Cooperative Robustness to Static Disorder: Superradiance and localization in a nanoscale ring to model natural light-harvesting systems

We analyze a 1-d ring structure composed of many two-level systems, in the limit where only one excitation is present. The two-level systems are coupled to a common environment, where the excitation can be lost, which induces super and subradiant behavior, an example of cooperative quantum coherent effect. We consider time-independent random fluctuations of the excitation energies. This static disorder, also called inhomogeneous broadening in literature, induces Anderson localization and is able to quench Superradiance. We identify two different regimes: $i)$ weak opening, in which Superradiance is quenched at the same critical disorder at which the states of the closed system localize; $ii)$ strong opening, with a critical disorder strength proportional to both the system size and the degree of opening, displaying robustness of cooperativity to disorder. Relevance to photosynthetic complexes is discussed.Comment: 12 pages, 7 figs., Superradiance, Anderson Localization, Cooperative effects. Accepted for publication in Phys. Rev.

Optimal efficiency of quantum transport in a disordered trimer

Disordered quantum networks, as those describing light-harvesting complexes, are often characterized by the presence of peripheral ring-like structures, where the excitation is initialized, and inner reaction centers (RC), where the excitation is trapped. The peripheral rings display coherent features: their eigenstates can be separated in the two classes of superradiant and subradiant states. Both are important to optimize transfer efficiency. In the absence of disorder, superradiant states have an enhanced coupling strength to the RC, while the subradiant ones are basically decoupled from it. Static on-site disorder induces a coupling between subradiant and superradiant states, creating an indirect coupling to the RC. The problem of finding the optimal transfer conditions, as a function of both the RC energy and the disorder strength, is very complex even in the simplest network, namely a three-level system. In this paper we analyze such trimeric structure choosing as initial condition a subradiant state, rather than the more common choice of an excitation localized on a site. We show that, while the optimal disorder is of the order of the superradiant coupling, the optimal detuning between the initial state and the RC energy strongly depends on system parameters: when the superradiant coupling is much larger than the energy gap between the superradiant and the subradiant levels, optimal transfer occurs if the RC energy is at resonance with the subradiant initial state, whereas we find an optimal RC energy at resonance with a virtual dressed state when the superradiant coupling is smaller than or comparable with the gap. The presence of dynamical noise, which induces dephasing and decoherence, affects the resonance structure of energy transfer producing an additional 'incoherent' resonance peak, which corresponds to the RC energy being equal to the energy of the superradiant state.Comment: This article shares part of the introduction and most of Section II with arXiv:1508.01613, the remaining parts of the two articles treat different problem

Shielding and localization in presence of long range hopping

We investigate a paradigmatic model for quantum transport with both nearest-neighbor and infinite range hopping coupling (independent of the position). Due to long range homogeneous hopping, a gap between the ground state and the excited states can be induced, which is mathematically equivalent to the superconducting gap. In the gapped regime, the dynamics within the excited states subspace is shielded from long range hopping, namely it occurs as if long range hopping would be absent. This is a cooperative phenomenon since shielding is effective over a time scale which diverges with the system size. We named this effect {\it Cooperative Shielding}. We also discuss the consequences of our findings on Anderson localization. Long range hopping is usually thought to destroy localization due to the fact that it induces an infinite number of resonances. Contrary to this common lore we show that the excited states display strong localized features when shielding is effective even in the regime of strong long range coupling. A brief discussion on the extension of our results to generic power-law decaying long range hopping is also given. Our preliminary results confirms that the effects found for the infinite range case are generic.Comment: 7 pages, 9 figur

The Topological Non-connectivity Threshold in quantum long-range interacting spin systems

Quantum characteristics of the Topological Non-connectivity Threshold (TNT), introduced in F.Borgonovi, G.L.Celardo, M.Maianti, E.Pedersoli, J. Stat. Phys., 116, 516 (2004), have been analyzed in the hard quantum regime. New interesting perspectives in term of the possibility to study the intriguing quantum-classical transition through Macroscopic Quantum Tunneling have been addressed.Comment: contribution to NEXTSIGMAPHI 3r

Open system of interacting fermions: Statistical properties of cross sections and fluctuations

Statistical properties of cross sections are studied for an open system of interacting fermions. The description is based on the effective non-Hermitian Hamiltonian that accounts for the existence of open decay channels preserving the unitarity of the scattering matrix. The intrinsic interaction is modelled by the two-body random ensemble of variable strength. In particular, the crossover region from isolated to overlapping resonances accompanied by the effect of the width redistribution creating super-radiant and trapped states is studied in detail. The important observables, such as average cross section, its fluctuations, autocorrelation functions of the cross section and scattering matrix, are very sensitive to the coupling of the intrinsic states to the continuum around the crossover. A detailed comparison is made of our results with standard predictions of statistical theory of cross sections, such as the Hauser-Feshbach formula for the average cross section and Ericson theory of fluctuations and correlations of cross sections. Strong deviations are found in the crossover region, along with the dependence on intrinsic interactions and degree of chaos inside the system.Comment: 13 pages, 11 figure

Optimal Dephasing for Ballistic Energy Transfer in Disordered Linear Chains

We study the interplay between dephasing, disorder, and openness on transport efficiency in a one-dimensional chain of finite length $N$, and in particular the beneficial or detrimental effect of dephasing on transport. The excitation moves along the chain by coherent nearest-neighbor hopping $\Omega$, under the action of static disorder $W$ and dephasing $\gamma$. The system is open due to the coupling of the last site with an external acceptor system (sink), where the excitation can be trapped with a rate $\Gamma_{\rm trap}$, which determines the opening strength. While it is known that dephasing can help transport in the localized regime, here we show that dephasing can enhance energy transfer even in the ballistic regime. Specifically, in the localized regime we recover previous results, where the optimal dephasing is independent of the chain length and proportional to $W$ or $W^2/\Omega$. In the ballistic regime, the optimal dephasing decreases as $1/N$ or $1/\sqrt{N}$ respectively for weak and moderate static disorder. When focusing on the excitation starting at the beginning of the chain, dephasing can help excitation transfer only above a critical value of disorder $W^{\rm cr}$, which strongly depends on the opening strength $\Gamma_{\rm trap}$. Analytic solutions are obtained for short chains.Comment: 16 pages, inlcuding 9 figure

Broken Ergodicity in classically chaotic spin systems

A one dimensional classically chaotic spin chain with asymmetric coupling and two different inter-spin interactions, nearest neighbors and all-to-all, has been considered. Depending on the interaction range, dynamical properties, as ergodicity and chaoticity are strongly different. Indeed, even in presence of chaoticity, the model displays a lack of ergodicity only in presence of all to all interaction and below an energy threshold, that persists in the thermodynamical limit. Energy threshold can be found analytically and results can be generalized for a generic XY model with asymmetric coupling.Comment: 6 pages, 3 figure

Transition from isolated to overlapping resonances in the open system of interacting fermions

We study the statistical properties of resonance widths and spacings in an open system of interacting fermions at the transition between isolated and overlapping resonances, where a radical change in the width distribution occurs. Our main interest is to reveal how this transition is influenced by the onset of chaos in the internal dynamics as the strength of random two-body interaction between the particles increases. We have found that in the region of overlapped resonances, the fluctuations of the widths (rather than their mean values) are strongly affected by the onset of an internal chaos. The results may be applied to the analysis of neutron cross sections, as well as in the physics of mesoscopic devices with strongly interacting electrons.Comment: 4 pages, 5 figures, corrected version, figures are replace

Evidence of diffusive fractal aggregation of TiO2 nanoparticles by femtosecond laser ablation at ambient conditions

The specific mechanisms which leads to the formation of fractal nanostructures by pulsed laser deposition remain elusive despite intense research efforts, motivated mainly by the technological interest in obtaining tailored nanostructures with simple and scalable production methods. Here we focus on fractal nanostructures of titanium dioxide, $TiO_2$, a strategic material for many applications, obtained by femtosecond laser ablation at ambient conditions. We model the fractal formation through extensive Monte Carlo simulations based on a set of minimal assumptions: irreversible sticking and size independent diffusion. Our model is able to reproduce the fractal dimensions and the area distributions of the nanostructures obtained in the experiments for different densities of the ablated material. The comparison of theory and experiment show that such fractal aggregates are formed after landing of the ablated material on the substrate surface by a diffusive mechanism. Finally we discuss the role of the thermal conductivity of the substrate and the laser fluence on the properties of the fractal nanostructures. Our results represent an advancement towards controlling the production of fractal nanostructures by pulsed laser deposition.Comment: 21 page