New urea-absorbing polymers for artificial kidney machines

Etherified polymer is made from modified cellulose derivative which is reacted with periodate. It will absorb 2 grams of urea per 100 grams of polymer. Indications are that polymers could be used to help remove uremic wastes in artificial kidneys, or they could be administered orally as therapy for uremia

Aldehyde-containing urea-absorbing polysaccharides

A novel aldehyde containing polymer (ACP) is prepared by reaction of a polysaccharide with periodate to introduce aldehyde groups onto the C2 - C3 carbon atoms. By introduction of ether and ester groups onto the pendant primary hydroxyl solubility characteristics are modified. The ACP is utilized to absorb nitrogen bases such as urea in vitro or in vivo

Analyses of the solid earth and ocean tidal perturbations on the orbits of the GEOS-1 and GEOS-2 satellites

The luni-solar tidal perturbations in the inclination of the GEOS-I and GEOS-II satellite orbits were analyzed for the solid Earth and ocean tide conditions. Precision reduced camera and TRANET Doppler observations spanning periods of over 600 days for each satellite were used to derive mean orbital elements. Perturbations due to the earth's gravity field, solar radiation pressure, and atmospheric drag were modelled, and the resulting inclination residuals were analyzed for tidal effects. The amplitudes of the observed total tidal effects were about 1.2 arc seconds (36 meters) in the inclination of GEOS-I and 4.5 arc seconds (135 meters) for GEOS-II. The solid earth tides were then modelled using earth tide measurements, earth rotation observations, and seismic data. The resulting inclination residuals were analyzed for ocean tide parameters. The derived parameters consist of one second degree coefficient and an accompanying phase angle in a spherical harmonic expansion of the ocean tidal potential for each tidal constituent. The results are presented

A comparison and evaluation of satellite derived positions of tracking stations

A comparison is presented of sets of satellite tracking station coordinate values published in the past few years by a number of investigators, i.e. Goddard Space Flight Center, Smithsonian Astrophysical Observatory, Ohio State University, The Naval Weapons Laboratory, Air Force Cambridge Research Laboratories, and Wallops Island. The comparisons have been made in terms of latitude, longitude and height. The results of the various solutions have been compared directly and also with external standards such as local survey data and gravimetrically derived geoid heights. After taking into account systematic rotations, latitude and longitude agreement on a global basis is generally 15 meters or better, on the North American Datum agreement is generally better than 10 meters. Allowing for scale differences (of the order of 2 ppm) radial agreement is generally of the order of 10 meters

Ultrafast harmonic mode-locking of monolithic compound-cavity laser diodes incorporating photonic-bandgap reflectors

We present the first demonstration of reproducible harmonic mode-locked operation from a novel design of monolithic semiconductor laser comprising a compound cavity formed by a 1-D photonic-bandgap (PBG) mirror. Mode-locking (ML) is achieved at a harmonic of the fundamental round-trip frequency with pulse repetition rates from 131 GHz up to a record high frequency of 2.1 THz. The devices are fabricated from GaAs-Al-GaAs material emitting at a wavelength of 860 nm and incorporate two gain sections with an etched PBG reflector between them, and a saturable absorber section. Autocorrelation studies are reported which allow the device behavior for different ML frequencies, compound cavity ratios, and type and number of intra-cavity reflectors to be analyzed. The highly reflective PBG microstructures are shown to be essential for subharmonic-free ML operation of the high-frequency devices. We have also demonstrated that the single PBG reflector can be replaced by two separate features with lower optical loss. These lasers may find applications in terahertz; imaging, medicine, ultrafast optical links, and atmospheric sensing

Dynamic sea surface topography, gravity and improved orbit accuracies from the direct evaluation of SEASAT altimeter data

A method for the simultaneous solution of dynamic ocean topography, gravity and orbits using satellite altimeter data is described. A GEM-T1 based gravitational model called PGS-3337 that incorporates Seasat altimetry, surface gravimetry and satellite tracking data has been determined complete to degree and order 50. The altimeter data is utilized as a dynamic observation of the satellite's height above the sea surface with a degree 10 model of dynamic topography being recovered simultaneously with the orbit parameters, gravity and tidal terms in this model. PGS-3337 has a geoid uncertainty of 60 cm root-mean-square (RMS) globally, with the uncertainty over the altimeter tracked ocean being in the 25 cm range. Doppler determined orbits for Seasat, show large improvements, with the sub-30 cm radial accuracies being achieved. When altimeter data is used in orbit determination, radial orbital accuracies of 20 cm are achieved. The RMS of fit to the altimeter data directly gives 30 cm fits for Seasat when using PGS-3337 and its geoid and dynamic topography model. This performance level is two to three times better than that achieved with earlier Goddard earth models (GEM) using the dynamic topography from long-term oceanographic averages. The recovered dynamic topography reveals the global long wavelength circulation of the oceans with a resolution of 1500 km. The power in the dynamic topography recovery is now found to be closer to that of oceanographic studies than for previous satellite solutions. This is attributed primarily to the improved modeling of the geoid which has occurred. Study of the altimeter residuals reveals regions where tidal models are poor and sea state effects are major limitations

A tribenzylidenemethane–tantalum compound: some experiences with 'inversion twinning'

The six-electron-donating ligand tribenzylidenemethandiide has been used to form a tantalum (group 5) mimic, (η^5-cyclopentadienyl)(η^4-tribenzylidenemethandiide)dimethyltantalum, of a group 4 bent metallocene. The material crystallizes with two molecules in the asymmetric unit with quite different packing arrangements, although the overall structures of the two are similar. The Cp and methyl ligands are disordered about a threefold axis. Crystal data: [Ta{(C_7H_6)_3C}(C_5H_5)(CH_3), trigonal P31c, with a = 12.681 (3), c = 16.124 (5) Å, V = 2245.5 (7) Å^3, T = 293 K, Z = 4, M_r = 558.47, D_x = 1.65 g cm^(-3), F(000) = 1104, Mo Kα, λ = 0.71073 Å, µ = 4.91 mm^(-1), R = 0.020 for 1319 reflections with F_o > 4σ(F_o); S = 2.18. Because of crystal decay, three separate crystals were needed for a full data set. These polar (but achiral) crystals showed apparently differing amounts of inversion twinning, leading to problems in accurately merging the three data sets and refining the structure. These problems are discussed briefly

The Distance of the Gamma-ray Binary 1FGL J1018.6-5856

The recently discovered gamma-ray binary 1FGL J1018.6-5856 has a proposed optical/near-infrared (OIR) counterpart 2MASS 10185560-5856459. We present Stromgren photometry of this star to investigate its photometric variability and measure the reddening and distance to the system. We find that the gamma-ray binary has E(B-V) = 1.34 +/- 0.04 and d = 5.4^+4.6_-2.1 kpc. While E(B-V) is consistent with X-ray observations of the neutral hydrogen column density, the distance is somewhat closer than some previous authors have suggested.Comment: Accepted to PAS

Cosmology of Axions and Moduli: A Dynamical Systems Approach

This paper is concerned with string cosmology and the dynamics of multiple scalar fields in potentials that can become negative, and their features as (Early) Dark Energy models. Our point of departure is the "String Axiverse", a scenario that motivates the existence of cosmologically light axion fields as a generic consequence of string theory. We couple such an axion to its corresponding modulus. We give a detailed presentation of the rich cosmology of such a model, ranging from the setting of initial conditions on the fields during inflation, to the asymptotic future. We present some simplifying assumptions based on the fixing of the axion decay constant $f_a$, and on the effective field theory when the modulus trajectory is adiabatic, and find the conditions under which these assumptions break down. As a by-product of our analysis, we find that relaxing the assumption of fixed $f_a$ leads to the appearance of a new meta-stable de-Sitter region for the modulus without the need for uplifting by an additional constant. A dynamical systems analysis reveals the existence of many fixed point attractors, repellers and saddle points, which we analyse in detail. We also provide geometric interpretations of the phase space. The fixed points can be used to bound the couplings in the model. A systematic scan of certain regions of parameter space reveals that the future evolution of the universe in this model can be rich, containing multiple epochs of accelerated expansion.Comment: 27 pages, 12 figures, comments welcome, v2 minor correction