Diblocks and triblocks with hydrophilic ends are shown to possess narrow distributions corresponding to formation of monodispersed mesoglobules. Diblocks with hydrophobic ends are found to produce inter-cluster multimers due to bridging by the hydrophilic middle blocks, resulting in polydisperse distributions. Implications of these observations for preparation of monodispersed nanoparticles and, potentially, understanding of the quaternary structure of proteins are discussed.Comment: 4 pages, 4 PS figures. Accepted for publication in EP

Scaling theory of DNA confined in nanochannels and nanoslits

A scaling analysis is presented of the statistics of long DNA confined in nanochannels and nanoslits. It is argued that there are several regimes in between the de Gennes and Odijk limits introduced long ago. The DNA chain folds back on itself giving rise to a global persistence length which may be very large owing to entropic deflection. Moreover, there is an orientational excluded-volume effect between the DNA segments imposed solely by the nanoconfinement. These two effects cause the chain statistics to be intricate leading to nontrivial power laws for the chain extension in the intermediate regimes. It is stressed that DNA confinement within nanochannels differs from that in nanoslits because the respective orientational excluded-volume effects are not the same.Comment: 5 pages, 1 figure Several corrections, some minor changes in the text and replacement of one referenc

Structure of bottle-brush brushes under good solvent conditions. A molecular dynamics study

We report a simulation study for bottle-brush polymers grafted on a rigid backbone. Using a standard coarse-grained bead-spring model extensive molecular dynamics simulations for such macromolecules under good solvent conditions are performed. We consider a broad range of parameters and present numerical results for the monomer density profile, density of the untethered ends of the grafted flexible backbones and the correlation function describing the range that neighboring grafted bottle-brushes are affected by the presence of the others due to the excluded volume interactions. The end beads of the flexible backbones of the grafted bottle-brushes do not access the region close to the rigid backbone due to the presence of the side chains of the grafted bottle-brush polymers, which stretch further the chains in the radial directions. Although a number of different correlation lengths exist as a result of the complex structure of these macromolecules, their properties can be tuned with high accuracy in good solvents. Moreover, qualitative differences with "typical" bottle-brushes are discussed. Our results provide a first approach to characterizing such complex macromolecules with a standard bead spring model.Comment: To appear in Journal of Physics Condensed Matter (2011

Scaling of Entropic Shear Rigidity

The scaling of the shear modulus near the gelation/vulcanization transition is explored heuristically and analytically. It is found that in a dense melt the effective chains of the infinite cluster have sizes that scale sub-linearly with their contour length. Consequently, each contributes k_B T to the rigidity, which leads to a shear modulus exponent d\nu. In contrast, in phantom elastic networks the scaling is linear in the contour length, yielding an exponent identical to that of the random resistor network conductivity, as predicted by de Gennes'. For non-dense systems, the exponent should cross over to d\nu when the percolation length becomes much larger than the density-fluctuation length.Comment: 4 pages, 2 eps figure

Entropic Elasticity of Phantom Percolation Networks

A new method is used to measure the stress and elastic constants of purely entropic phantom networks, in which a fraction $p$ of neighbors are tethered by inextensible bonds. We find that close to the percolation threshold $p_c$ the shear modulus behaves as $(p-p_c)^f$, where the exponent $f\approx 1.35$ in two dimensions, and $f\approx 1.95$ in three dimensions, close to the corresponding values of the conductivity exponent in random resistor networks. The components of the stiffness tensor (elastic constants) of the spanning cluster follow a power law $\sim(p-p_c)^g$, with an exponent $g\approx 2.0$ and 2.6 in two and three dimensions, respectively.Comment: submitted to the Europhys. Lett., 7 pages, 5 figure

Effective interactions between star polymers

We study numerically the effective pair potential between star polymers with equal arm lengths and equal number $f$ of arms. The simulations were done for the soft core Domb-Joyce model on the simple cubic lattice, to minimize corrections to scaling and to allow for an unlimited number of arms. For the sampling, we used the pruned-enriched Rosenbluth method (PERM). We find that the potential is much less soft than claimed in previous papers, in particular for $f\gg 1$. While we verify the logarithmic divergence of $V(r)$, with $r$ being the distance between the two cores, predicted by Witten and Pincus, we find for $f>20$ that the Mayer function is hardly distinguishable from that for a Gaussian potential.Comment: 5 pages, 5 figure

La prévision des précipitations par recherche d'analogues : état de l'art et perspectives

La prévision des précipitations par analogie, adaptée des sorties de modèles numériques de prévision, s'est améliorée ces dix dernières années et est actuellement implémentée opérationnellement dans diverses infrastructures françaises. Le premier objectif de cette étude est de dresser l'état de l'art de cette approche. L'application de cette méthode nécessite une base de données contenant les champs des variables qui permettent de caractériser les situations météorologiques passées. Etant donné qu'il existe deux archives de génération différente (réanalyses ERA-40 et NCEP/NCAR), la sensibilité de cette méthode de prévision au choix de l'archive a été étudiée. Les résultats révèlent une faible sensibilité, même si de manière générale les performances sont légèrement supérieures avec l'archive ERA-40, notamment pour les événements pluvieux extrêmes. Enfin, des perspectives d'amélioration de la méthode susceptibles d'être exploitées à court terme sont évoquées. / Precipitation forecasting based on an adaptation of model outputs through an analog sorting technique has been improved for around ten years. The method runs operationally in several French institutions. First, this short paper presents the state of the art of this approach and the more recent developments. Second, a sensitivity analysis to the choice of the database from which the variables that characterise the past meteorological situations are extracted is performed. Two available archives are tested (ERA-40 and NCEP/NCAR re-analyses). The results show that despite the performances obtained with the ERA-40 database are slightly better, especially for heavy rainfall events, the sensitivity is weak. Finally, further ways for improvement that could be investigated are suggested