1,449 research outputs found
The 3s Rydberg state as a doorway state in the ultrafast dynamics of 1,1-difluoroethylene
The deactivation dynamics of 1,1-difluoroethylene after light excitation is studied within the surface hopping formalism in the presence of 3s and 3p Rydberg states using multi-state second order perturbation theory (MS-CASPT2). Due to the proximity of the Rydberg π-3s state with the ππ* state, the states are mixed favoring ultrafast exchange of population via a conical intersection that closely resembles the equilibrium structure. After excitation, it is found that the π-3s state acts as a doorway state, trapping the population and delaying internal conversion to the ππ* state, from which deactivation to the closed-shell ground state takes place. Besides the conical intersection between the π-3s and ππ* states, five additional conical intersections between the ππ* state and the ground state are found, indicating that after the system is excited, it stretches the C[double bond, length as m-dash]C bond before it twists and pyramidalizes at any of the carbon atoms, in the spirit of a hula-twist mechanism
Publishing Linked Data - There is no One-Size-Fits-All Formula
Publishing Linked Data is a process that involves several design decisions and technologies. Although some initial guidelines have been already provided by Linked Data publishers, these are still far from covering all the steps that are necessary (from data source selection to publication) or giving enough details about all these steps, technologies, intermediate products, etc. Furthermore, given the variety of data sources from which Linked Data can be generated, we believe that it is possible to have a single and uni�ed method for publishing Linked Data, but we should rely on di�erent techniques, technologies and tools for particular datasets of a given domain. In this paper we present a general method for publishing Linked Data and the application of the method to cover di�erent sources from di�erent domains
The IGN-E case: Integrating through a hidden ontology
National Geographic Institute of Spain (IGN-E) wanted to integrate its main information sources for building a common vocabulary reference and thus to manage the huge amount of information it held. The main problem of this integration is the great heterogeneity of data sources. The Ontology Engineering Group (OEG) is working with IGN-E to attain this objective in two phases: first, by creating automatically an ontology using the semantics of catalogues sections, and second, by discovering mappings automatically that can relate ontology concepts to database instances. So, these mappings are the instruments to break the syntactic, semantic and granularity heterogeneity gap. We have developed software for building a first ontology version and for discovering automatically mappings using techniques that take into account all types of heterogeneity. The ontology contains a set of extra-attributes which are identified in the building process. The ontology, called PhenomenOntology, will be reviewed by domain experts of IGN-E. The automatic mapping discovery will be also used for discovering new knowledge that will be added to the ontology. For increasing the usability and giving independence to different parts, the processes of each phase will be designed automatically and as upgradeable as possible
GeoLinked Data. An application case / Un caso de aplicación
In this paper we present the process that has been followed for the development of an application that makes use of several heterogeneous Spanish public datasets that are related to three themes of INSPIRE Directive, specifically Administrative Units, Hydrography, and Statistical Units. Our application aims at analysing existing relations between the Spanish coastal area and different statistical variables such as population, unemployment, dwelling, industry, and building trade. Besides providing ethodological guidelines for the generation, publishing and exploitation of Linked Data from such datasets, we provide an important innovation with respect to other similar processes followed in other initiatives by dealing with the geometrical information of features
Rivière or Fleuve? Modelling Multilinguality in the Hydrographical
The need for interoperability among geospatial resources in different natural languages evidences the difficulties to cope with domain representations highly dependent of the culture in which they have been conceived. In this paper we characterize the problem of representing cultural discrepancies in ontologies. We argue that such differences can be accounted for at the ontology terminological layer by means of external elaborated models of linguistic information associated to ontologies. With the aim of showing how external models can cater for cultural discrepancies, we compare two versions of an ontology of the hydrographical domain: hydrOntology. The first version makes use of the labeling system supported by RDF(S) and OWL to include multilingual linguistic information in the ontology. The second version relies on the Linguistic Information Repository model (LIR) to associate structured multilingual information to ontology concepts. In this paper we propose an extension to the LIR to better capture linguistic and cultural specificities within and across language
Robot computing for music visualization
© Springer Nature Switzerland AG 2019. This paper presents an algorithm design of Music Visualization on Robot (MVR) which could automatically link the flashlight, color, and emotion through music. We call this algorithm as MVR algorithm that composed by two analyses. First, we focus on Music Signal Analysis. Second, we focus on Music Sentiment Analysis. We integrate two analysis results and implement the MVR algorithm on a robot called Zenbo which is released from ASUS Company. We perform the Zenbo Robot in luminous environments. The MVR system not only could be used in Zenbo robot but also could extend to other fields of Artificial Intelligent (AI) equipment in the future
Combinando Linked Data con servicios geoespaciales
La Web de Linked Data supone un nuevo paradigma que pretende explotar la Web como un espacio global de información. La aplicación de los principios de esta nueva Web a la información geoespacial superará la integración de información tradicional, logrando una articulación semántica de los datos que haga desaparecer los silos de datos presentes en las actuales Infraestructuras de Datos Espaciales.
Ante esta propuesta, en este artículo se describe el trabajo desarrollado en el marco de un caso de uso utilizando una parte de los datos del SIGNA. En este caso de uso se ha llevado a cabo un proceso de generación y publicación de los mencionados datos conforme a los principios de Linked Data y estos se combinan con diversos servicios de la IDEE y CartoCiudad para explotar el componente geoespacial
LinkedData en el dominio geográfico español y posibles aplicaciones
Es un esfuerzo de la comunidad para:
• Publicar conjuntos de datos abiertos en la Web.
• Conectar “cosas” entre diferentes conjuntos de datos
Photocatalytic hydrogen production by biomimetic indium sulfide using Mimosa pudica leaves as template
Biomimetic sulfur-deficient indium sulfide (In2.77S4) was synthesized by a template-assisted hydrothermal method using leaves of Mimosa pudica as a template for the first time. The effect of this template in modifying the morphology of the semiconductor particles was determined by physicochemical characterization, revealing an increase in surface area, decrease in microsphere size and pore size and an increase in pore volume density in samples synthesized with the template. X-ray photoelectron spectroscopy (XPS) analysis showed the presence of organic sulfur (S O/S C/S H) and sulfur oxide species ( SO2, SO32−, SO42−) at the surface of the indium sulfide in samples synthesized with the template. Biomimetic indium sulfide also showed significant amounts of Fe introduced as a contaminant present on the Mimosa pudica leaves. The presence of these sulfur and iron species favors the photocatalytic activity for hydrogen production by their acting as a sacrificial reagent and promoting water oxidation on the surface of the templated particles, respectively. The photocatalytic hydrogen production rates over optimally-prepared biomimetic indium sulfide and indium sulfide synthesized without the organic template were 73 and 22 μmol g−1, respectively, indicating an improvement by a factor of three in the templated sample
Characteristic Evolution and Matching
I review the development of numerical evolution codes for general relativity
based upon the characteristic initial value problem. Progress in characteristic
evolution is traced from the early stage of 1D feasibility studies to 2D
axisymmetric codes that accurately simulate the oscillations and gravitational
collapse of relativistic stars and to current 3D codes that provide pieces of a
binary black hole spacetime. Cauchy codes have now been successful at
simulating all aspects of the binary black hole problem inside an artificially
constructed outer boundary. A prime application of characteristic evolution is
to extend such simulations to null infinity where the waveform from the binary
inspiral and merger can be unambiguously computed. This has now been
accomplished by Cauchy-characteristic extraction, where data for the
characteristic evolution is supplied by Cauchy data on an extraction worldtube
inside the artificial outer boundary. The ultimate application of
characteristic evolution is to eliminate the role of this outer boundary by
constructing a global solution via Cauchy-characteristic matching. Progress in
this direction is discussed.Comment: New version to appear in Living Reviews 2012. arXiv admin note:
updated version of arXiv:gr-qc/050809
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