An ab initio and force field study on the conformation and chain flexibility of the dichlorophosphazene trimer

Ab initio molecular orbital calculations have been used to study the conformation, valence electron charge density, and chain flexibility of a dichlorophosphazene trimer (CH3[NP(Cl2)]3CH3). The calculations were carried out at the restricted Hartree-Fock level with the 6-31 G* basis set. The dichlorophosphazene trimer adopts a planar transcis conformation. The valence electron charge distribution indicates strong charge separations along the backbone of the molecule, and is in agreement with Dewar's island delocalization model for bonding in linear and cyclic phosphazenes. In order to determine the height of the torsional barrier (2,5 kcal/mol), the torsional potential of a central P-N bond of the trimer was studied with a rigid rotor scan and geometry optimizations of selected rotamers. The flexibility of the P-N-P bond angle contributes significantly to the chain flexibility. Based on the results of the ab initio calculations, an empirical force field for the dichlorophosphazene trimer was developed. The energy expression includes bond stretch, angle bend, electrostatic, van der Waals, and torsional potential terms. A relaxed scan with the force field achieves good agreement with the ab initio results for the torsional potential in the vicinity of the stable conformation, and an excellent agreement with the ab initio results on changes in the P2N2P3 bond angle and the N1P2 - N2P3 dihedral angle during a full rotation around the N2 - P3 bond

An Investigation of AdS2_2 Backreaction and Holography

We investigate a dilaton gravity model in AdS$_2$ proposed by Almheiri and Polchinski and develop a 1d effective description in terms of a dynamical boundary time with a Schwarzian derivative action. We show that the effective model is equivalent to a 1d version of Liouville theory, and investigate its dynamics and symmetries via a standard canonical framework. We include the coupling to arbitrary conformal matter and analyze the effective action in the presence of possible sources. We compute commutators of local operators at large time separation, and match the result with the time shift due to a gravitational shockwave interaction. We study a black hole evaporation process and comment on the role of entropy in this model.Comment: 32 pages, 6 figures, v3: typos corrected and references added, matches published versio

An Experimental Test of Precautionary Bidding

Auctions often involve goods exhibiting a common knowledge ex-post risk that is independent of buyers’ private values or their signals regarding common value components. Esö and White (2004) showed theoretically that ex-post risk leads to precautionary bidding for DARA bidders: Agents reduce their bids by more than their appropriate risk premium. Testing precautionary bidding with data from the field seems almost impossible. We conduct experimental first-price auctions that allow us to directly identify the precautionary premium and find clear evidence for precautionary bidding. Bidders are significantly better off when a risky object rather than an equally valued sure object is auctioned. Our results are robust if we control for potentially confounding decision biases

Tempus Fugit: Time Pressure in Risky Decisions

We study the effects of time pressure on risky decisions for pure gain prospects, pure loss prospects, and mixed prospects involving both gains and losses. In an experiment we find that risk aversion for gains is robust under time pressure whereas risk seeking for losses turns into risk aversion under time pressure. For mixed prospects, subjects become more loss averse and more gain seeking under time pressure, depending on the framing of the prospects. The results suggest the importance of aspiration levels under time pressure. We discuss the implications of our findings for decision making situations that involve time pressure

Well-defined side-chain liquid-crystalline polysiloxanes

A route to well-defined side-chain liquid-crystalline polysiloxanes (ratio of weight-to number-average molar masses Mw/Mn < 1.2 is reported. Anionic ring-opening polymerization of pentamethylvinylcyclotrisiloxane yielded a poly(dimethylsiloxane-co-methylvinylsiloxane) backbone. A flexible disiloxane spacer was used to connect 4-(ω-alkenyloxy)-4'-cyanobiphenyl mesogenic molecules to the vinyl groups which belong to the backbone, leading to a side-chain liquid-crystalline polysiloxane (SCLCP) which has its mesogens distributed regularly along the main chain. Preliminary measurements indicate an electro-optic switching time s = 1 min at 20°C and 7 s at 32°C (dc, 5 V/µm))

Tempus Fugit: Time Pressure in Risky Decisions

We study the effects of time pressure on risky decisions for pure gain prospects, pure loss prospects, and mixed prospects involving both gains and losses. In an experiment we find that risk aversion for gains is robust under time pressure whereas risk seeking for losses turns into risk aversion under time pressure. For mixed prospects, subjects become more loss averse and more gain seeking under time pressure, depending on the framing of the prospects. The results suggest the importance of aspiration levels under time pressure. We discuss the implications of our findings for decision making situations that involve time pressure.time pressure; risky decisions; risk aversion; loss aversion; gain seeking; aspiration level

An Experimental Test of Precautionary Bidding

Auctions often involve goods exhibiting a common knowledge ex-post risk that is independent of buyers’ private values or their signals regarding common value components. Esö and White (2004) showed theoretically that ex-post risk leads to precautionary bidding for DARA bidders: Agents reduce their bids by more than their appropriate risk premium. Testing precautionary bidding with data from the field seems almost impossible. We conduct experimental first-price auctions that allow us to directly identify the precautionary premium and find clear evidence for precautionary bidding. Bidders are significantly better off when a risky object rather than an equally valued sure object is auctioned. Our results are robust if we control for potentially confounding decision biases.precautionary bidding; prudence; auction; experiment

Cloud information for FIRE from surface weather reports

Surface weather observations of clouds were analyzed to obtain a global cloud climatology (Warren et al, 1986; 1988). The form of the synoptic weather code limits the types of cloud information which are available from these reports. Comparison of surface weather reports with instrumental observations during the FIRE field experiments can help to clarify the operational definitions which were made in the climatology because of the nature of the synoptic code. The long-term climatology from surface weather observations is also useful background for planning the location and timing of intensive field experiments