Production and reliability oriented SOFC cell and stack design

The paper presents an innovative development methodology for a production and reliability oriented SOFC cell and stack design aiming at improving the stacks robustness, manufacturability, efficiency and cost. Multi-physics models allowed a probabilistic approach to consider statistical variations in production, material and operating parameters for the optimization phase. A methodology for 3D description of spatial distribution of material properties based on a random field models was developed and validated by experiments. Homogenized material models on multiple levels of the SOFC stack were established. The probabilistic models were related to the experimentally obtained properties of base materials to establish a statistical relationship between the material properties and the most relevant load effects. Software algorithms for meta models that allow the detection of relationships between input and output parameters and to perform a sensitivity analysis were developed and implemented. The capabilities of the methodology is illustrated on two practical cases

Temperature dependence of CO desorption kinetics at a novel Pt-on-Au/C PEM fuel cell anode

A Pt-on-Au/C fuel cell anode catalyst has been obtained by electrochemical deposition of platinum on carbon-supported gold nanoparticles. Its composition, structure and nanoparticle size distribution have been characterized before and after the desorption experiments using microstructural techniques. The temperature dependence of the CO desorption process on this system has been investigated using isotopic exchange experiments. The CO desorption kinetics have been studied as a function of temperature and flow rate. Desorption rate constants have been measured for a temperature range between 25 and 150°C. These desorption rate constants have been compared with the benchmarking desorption rate data obtained for the commercial Pt/C catalyst under similar experimental conditions. A comparable desorption rate constant for the Pt-on-Au/C and Pt/C systems has been obtained at 25°C. The dependence in temperature of the desorption rate constants for the novel Pt-on-Au/C system is however much lower than that observed for the Pt/C system. This suggests that the nature of the substrate has a significant influence on the catalyst surface properties. It shows that, in surface-modified catalysts, the interactions between underlayer and overlayer materials are worthy of consideration, since they can significantly modify the intrinsic properties of the active sites. The kinetics of the CO desorption process have been discussed with regards to the CO tolerance issue at the PEM fuel cell anode.JRC.F.2-Cleaner energ