87 research outputs found

    Structures and Catalytic Properties of Diphosphinidenecyclobutene Complexes

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    Synthesis and coordination behavior of Cu(I) bis(phosphaethenyl)pyridine complexes.

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    Cu(I) complexes bearing BPEP as a PNP-pincer type phosphaalkene ligand undergo effective bonding interactions with SbF(6)(-) and PF(6)(-) as non-coordinating anions to give [Cu(SbF(6))(BPEP)] and [Cu(2)(BPEP)(2)(μ-PF(6))](+), respectively [BPEP = 2, 6-bis(1-phenyl-2-phosphaethenyl)pyridine]. NMR and theoretical studies indicate a reduced anionic charge of the μ-PF(6) ligand, which is induced by the strong π-accepting ability of BPEP

    Reactions of cis

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    Mechanistic Study on the Insertion of Phenylacetylene into cis

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