Generalized van der Waals theory for the twist elastic modulus and helical pitch of cholesterics

We present a generalized van der Waals theory for a lyotropic cholesteric system of chiral spherocylinders based on the classical Onsager theory for hard anisometric bodies. The rods consist of a hard spherocylindrical backbone surrounded with a square-well potential to account for attractive (or soft repulsive) interactions. Long-ranged chiral interactions are described by means of a simple pseudo-scalar potential which is appropriate for weak chiral forces of a predominant electrostatic origin. Based on the formalism proposed by Straley [Phys. Rev. A {\bf 14}, 1835 (1976)] we derive explicit algebraic expressions for the twist elastic modulus and the cholesteric pitch for rods as a function of density and temperature. The pitch varies non-monotonically with density, with a sharp decrease at low packing fractions and a marked increase at higher packing fractions. A similar trend is found for the temperature dependence. The unwinding of the helical pitch at high densities (or low temperatures) originates from a marked increase in the local nematic order and a steep increase of the twist elastic resistance associated with near-parallel local rod configurations. This contrasts with the commonly held view that the increase in pitch with decreasing temperature as often observed in cholesterics is due to layer formation resulting from pre-smectic fluctuations. The increase in pitch with increasing temperature is consistent with an entropic unwinding as the chiral interaction becomes less and less significant than the thermal energy. The variation of the pitch with density, temperature and contour length is in qualitative agreement with recent experimental results on colloidal {\em fd} rods.Comment: 17 pages, 6 figures, to appear in J. Chem. Phy

Feynman-Jackson integrals

We introduce perturbative Feynman integrals in the context of q-calculus generalizing the Gaussian q-integrals introduced by Diaz and Teruel. We provide analytic as well as combinatorial interpretations for the Feynman-Jackson integrals.Comment: Final versio

Investigation of light scattering in highly reflecting pigmented coatings. Volume 3 - Monte Carlo and other statistical investigations Final report, 1 May 1963 - 30 Sep. 1966

Monte Carlo methods, Mie theory, and random walk and screen models for predicting reflective properties of paint film

Stochastic Quantization and Casimir Forces: Pistons of Arbitrary Cross Section

Recently, a method based on stochastic quantization has been proposed to compute the Casimir force and its fluctuations in arbitrary geometries. It relies on the spectral decomposition of the Laplacian operator in the given geometry. Both quantum and thermal fluctuations are considered. Here we use such method to compute the Casimir force on the plates of a finite piston of arbitrary cross section. Asymptotic expressions valid at low and high temperatures and short and long distances are obtained. The case of a piston with triangular cross section is analysed in detail. The regularization of the divergent stress tensor is described.Comment: 10 pages and 4 figures. Accepted for publication in the Proceedings of the tenth conference on Quantum Field Theory under the influence of external conditions - QFEXT'1

THE ROLE OF SMALL BUSINESS IN ECONOMIC GROWTH AND POVERTY ALLEVIATION IN WEST VIRGINIA: AN EMPIRICAL ANALYSIS

In OLS and 2SLS regression analysis a positive relationship exists between small business and economic growth. A strong inverse relationship also exists between the incidence of poverty and small business and economic growth. Thus, the empirical result establishes the linkage between small business, economic growth and the incidence of povertyResearch Methods/ Statistical Methods,

Investigation of Light Scattering in Highly Reflecting Pigmented Coatings Quarterly Report, Feb. 1 - May 1, 1966

Monte Carlo method applied to pigment particle clusters, and relevance of Mie scattering function to reflected ligh

Investigation of light scattering in highly reflecting pigmented coatings Quarterly report, Nov. 1, 1965 - Feb. 1, 1966

Monte Carlo treatment to find light scattering parameters of metal filled, reflecting pigmented coating

Solvable Examples of Drift and Diffusion of Ions in Non-uniform Electric Fields

The drift and diffusion of a cloud of ions in a fluid are distorted by an inhomogeneous electric field. If the electric field carries the center of the distribution in a straight line and the field configuration is suitably symmetric, the distortion can be calculated analytically. We examine the specific examples of fields with cylindrical and spherical symmetry in detail assuming the ion distributions to be of a generally Gaussian form. The effects of differing diffusion coefficients in the transverse and longitudinal directions are included

Ray model and ray-wave correspondence in coupled optical microdisks

We introduce a ray model for coupled optical microdisks, in which we select coupling-efficient rays among the splitting rays. We investigate the resulting phase-space structure and report island structures arising from the ray-coupling between the two microdisks. We find the microdisks's refractive index to influence the phase-space structure and calculate the stability and decay rates of the islands. Turning to ray-wave correspondence, we find many resonances to be directly related to the presence of these islands. We study the relation between the (ray-picture originating) island structures and the (wave-picture originating) spectral properties of resonances, especially the leakiness of the resonances which is represented as the imaginary part of the complex wave vector.Comment: 9 pages, 8 figure