Charge and momentum transfer in supercooled melts: Why should their relaxation times differ?

The steady state values of the viscosity and the intrinsic ionic-conductivity of quenched melts are computed, in terms of independently measurable quantities. The frequency dependence of the ac dielectric response is estimated. The discrepancy between the corresponding characteristic relaxation times is only apparent; it does not imply distinct mechanisms, but stems from the intrinsic barrier distribution for $\alpha$-relaxation in supercooled fluids and glasses. This type of intrinsic ``decoupling'' is argued not to exceed four orders in magnitude, for known glassformers. We explain the origin of the discrepancy between the stretching exponent $\beta$, as extracted from $\epsilon(\omega)$ and the dielectric modulus data. The actual width of the barrier distribution always grows with lowering the temperature. The contrary is an artifact of the large contribution of the dc-conductivity component to the modulus data. The methodology allows one to single out other contributions to the conductivity, as in ``superionic'' liquids or when charge carriers are delocalized, implying that in those systems, charge transfer does not require structural reconfiguration.Comment: submitted to J Chem Phy

Simple Lattice-Models of Ion Conduction: Counter Ion Model vs. Random Energy Model

The role of Coulomb interaction between the mobile particles in ionic conductors is still under debate. To clarify this aspect we perform Monte Carlo simulations on two simple lattice models (Counter Ion Model and Random Energy Model) which contain Coulomb interaction between the positively charged mobile particles, moving on a static disordered energy landscape. We find that the nature of static disorder plays an important role if one wishes to explore the impact of Coulomb interaction on the microscopic dynamics. This Coulomb type interaction impedes the dynamics in the Random Energy Model, but enhances dynamics in the Counter Ion Model in the relevant parameter range.Comment: To be published in Phys. Rev.

Invest in fast-charging infrastructure or in longer battery ranges? A cost-efficiency comparison for Germany

To reach ambitious CO₂ mitigation targets, the transport sector has to become nearly emission-free and the most promising option for passenger cars are battery electric vehicles (BEV) powered using renewable energy. Despite their important benefits, BEV still face technological barriers, mainly their limited battery range and the limited availability of public fast-charging infrastructure. These factors are hindering the diffusion of electric vehicles (EV). The question of how to address these technical barriers has been widely analyzed in the literature, but so far there has been no cost-efficiency comparison of longer battery ranges and more widespread fast-charging infrastructure that evaluates them both technically and economically. This paper aims to find cost-efficient ways to address limited battery ranges and availability of public fast-charging infrastructure. We focus on German passenger cars that are licensed to commercial owners, since these are an important first market for EV. Our results indicate that fast-charging infrastructure is very cost-efficient as it enables significant proportions of BEV in the fleet at low infrastructure density. The technically feasible maximum BEV shares in the commercial sector can only be achieved with longer battery ranges. However, longer battery ranges are currently associated with comparatively high additional costs

Contributions to the mixed-alkali effect in molecular dynamics simulations of alkali silicate glasses

The mixed-alkali effect on the cation dynamics in silicate glasses is analyzed via molecular dynamics simulations. Observations suggest a description of the dynamics in terms of stable sites mostly specific to one ionic species. As main contributions to the mixed--alkali slowdown longer residence times and an increased probability of correlated backjumps are identified. The slowdown is related to the limited accessibility of foreign sites. The mismatch experienced in a foreign site is stronger and more retarding for the larger ions, the smaller ions can be temporarily accommodated. Also correlations between unlike as well as like cations are demonstrated that support cooperative behavior.Comment: 10 pages, 12 figures, 1 table, revtex4, submitted to Phys. Rev.

Nitrogen compounds and ozone in the stratosphere: comparison of MIPAS satellite data with the Chemistry Climate Model ECHAM5/MESSy1

International audienceThe chemistry climate model ECHAM5/MESSy1 (E5/M1) in a setup extending from the surface to 80 km with a vertical resolution of about 600 m near the tropopause with nudged tropospheric meteorology allows a direct comparison with satellite data of chemical species at the same time and location. Here we present results out of a transient 10 years simulation for the period of the Antarctic vortex split in September 2002, where data of MIPAS on the ENVISAT-satellite are available. For the first time this satellite instrument opens the opportunity, to evaluate all stratospheric nitrogen containing species simultaneously with a good global coverage, including the source gas N2O which allows an estimate for NOx-production in the stratosphere. We show correlations between simulated and observed species in the altitude region between 10 and 50 hpa for different latitude belts, together with the Probability Density Functions (PDFs) of model results and observations. This is supplemented by global charts on pressure levels showing the satellite data and the simulated data sampled at the same time and location. We demonstrate that the model in most cases captures the partitioning in the nitrogen family, the diurnal cycles and the spatial distribution within experimental uncertainty. There appears to be, however, a problem to reproduce the observed nighttime partitioning between N2O5 and NO2 in the middle stratosphere

Nutritional composition of formulated complementary food produced from blends of malted and unmalted yellow maize (Zea mays), soybean (Glycine max), and tiger nut (Cyperus esculentus) flour

Protein-energy malnutrition (PEM) and micronutrient deficiencies among infants and children in developing countries have been a major concern of the World Health Organization. Formulation of complementary food from local sources of raw materials can be of great help in solving the problems of protein energy malnutrition. This study determined the nutritional composition of four formulated complementary foods from malted yellow maize, pre-gelatinized yellow maize, soybean, and tiger nut flour. The results showed an increase in protein content (17.6, 16.9, 20.4 & 19.7 %), crude fat (14.9, 12.9, 13.0 & 12.9 %) and energy (433.1, 419.4, 421.5 & 426.6 %) when compared with the control sample. The functional properties also competed favourably with the control sample, with the formulated samples having water absorption capacity (171.9, 169.0, 184.1 & 167.4 %), swelling power (27.9, 25.2, 29.8 and 28.1 %), and bulk density at the same level for all the formulated samples (0.5 g/ml). The formulated samples contained a higher amount of iron and magnesium, and the anti-nutritional factors fell below the hazard level. In conclusion, formulated complementary food made from locally sourced raw materials has enough nutritional composition to be able to combat PEM and micronutrient deficiencies among infants and children